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Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O2 and Oxidation of H2, Alcohols, Biomass, and Complex Fuels

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Anson, Colin W., Stahl, Shannon S.·2020·Chemical Reviews

Abstract

Mediated fuel cells are electrochemical devices that produce power in a manner similar to that of conventional proton exchange membrane fuel cells (PEMFCs). They differ from PEMFCs in their use of redox mediators dissolved in liquid electrolyte to conduct oxidation of the fuel or reduction of the oxidant, typically O 2, in bulk solution. The mediators transport electrons (and often protons) between the electrode and the catalysts or chemical reagents in solution. This strategy can help overcome many of the challenges associated with conventional fuel cells, including managing complex multiphase reactions (as in O 2 reduction) or the use of challenging or heterogeneous fuels, such as hydrocarbons, polyols, and biomass. Mediators are also commonly used in enzymatic fuel cells, where direct electron transfer from the electrode to the enzymatic active site can be slow. This review provides a comprehensive survey of historical and recent mediated fuel cell efforts, including applications using chemical and enzymatic catalysts.

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Metadata

Authors
Anson, C. W., & Stahl, S. S.
Venue
Chemical Reviews
Published
2020-03-27
Volume
120
Issue
8
Pages
3749-3786
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
OpenAlex
W3014068938
Cited by
201
References
6
FWCI
1.16
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O2 and Oxidation of H2, Alcohols, Biomass, and Complex Fuels. https://app.cochat.ai/papers/10.1021/acs.chemrev.9b00717
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Anson, C. W., & Stahl, S. S. (2020). Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O2 and Oxidation of H2, Alcohols, Biomass, and Complex Fuels. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.9b00717

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.