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Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O2 and Oxidation of H2, Alcohols, Biomass, and Complex Fuels
Open accessAbstract
Mediated fuel cells are electrochemical devices that produce power in a manner similar to that of conventional proton exchange membrane fuel cells (PEMFCs). They differ from PEMFCs in their use of redox mediators dissolved in liquid electrolyte to conduct oxidation of the fuel or reduction of the oxidant, typically O 2, in bulk solution. The mediators transport electrons (and often protons) between the electrode and the catalysts or chemical reagents in solution. This strategy can help overcome many of the challenges associated with conventional fuel cells, including managing complex multiphase reactions (as in O 2 reduction) or the use of challenging or heterogeneous fuels, such as hydrocarbons, polyols, and biomass. Mediators are also commonly used in enzymatic fuel cells, where direct electron transfer from the electrode to the enzymatic active site can be slow. This review provides a comprehensive survey of historical and recent mediated fuel cell efforts, including applications using chemical and enzymatic catalysts.
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Gasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156
Kongkanand, A., & Mathias, M. F. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00216 · Cited by 1,202
Integrating PGM‐Free Catalysts into Catalyst Layers and Proton Exchange Membrane Fuel Cell Devices
Banham, D., Choi, J., Kishimoto, T., & Ye, S. (2019) · Advanced Materials · doi:10.1002/adma.201804846 · Cited by 157
Cited by
The Significance of Properly Reporting Turnover Frequency in Electrocatalysis Research
Anantharaj, S., Karthik, P. E., & Noda, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202110352 · Cited by 494
Zhang, B., Biswal, B. K., Zhang, J., & Balasubramanian, R. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00673 · Cited by 432
Zhu, J., Xia, L., Yu, R., Lu, R., Li, J., He, R., Wu, Y., Zhang, W., Hong, X., Chen, W., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c03982 · Cited by 384
Non-carbon-supported single-atom site catalysts for electrocatalysis
Zheng, X., Li, P., Dou, S., Sun, W., Pan, H., Wang, D., & Li, Y. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00248a · Cited by 346
Yang, F., Ye, J., Gao, L., Yu, J., Yang, Z., Lu, Y., Ma, C., Zeng, Y., & Huang, H. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202301408 · Cited by 79
Metadata
- Authors
- Anson, C. W., & Stahl, S. S.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-03-27
- Volume
- 120
- Issue
- 8
- Pages
- 3749-3786
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W3014068938
- Cited by
- 201
- References
- 6
- FWCI
- 1.16
- Type
- journal article
- Language
- en
- Open access
- green
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- Anson, C. W., & Stahl, S. S. (2020). Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O2 and Oxidation of H2, Alcohols, Biomass, and Complex Fuels. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.9b00717
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