The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Exploring the Role of Persulfate in the Activation Process: Radical Precursor Versus Electron Acceptor
Abstract
This study elucidates the mechanism behind persulfate activation by exploring the role of various oxyanions (e.g., peroxymonosulfate, periodate, and peracetate) in two activation systems utilizing iron nanoparticle (nFe 0 ) as the reducing agent and single-wall carbon nanotubes (CNTs) as electron transfer mediators. Since the tested oxyanions serve as both electron acceptors and radical precursors in most cases, oxidative degradation of organics was achievable through one-electron reduction of oxyanions on nFe 0 (leading to radical-induced oxidation) and electron transfer mediation from organics to oxyanions on CNTs (leading to oxidative decomposition involving no radical formation). A distinction between degradative reaction mechanisms of the nFe 0 /oxyanion and CNT/oxyanion systems was made in terms of the oxyanion consumption efficacy, radical scavenging effect, and EPR spectral analysis. Statistical study of substrate-specificity and product distribution implied that the reaction route induced on nFe 0 varies depending on the oxyanion (i.e., oxyanion-derived radical), whereas the similar reaction pathway initiates organic oxidation in the CNT/oxyanion system irrespective of the oxyanion type. Chronoamperometric measurements further confirmed electron transfer from organics to oxyanions in the presence of CNTs, which was not observed when applying nFe 0 instead.
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Cites
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution
Neta, P., Huie, R. E., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555808 · Cited by 3,651
Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy
Dresselhaus, M. S., Jorio, A., Hofmann, M., Dresselhaus, G., & Saito, R. (2010) · Nano Letters · doi:10.1021/nl904286r · Cited by 3,254
Oh, W.-D., Dong, Z., & Lim, T.-T. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.003 · Cited by 2,612
A review of classic Fenton’s peroxidation as an advanced oxidation technique
Neyens, E., & Baeyens, J. (2003) · Journal of Hazardous Materials · doi:10.1016/s0304-3894(02)00282-0 · Cited by 2,438
Standard Potentials in Aqueous Solution.
Trasatti, S. (1987) · Bioelectrochemistry and Bioenergetics · doi:10.1016/0302-4598(87)80040-5 · Cited by 1,633
A rapid spectrophotometric determination of persulfate anion in ISCO
Liang, C., Huang, C.-F., Mohanty, N., & Kurakalva, R. M. (2008) · Chemosphere · doi:10.1016/j.chemosphere.2008.08.043 · Cited by 1,456
Influence of pH on the Formation of Sulfate and Hydroxyl Radicals in the UV/Peroxymonosulfate System
Guan, Y.-H., Ma, J., Li, X.-C., Fang, J.-Y., & Chen, L.-W. (2011) · Environmental Science & Technology · doi:10.1021/es2017363 · Cited by 1,338
Rastogi, A., Al-Abed, S. R., & Dionysiou, D. D. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2008.07.010 · Cited by 1,112
Non-photochemical production of singlet oxygen via activation of persulfate by carbon nanotubes
Cheng, X., Guo, H., Zhang, Y., Wu, X., & Liu, Y. (2017) · Water Research · doi:10.1016/j.watres.2017.02.016 · Cited by 1,065
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Wang, J., & Wang, S. (2019) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2019.04.282 · Cited by 2,345
Reactive Species in Advanced Oxidation Processes: Formation, Identification and Reaction Mechanism
Wang, J., & Wang, S. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126158 · Cited by 1,585
Metal-Free Carbocatalysis in Advanced Oxidation Reactions
Duan, X., Sun, H., & Wang, S. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00535 · Cited by 1,329
Yun, E.-T., Lee, J. H., Kim, J., Park, H.-D., & Lee, J. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b00959 · Cited by 1,175
Self-citationTang, L., Liu, Y., Wang, J., Zeng, G., Deng, Y., Dong, H., Feng, H., Wang, J., & Peng, B. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.02.059 · Cited by 827
Metadata
- Authors
- Yun, E.-T., Yoo, H.-Y., Bae, H., Kim, H.-I., & Lee, J.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-16
- Volume
- 51
- Issue
- 17
- Pages
- 10090-10099
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2739613792
- Cited by
- 359
- References
- 44
- FWCI
- 14.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yun, E.-T., Yoo, H.-Y., Bae, H., Kim, H.-I., & Lee, J. (2017). Exploring the Role of Persulfate in the Activation Process: Radical Precursor Versus Electron Acceptor. Environmental Science & Technology. https://doi.org/10.1021/acs.est.7b02519
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