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Emerging applications of stimuli-responsive polymer materials

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Stuart, Martien A. Cohen, Huck, Wilhelm T. S., Genzer, Jan, Müller, Marcus, Ober, Christopher, Stamm, Manfred, Sukhorukov, Gleb B., Szleifer, Igal, Tsukruk, Vladimir V., Urban, Marek, Winnik, Françoise, Zauscher, Stefan, Luzinov, Igor, Minko, Sergiy·2010·Nature Materials

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  1. Senaratne, W., Andruzzi, L. & Ober, C. K. Self-assembled monolayers and polymer brushes in biotechnology: Current applications and future perspectives. Biomacromolecules 6, 2427–2448 (2005). · DOI · Paper page
  2. Jhaveri, S. J. et al. Release of nerve growth factor from HEMA hydrogel-coated substrates and its effect on the differentiation of neural cells. Biomacromolecules 10, 174–183 (2009). · DOI
  3. Hoffman, A. S. The origins and evolution of “controlled” drug delivery systems. J. Control. Release 132, 153–163 (2008). · DOI · Paper page
  4. Bayer, C. L. & Peppas, N. A. Advances in recognitive, conductive and responsive delivery systems. J. Control. Release 132, 216–221 (2008). · DOI
  5. Mendes, P. M. Stimuli-responsive surfaces for bio-applications. Chem. Soc. Rev. 37, 2512–2529 (2008). · DOI · Paper page
  6. Luzinov, I., Minko, S. & Tsukruk, V. V. Responsive brush layers: from tailored gradients to reversibly assembled nanoparticles. Soft Matter 4, 714–725 (2008). · DOI · Paper page
  7. Motornov, M. et al. Reversible tuning of wetting behaviour of polymer surface with responsive polymer brushes. Langmuir 19, 8077–8085 (2003). · DOI
  8. Liu, Z. S. & Calvert, P. Multilayer hydrogels as muscle-like actuators. Adv. Mater. 12, 288–291 (2000). · DOI · Paper page
  9. Anker, J. N. et al. Biosensing with plasmonic nanosensors. Nature Mater. 7, 442–453 (2008). · DOI · Paper page
  10. Tokarev, I. & Minko, S. Stimuli-responsive hydrogel thin films. Soft Matter 5, 511–524 (2009). · DOI · Paper page
  11. Koberstein, J. T. Molecular design of functional polymer surfaces. J. Polym. Sci. Pol. Phys. 42, 2942–2956 (2004). · doi:10.1002/polb.20157
  12. Carey, D. H., Grunzinger, S. J. & Ferguson, G. S. Entropically influenced reconstruction at the PBD-ox/water interface: The role of physical crosslinking and rubber elasticity. Macromolecules 33, 8802–8812 (2000). · doi:10.1021/ma000189z
  13. Draper, J., Luzinov, I., Minko, S., Tokarev, I. & Stamm, M. Mixed polymer brushes by sequential polymer addition: Anchoring layer effect. Langmuir 20, 4064–4075 (2004). · DOI
  14. Motornov, M. et al. Stimuli-responsive colloidal systems from mixed brush-coated nanoparticles. Adv. Funct. Mater. 17, 2307–2314 (2007). · doi:10.1002/adfm.200600934
  15. Abu-Lail, N. I., Kaholek, M., LaMattina, B., Clark, R. L. & Zauscher, S. Micro-cantilevers with end-grafted stimulus-responsive polymer brushes for actuation and sensing. Sensor. Actuat. B-Chem. 114, 371–378 (2006). · DOI
  16. Ayres, N., Cyrus, C. D. & Brittain, W. J. Stimuli-responsive surfaces using polyampholyte polymer brushes prepared via atom transfer radical polymerization. Langmuir 23, 3744–3749 (2007). · DOI
  17. Azzaroni, O., Brown, A. A. & Huck, W. T. S. UCST wetting transitions of polyzwitterionic brushes driven by self-association. Angew. Chem. Int. Ed. 45, 1770–1774 (2006). · DOI · Paper page
  18. Santer, S., Kopyshev, A., Donges, J., Yang, H. K. & Ruhe, J. Dynamically reconfigurable polymer films: Impact on nanomotion. Adv. Mater. 18, 2359–2362 (2006). · DOI
  19. Wu, T. et al. Behaviour of surface-anchored poly(acrylic acid) brushes with grafting density gradients on solid substrates: 1. Experiment. Macromolecules 40, 8756–8764 (2007). · DOI · Paper page
  20. Xu, C. et al. Effect of block length on solvent response of block copolymer brushes: Combinatorial study with block copolymer brush gradients. Macromolecules 39, 3359–3364 (2006). · DOI
  21. Motornov, M., Sheparovych, R., Tokarev, I., Roiter, Y. & Minko, S. Nonwettable thin films from hybrid polymer brushes can be hydrophilic. Langmuir 23, 13–19 (2007). · doi:10.1021/la061737q
  22. Sheparovych, R., Motornov, M. & Minko, S. Adapting low-adhesive thin films from mixed polymer brushes. Langmuir 24, 13828–13832 (2008). · doi:10.1021/la803117y
  23. Sheparovych, R., Motornov, M. & Minko, S. Low adhesive surfaces which adapt changing surrounding environment. Adv. Mater. 21, 1840–1844 (2009). · DOI
  24. Tanaka, T. & Fillmore, D. J. Kinetics of swelling of gels. J. Chem. Phys. 70, 1214–1218 (1979). · DOI · Paper page
  25. Toomey, R., Freidank, D. & Ruhe, J. Swelling behaviour of thin, surface-attached polymer networks. Macromolecules 37, 882–887 (2004). · DOI · Paper page
  26. Crowe-Willoughby, J. A. & Genzer, J. Formation and properties of responsive siloxane-based polymeric surfaces with tunable surface reconstruction kinetics. Adv. Funct. Mater. 19, 460–469 (2009). · doi:10.1002/adfm.200800622
  27. Crowe, J. A. & Genzer, J. Creating responsive surfaces with tailored wettability switching kinetics and reconstruction reversibility. J. Am. Chem. Soc. 127, 17610–17611 (2005). · doi:10.1021/ja056926u
  28. Tokarev, I., Orlov, M. & Minko, S. Responsive polyelectrolyte gel membranes. Adv. Mater. 18, 2458–2460 (2006). · doi:10.1002/adma.200601288
  29. Tokarev, I. & Minko, S. Multiresponsive hierarchically structured membranes: new challenging biomimetic materials for biosensors, controlled release, biochemical gates and nanoreactors. Adv. Mater. 21, 241–247 (2009). · DOI
  30. Tokarev, I. et al. Stimuli-responsive hydrogel membranes coupled with biocatalytic processes. ACS Appl. Mater. Interfaces 3, 532–536 (2009). · DOI · Paper page
  31. Decher, G. Fuzzy nanoassemblies: Toward layered polymeric multicomposites. Science 277, 1232–1237 (1997). · DOI · Paper page
  32. Lvov, Y., Ariga, K., Ichinose, I. & Kunitake, T. Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption. J. Am. Chem. Soc. 117, 6117–6123 (1995). · DOI · Paper page
  33. Decher, G. & Schlenoff, J. B. Multilayer Thin Films (Wiley-VCH, 2003).
  34. Itano, K., Choi, J. Y. & Rubner, M. F. Mechanism of the pH-induced discontinuous swelling/deswelling transitions of poly(allylamine hydrochloride)-containing polyelectrolyte multilayer films. Macromolecules 38, 3450–3460 (2005). · DOI
  35. Kharlampieva, E., Kozlovskaya, V., Tyutina, J. & Sukhishvili, S. A. Hydrogen-bonded multilayers of thermoresponsive polymers. Macromolecules 38, 10523–10531 (2005). · DOI
  36. Hua, F., Cui, T. H. & Lvov, Y. M. Ultrathin cantilevers based on polymer-ceramic nanocomposite assembled through layer-by-layer adsorption. Nano Lett. 4, 823–825 (2004). · doi:10.1021/nl0498031
  37. Mertz, D. et al. Mechanically responding nanovalves based on polyelectrolyte multilayers. Nano Lett. 7, 657–662 (2007). · DOI
  38. Urban, M. W. Intelligent polymeric coatings; current and future advances. Polym. Rev. 46, 329–339 (2006).
  39. Misra, A., Jarrett, W. L. & Urban, M. W. Fluoromethacrylate-containing colloidal dispersions: Phospholipid-assisted synthesis, particle morphology, and temperature-responsive stratification. Macromolecules 40, 6190–6198 (2007). · doi:10.1021/ma070852k
  40. Motornov, M., Sheparovych, R., Lupitskyy, R., MacWilliams, E. & Minko, S. Superhydrophobic surfaces generated from water-borne dispersions of hierarchically assembled nanoparticles coated with a reversibly switchable shell. Adv. Mater. 20, 200–205 (2008). · doi:10.1002/adma.200700030
  41. Urban, M. W. Stratification, Stimuli-responsiveness, self-healing, and signalling in polymer networks. Prog. Polym. Sci. 34, 679–687 (2009). · doi:10.1016/j.progpolymsci.2009.03.004
  42. Andreeva, D. V., Fix, D., Mohwald, H. & Shchukin, D. G. Self-healing anticorrosion coatings based on pH-sensitive polyelectrolyte/inhibitor sandwich-like nanostructures. Adv. Mater. 20, 2789–2794 (2008). · DOI · Paper page
  43. Bajpai, A. K., Shukla, S. K., Bhanu, S. & Kankane, S. Responsive polymers in controlled drug delivery. Prog. Polym. Sci. 33, 1088–1118 (2008). · DOI · Paper page
  44. Alexander, C. & Shakesheff, K. M. Responsive polymers at the biology/materials science interface. Adv. Mater. 18, 3321–3328 (2006). · DOI · Paper page
  45. Lutolf, M. P. et al. Synthetic matrix metalloproteinase-sensitive hydrogels for the conduction of tissue regeneration: Engineering cell-invasion characteristics. Proc. Natl Acad. Sci. USA 100, 5413–5418 (2003). · DOI · Paper page
  46. Alarcon, C. D. H., Farhan, T., Osborne, V. L., Huck, W. T. S. & Alexander, C. Bioadhesion at micro-patterned stimuli-responsive polymer brushes. J. Mater. Chem. 15, 2089–2094 (2005). · DOI
  47. Ionov, L., Houbenov, N., Sidorenko, A., Stamm, M. & Minko, S. Stimuli-responsive command polymer surface for generation of protein gradients. Biointerphases 4, FA45–FA49 (2009). · DOI
  48. Hayashi, G., Hagihara, M., Dohno, C. & Nakatani, K. Photoregulation of a peptide-RNA interaction on a gold surface. J. Am. Chem. Soc. 129, 8678–8679 (2007). · doi:10.1021/ja071298x
  49. Ebara, M. et al. Temperature-responsive cell culture surfaces enable “on-off” affinity control between cell integrins and RGDS ligands. Biomacromolecules 5, 505–510 (2004). · DOI
  50. Lue, S. J., Hsu, J. J. & Wei, T. C. Drug permeation modeling through the thermo-sensitive membranes of poly(N-isopropylacrylamide) brushes grafted onto micro-porous films. J. Membrane Sci. 321, 146–154 (2008). · doi:10.1016/j.memsci.2008.04.053
  51. Motornov, M. et al. Switchable selectivity for gating ion transport with mixed polyelectrolyte brushes: approaching 'smart' drug delivery systems. Nanotechnology 20, 434006 (2009). · DOI
  52. Wong, V. N. et al. Separation of peptides with polyionic nanosponges for MALDI-MS analysis. Langmuir 25, 1459–1465 (2009). · doi:10.1021/la802723r
  53. Nagase, K. et al. Effects of graft densities and chain lengths on separation of bioactive compounds by nanolayered thermoresponsive polymer brush surfaces. Langmuir 24, 511–517 (2008). · DOI
  54. Edmondson, S., Frieda, K., Comrie, J. E., Onck, P. R. & Huck, W. T. S. Buckling in quasi-2D polymers. Adv. Mater. 18, 724–728 (2006). · DOI
  55. Zhou, F., Shu, W. M., Welland, M. E. & Huck, W. T. S. Highly reversible and multi-stage cantilever actuation driven by polyelectrolyte brushes. J. Am. Chem. Soc. 128, 5326–5327 (2006). · DOI · Paper page
  56. Valiaev, A., Abu-Lail, N. I., Lim, D. W., Chilkoti, A. & Zauscher, S. Microcantilever sensing and actuation with end-grafted stimulus-responsive elastin-like polypeptides. Langmuir 23, 339–344 (2007). · doi:10.1021/la0616698
  57. Zhou, F. et al. Polyelectrolyte brush amplified electroactuation of microcantilevers. Nano Lett. 8, 725–730 (2008). · DOI
  58. Singamaneni, S. et al. Bimaterial microcantilevers as a hybrid sensing platform. Adv. Mater. 20, 653–680 (2008). · DOI · Paper page
  59. Jonas, A. M., Hu, Z. J., Glinel, K. & Huck, W. T. S. Effect of nanoconfinement on the collapse transition of responsive polymer brushes. Nano Lett. 8, 3819–3824 (2008). · DOI
  60. Lee, W. K., Patra, M., Linse, P. & Zauscher, S. Scaling behaviour of nanopatterned polymer brushes. Small 3, 63–66 (2007). · DOI
  61. Raynor, J. E., Petrie, T. A., Garcia, A. J. & Collard, D. M. Controlling cell adhesion to titanium: Functionalization of poly[oligo(ethylene glycol)methacrylate] brushes with cell-adhesive peptides. Adv. Mater. 19, 1724–1728 (2007). · DOI
  62. Howse, J. R. et al. Reciprocating power generation in a chemically driven synthetic muscle. Nano Lett. 6, 73–77 (2006). · DOI
  63. Merlitz, H., He, G. L., Wu, C. X. & Sommer, J. U. Surface instabilities of monodisperse and densely grafted polymer brushes. Macromolecules 41, 5070–5072 (2008). · doi:10.1021/ma800163a
  64. Tokareva, I., Minko, S., Fendler, J. H. & Hutter, E. Nanosensors based on responsive polymer brushes and gold nanoparticle enhanced transmission surface plasmon resonance spectroscopy. J. Am. Chem. Soc. 126, 15950–15951 (2004). · DOI · Paper page
  65. Gupta, S. et al. Gold nanoparticles immobilized on stimuli responsive polymer brushes as nanosensors. Macromolecules 41, 8152–8158 (2008). · DOI
  66. Kozlovskaya, V. et al. Ultrathin layer-by-layer hydrogels with incorporated gold nanorods as pH-sensitive optical materials. Chem. Mater. 20, 7474–7485 (2008). · doi:10.1021/cm8023633
  67. Podsiadlo, P. et al. Exponential growth of LBL films with incorporated inorganic sheets. Nano Lett. 8, 1762–1770 (2008). · doi:10.1021/nl8011648
  68. Jiang, G. Q., Baba, A. & Advincula, R. Nanopatterning and fabrication of memory devices from layer-by-layer poly(3,4-ethylenedioxythiophene)-poly(styrene sulphonate) ultrathin films. Langmuir 23, 817–825 (2007). · doi:10.1021/la061817u
  69. Mitamura, K., Imae, T., Tian, S. & Knoll, W. Surface plasmon fluorescence investigation of energy-transfer-controllable organic thin films. Langmuir 24, 2266–2270 (2008). · doi:10.1021/la703001y
  70. Hilt, J. Z., Gupta, A. K., Bashir, R. & Peppas, N. A. Ultrasensitive biomems sensors based on microcantilevers patterned with environmentally responsive hydrogels. Biomed. Microdevices 5, 177–184 (2003). · DOI · Paper page
  71. Mack, N. H. et al. Optical transduction of chemical forces. Nano Lett 7, 733–737 (2007). · DOI
  72. Kang, J. H. et al. Thermoresponsive hydrogel photonic crystals by three-dimensional holographic lithography. Adv. Mater. 20, 3061–3065 (2008). · doi:10.1002/adma.200800141
  73. Ben-Moshe, M., Alexeev, V. L. & Asher, S. A. Fast responsive crystalline colloidal array photonic crystal glucose sensors. Anal. Chem. 78, 5149–5157 (2006). · DOI · Paper page
  74. Jiang, C. Y., Markutsya, S., Pikus, Y. & Tsukruk, V. V. Freely suspended nanocomposite membranes as highly sensitive sensors. Nature Mater. 3, 721–728 (2004). · DOI · Paper page
  75. Dong, L., Agarwal, A. K., Beebe, D. J. & Jiang, H. R. Adaptive liquid microlenses activated by stimuli-responsive hydrogels. Nature 442, 551–554 (2006). · DOI · Paper page
  76. Hendrikson, G. R. & Lyon, L. A. Bioresponsive hydrogels for sensing application. Soft Matter 5, 29–35 (2009). · DOI
  77. Sidorenko, A., Krupenkin, T., Taylor, A., Fratzl, P. & Aizenberg, J. Reversible switching of hydrogel-actuated nanostructures into complex micropatterns. Science 315, 487–490 (2007). · DOI · Paper page
  78. Kuksenok, O., Yashin, V. V. & Balazs, A. C. Mechanically induced chemical oscillations and motion in responsive gels. Soft Matter 3, 1138–1144 (2007). · doi:10.1039/b707393c
  79. Discher, D. E. et al. Emerging applications of polymersomes in delivery: From molecular dynamics to shrinkage of tumours. Prog. Polym. Sci. 32, 838–857 (2007). · DOI · Paper page
  80. Qi, L., Chapel, J. P., Castaing, J. C., Fresnais, J. & Berret, J. F. Organic versus hybrid coacervate complexes: co-assembly and adsorption properties. Soft Matter 4, 577–585 (2008). · DOI
  81. Yan, Y. et al. Hierarchical self-assembly in solutions containing metal ions, ligand, and diblock copolymer. Angew. Chem. Int. Ed. 46, 1807–1809 (2007). · DOI
  82. Voets, I. K. et al. Spontaneous symmetry breaking: formation of Janus micelles. Soft Matter 5, 999–1005 (2009). · DOI
  83. Li, M. H. & Keller, P. Stimuli-responsive polymer vesicles. Soft Matter, 5, 927–937 (2009). · DOI · Paper page
  84. Chiu, H. C., Lin, Y. W., Huang, Y. F., Chuang, C. K. & Chern, C. S. Polymer vesicles containing small vesicles within interior aqueous compartments and pH-responsive transmembrane channels. Angew. Chem. Int. Ed. 47, 1875–1878 (2008). · DOI
  85. Oh, J. K., Drumright, R., Siegwart, D. J. & Matyjaszewski, K. The development of microgels/nanogels for drug delivery applications. Prog. Polym. Sci. 33, 448–477 (2008). · DOI · Paper page
  86. Morimoto, N., Qiu, X. P., Winnik, F. M. & Akiyoshi, K. Dual stimuli-responsive nanogels by self-assembly of polysaccharides lightly grafted with thiol-terminated poly(N-isopropylacrylamide) chains. Macromolecules 41, 5985–5987 (2008). · DOI
  87. Morimoto, N., Winnik, F. M. & Akiyoshi, K. Botryoidal assembly of cholesteryl-pullulan/poly(N-isopropylacrylamide) nanogels. Langmuir 23, 217–223 (2007). · doi:10.1021/la0616045
  88. Motornov, M. et al. “Chemical transformers” from nanoparticle ensembles operated with logic. Nano Lett. 8, 2993–2997 (2008). · DOI
  89. Donath, E., Sukhorukov, G. B., Caruso, F., Davis, S. A. & Möhwald, H. Novel hollow polymer shells by colloid-templated assembly of polyelectrolytes. Angew. Chem. Int. Ed. 37, 2202–2205 (1998). · DOI · Paper page
  90. Zelikin, A. N., Li, Q. & Caruso, F. Disulphide-stabilized poly(methacrylic acid) capsules: Formation, crosslinking, and degradation behaviour. Chem. Mater. 20, 2655–2661 (2008). · DOI · Paper page
  91. Levy, T., Dejugnat, C. & Sukhorukov, G. B. Polymer microcapsules with carbohydrate-sensitive properties. Adv. Funct. Mater. 18, 1586–1594 (2008). · doi:10.1002/adfm.200701291
  92. Kozlovskaya, V., Kharlampieva, E., Mansfield, M. L. & Sukhishvili, S. A. Poly(methacrylic acid) hydrogel films and capsules: Response to pH and ionic strength, and encapsulation of macromolecules. Chem. Mater. 18, 328–336 (2006). · DOI · Paper page
  93. Edwards, E. W., Chanana, M., Wang, D. & Möhwald, H. Stimuli-responsive reversible transport of nanoparticles across water/oil interfaces. Angew. Chem. Int. Ed. 47, 320–323 (2008). · doi:10.1002/anie.200702597
  94. Binks, B. P., Murakami, R., Armes, S. P. & Fujii, S. Temperature-induced inversion of nanoparticle-stabilized emulsions. Angew. Chem. Int. Ed. 44, 4795–4798 (2005). · DOI · Paper page
  95. Binks, B. P. & Murakami, R. Phase inversion of particle-stabilized materials from foams to dry water. Nature Mater. 5, 865–869 (2006). · DOI · Paper page
  96. Lu, Y., Mei, Y., Drechsler, M. & Ballauff, M. Thermosensitive core-shell particles as carriers for Ag nanoparticles: Modulating the catalytic activity by a phase transition in networks. Angew. Chem. Int. Ed. 45, 813–816 (2006). · DOI · Paper page
  97. Lu, Y. et al. Thermosensitive core-shell microgel as a “nanoreactor” for catalytic active metal nanoparticles. J. Mater. Chem. 19, 3955–3961 (2009). · DOI · Paper page
  98. Skirtach, A. G. et al. Laser-induced release of encapsulated materials inside living cells. Angew. Chem. Int. Ed. 45, 4612–4617 (2006). · DOI · Paper page
  99. Kreft, O., Javier, A. M., Sukhorukov, G. B. & Parak, W. J. Polymer microcapsules as mobile local pH-sensors. J. Mater. Chem. 17, 4471–4476 (2007). · DOI · Paper page
  100. Gillies, E. R., Jonsson, T. B. & Frechet, J. M. J. Stimuli-responsive supramolecular assemblies of linear-dendritic copolymers. J. Am. Chem. Soc. 126, 11936–11943 (2004). · DOI · Paper page
  101. Laugel, N. et al. Relationship between the growth regime of polyelectrolyte multilayers and the polyanion/polycation complexation enthalpy. J. Phys. Chem. B 110, 19443–19449 (2006). · doi:10.1021/jp062264z
  102. Kakizawa, Y. & Kataoka, K. Block copolymer micelles for delivery of gene and related compounds. Adv. Drug Deliver. Rev. 54, 203–222 (2002). · DOI · Paper page
  103. Oishi, M., Hayashi, H., Michihiro, I. D. & Nagasaki, Y. Endosomal release and intracellular delivery of anticancer drugs using pH-sensitive PEGylated nanogels. J. Mater. Chem. 17, 3720–3725 (2007). · DOI
  104. Lee, E. S., Kim, D., Youn, Y. S., Oh, K. T. & Bae, Y. H. A virus-mimetic nanogel vehicle. Angew. Chem. Int. Ed. 47, 2418–2421 (2008). · DOI · Paper page
  105. Zhulina, E. B., Singh, C. & Balazs, A. C. Forming patterned films with tethered diblock copolymers. Macromolecules 29, 6338–6348 (1996). · DOI
  106. Roan, J. R. Soft nanopolyhedra as a route to multivalent nanoparticles. Phys. Rev. Lett. 96, 248301 (2006). · doi:10.1103/physrevlett.96.248301
  107. Müller, M. Phase diagram of a mixed polymer brush. Phys. Rev. E 65, 30802 (2002). · DOI
  108. Wenning, L., Müller, M. & Binder, K. How does the pattern of grafting points influence the structure of one-component and mixed polymer brushes? Europhys. Lett. 71, 639–645 (2005). · DOI
  109. Yin, Y. H. et al. A simulated annealing study of diblock copolymer brushes in selective solvents. Macromolecules 40, 5161–5170 (2007). · DOI
  110. Matsen, M. W. The standard Gaussian model for block copolymer melts. J. Phys. Condens. Matter. 14, R21–R47 (2002). · DOI · Paper page
  111. Müller-Plathe, F. Coarse-graining in polymer simulation: From the atomistic to the mesoscopic scale and back. Chemphyschem 3, 754–769 (2002). · doi:10.1002/1439-7641(20020916)3:9<754::aid-cphc754>3.0.co;2-u
  112. Praprotnik, M., Delle Site, L. & Kremer, K. Multiscale simulation of soft matter: From scale bridging to adaptive resolution. Annu. Rev. Phys. Chem. 59, 545–571 (2008). · DOI · Paper page
  113. Merlitz, H., He, G. L., Sommer, J. U. & Wu, C. H. Reversibly switchable polymer brushes with hydrophobic/hydrophilic behaviour: A Langevin dynamics study. Macromolecules 42, 445–451 (2009). · DOI
  114. Fang, F. & Szleifer, I. Controlled release of proteins from polymer-modified surfaces. Proc. Natl Acad. Sci. USA 103, 5769–5774 (2006). · DOI
  115. Szleifer, I. & Carignano, M. A. Tethered polymer layers: phase transitions and reduction of protein adsorption. Macromol. Rapid Comm. 21, 423–448 (2000). · doi:10.1002/(sici)1521-3927(20000501)21:8<423::aid-marc423>3.0.co;2-j
  116. Israels, R., Leermakers, F. A. M. & Fleer, G. J. On the theory of grafted weak polyacids. Macromolecules 27, 3087–3093 (1994). · doi:10.1021/ma00089a028
  117. Ye, Y., McCoy, J. D. & Curro, J. G. Application of density functional theory to tethered polymer chains: Effect of intermolecular attractions. J. Chem. Phys. 119, 555–564 (2003). · doi:10.1063/1.1577325
  118. Ren, C. L., Nap, R. J. & Szleifer, I. The role of hydrogen bonding in tethered polymer layers. J. Phys. Chem. B 112, 16238–16248 (2008). · DOI
  119. Zhulina, E. B. & Leermakers, F. A. M. A self-consistent field analysis of the neurofilament brush with amino-acid resolution. Biophys. J. 93, 1421–1430 (2007). · DOI
  120. Tagliazucchi, M., Calvo, E. J. & Szleifer, I. Molecular theory of chemically modified electrodes by redox polyelectrolytes under equilibrium conditions: Comparison with experiment. J. Phys. Chem. C 112, 458–471 (2008). · doi:10.1021/jp073123f
  121. Tagliazucchi, M., Calvo, E. J. & Szleifer, I. Redox and acid base coupling in ultrathin polyelectrolyte films. Langmuir 24, 2869–2877 (2008). · doi:10.1021/la702734n
  122. Mendez, S., Curro, J. G., McCoy, J. D. & Lopez, G. P. Computational modeling of the temperature-induced structural changes of tethered poly(N-isopropylacrylamide) with self-consistent field theory. Macromolecules 38, 174–181 (2005). · DOI
  123. Wang, Q. Internal structure and charge compensation of polyelectrolyte multilayers: a numerical study. Soft Matter 5, 413–424 (2009). · doi:10.1039/b809095e
  124. Pattanayek, S. K. & Pereira, G. G. Shape of micelles formed from strongly adsorbed grafted polymers in poor solvents. Macromol. Theor. Simul. 14, 347–357 (2005). · DOI
  125. Netz, R. R. & Andelman, D. Neutral and charged polymers at interfaces. Phys. Rep. 380, 1–95 (2003). · doi:10.1016/s0370-1573(03)00118-2
  126. Wang, J. & Müller, M. Microphase separation of diblock copolymer brushes in selective solvents: Single-chain-in-mean-field simulations and integral geometry analysis. Macromolecules 42, 2251–2264 (2009). · doi:10.1021/ma8026047
  127. Groot, R. D. & Warren, P. B. Dissipative particle dynamics: Bridging the gap between atomistic and mesoscopic simulation. J. Chem. Phys. 107, 4423–4435 (1997). · DOI · Paper page
  128. Daoulas, K. Ch. & Müller, M. Comparison of simulations of lipid membranes with membranes of block copolymers. Adv. Polym. Sci. 224, 197–233 (2009). · doi:10.1007/978-3-642-10479-4_27
  129. Santer, S. et al. Memory of surface patterns in mixed polymer brushes: Simulation and experiment. Langmuir 23, 279–285 (2007). · DOI
  130. Santer, S., Kopyshev, A., Donges, J., Yang, H. K. & Rühe, J. Domain memory of mixed polymer brushes. Langmuir 22, 4660–4667 (2006). · doi:10.1021/la060134b
  131. Tam, T. K., Ornatska, M., Pita, M., Minko, S. & Katz, E. Polymer brush-modified electrode with switchable and tunable redox activity for bioelectronic applications. J. Phys. Chem. C 112, 8438–8445 (2008). · doi:10.1021/jp801086w
  132. Motornov, M. et al. Integrated multifunctional nanosystem from command nanoparticles and enzymes. Small 5, 817–820 (2009). · doi:10.1002/smll.200801550
  133. Maye, M. M., Nykypanchuk, Cuisinier, M., van der Lelie, D. & Gang, O. Nature Mater. 8, 388–391 (2009). · DOI · Paper page
  134. Ghosh, B. & Urban, M. W. Self-repairing oxetane-substituted chitosan polyurethane networks. Science 323, 1458–1460 (2009). · DOI · Paper page

Cited by

See all 5,707

Metadata

Authors
Stuart, M. A. C., Huck, W. T. S., Genzer, J., Müller, M., Ober, C., Stamm, M., Sukhorukov, G. B., Szleifer, I., Tsukruk, V. V., Urban, M., Winnik, F., Zauscher, S., Luzinov, I., & Minko, S.
Venue
Nature Materials
Published
2010-01-22
Volume
9
Issue
2
Pages
101-113
ISSN
  • 1476-1122 (ISSN-L)
  • 1476-4660
OpenAlex
W2141947008
Cited by
5,707
References
2
FWCI
134.48
Type
journal article
Language
en
Open access
bronze
Licence

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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

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This page
CoChat. (2026). Citation check: Emerging applications of stimuli-responsive polymer materials. https://app.cochat.ai/papers/10.1038/nmat2614
The paper
Stuart, M. A. C., Huck, W. T. S., Genzer, J., Müller, M., Ober, C., Stamm, M., Sukhorukov, G. B., Szleifer, I., Tsukruk, V. V., Urban, M., Winnik, F., Zauscher, S., Luzinov, I., & Minko, S. (2010). Emerging applications of stimuli-responsive polymer materials. Nature Materials. https://doi.org/10.1038/nmat2614

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.