The Nanoscale Basis of CO2 Trapping for Geologic Storage

Bourg, Ian C.; Beckingham, Lauren E.; DePaolo, Donald J.

doi:10.1021/acs.est.5b03003

Cited by 163CO2 Sequestration and Geologic InteractionsEnhanced Oil Recovery TechniquesCarbon Dioxide Capture Technologies

The Nanoscale Basis of CO2 Trapping for Geologic Storage

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Bourg, Ian C., Beckingham, Lauren E., DePaolo, Donald J.·2015·Environmental Science & Technology

DOI 10.1021/acs.est.5b03003

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Abstract

Carbon capture and storage (CCS) is likely to be a critical technology to achieve large reductions in global carbon emissions over the next century. Research on the subsurface storage of CO2 is aimed at reducing uncertainties in the efficacy of CO2 storage in sedimentary rock formations. Three key parameters that have a nanoscale basis and that contribute uncertainty to predictions of CO2 trapping are the vertical permeability kv of seals, the residual CO2 saturation Sg,r in reservoir rocks, and the reactive surface area ar of silicate minerals. This review summarizes recent progress and identifies outstanding research needs in these areas. Available data suggest that the permeability of shale and mudstone seals is heavily dependent on clay fraction and can be extremely low even in the presence of fractures. Investigations of residual CO2 trapping indicate that CO2-induced alteration in the wettability of mineral surfaces may significantly influence Sg,r. Ultimately, the rate and extent of CO2 conversion to mineral phases are uncertain due to a poor understanding of the kinetics of slow reactions between minerals and fluids. Rapidly improving characterization techniques using X-rays and neutrons, and computing capability for simulating chemical interactions, provide promise for important advances.

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Reactivity hosted in thin water films has been demonstrated to alter geomechanical properties and subsurface porosity of reservoir rocks.
“Among various important nanoscale processes affecting carbon storage reservoirs 41,42 , reactivity hosted in thin water films have been demonstrated to alter geomechanical properties 43 and subsurface porosity 44 of reservoir rocks.”
From Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films (2022) · cites this paper as [41]

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Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films
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Thin Water Films Enable Low-Temperature Magnesite Growth Under Conditions Relevant to Geologic Carbon Sequestration
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Authors: Bourg, I. C., Beckingham, L. E., & DePaolo, D. J.
Affiliations: Lawrence Berkeley National Laboratory (US)
Corresponding author: Bourg, Ian C.
ORCID: Bourg, Ian C.
Beckingham, Lauren E.
DePaolo, Donald J.
Venue: Environmental Science & Technology
Publisher: American Chemical Society (ACS)
Published: 2015-08-20
Volume: 49
Issue: 17
Pages: 10265-10284
ISSN: 0013-936X (ISSN-L)
1520-5851
DOI: 10.1021/acs.est.5b03003
OpenAlex: W2381069085
Cited by: 163
References: 406
Citations by year: 2026: 22 · 2025: 17 · 2024: 14 · 2023: 19 · 2022: 10 · 2021: 13 · 2020: 11 · 2019: 14 · 2018: 17 · 2017: 17 · 2016: 8 · 2015: 1
FWCI: 10.33
Type: journal article
Language: en
Open access: green
www.osti.gov
Locations: Environmental Science & Technology (publishedVersion)
PubMed (publishedVersion)
OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
Funders: Basic Energy Sciences
Topics: Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
Physical Sciences › Engineering › Ocean Engineering › Enhanced Oil Recovery Techniques
Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
Keywords: carbon capture and storage, CO2 geological storage, CO2 trapping, nanoscale processes, clay content, fracture, wettability alteration, silicate minerals, reactive surface area, sedimentary rock formation
MeSH terms: Carbon Dioxide, Models, Theoretical, Silicates, Geologic Sediments, Nanoparticles, Carbon Sequestration

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The Nanoscale Basis of CO2 Trapping for Geologic Storage

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