Disentangling Light- and Temperature-Induced Thermal Effects in Colloidal Au Nanoparticles
Open accessAbstract
We present temperature-dependent (from room temperature to 80 °C) absorption spectra of Au/SiO 2 core-shell nanoparticles (NPs) (core diameter: ∼25 nm) in water in the range from 1.5 to 4.5 eV, which spans the localized surface plasmon resonance (LSPR) and the interband transitions.A decrease in absorption with temperature over the entire spectral range is observed, which is more prominent at the LSPR.These changes are well reproduced by theoretical calculations of the absorption spectra, based on the experimentally measured temperature-dependent real (ε 1 ) and imaginary (ε 2 ) parts of the dielectric constant of Au NPs and of the surrounding medium.In addition, we model the photoinduced response of the NPs over the entire spectral range.The experimental and theoretical results of the thermal heating and the simulations of the photoinduced heating are compared with the ultrafast photoinduced transient absorption (TA) spectra upon excitation of the LSPR.These show that while the latter is a reliable monitor of heating of the NP and its environment, the interband region mildly responds to heating but predominantly to the population evolution of charge carriers.
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There are two ways to make nanoparticles respond to internal or external stimuli: using nanomaterials with responsive effects, or modifying nanoparticles by polymerizing or linking functional groups with responsive effects.
“There are two ways to make nanoparticles respond to internal or external stimuli: first, to use nanomaterials with responsive effects, such as gold nanoparticles sensitive to light and heat; second, to modify the nanoparticles by polymerizing or linking functional groups with responsive effects.134,135”
From Smart nanoparticles for cancer therapy (2023) · cites this paper as [134]
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- Authors
- Wang, L., Zare, D., Chow, T. H., Wang, J., Magnozzi, M., & Chergui, M.
- Affiliations
- École Polytechnique Fédérale de Lausanne (CH)
- Chinese University of Hong Kong (HK)
- University of Genoa (IT)
- Corresponding author
- Chergui, Majed
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2022-02-14
- Volume
- 126
- Issue
- 7
- Pages
- 3591-3599
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- PMC
- PMC8883463
- OpenAlex
- W4213169446
- Cited by
- 14
- References
- 63
- Citations by year
- 2026: 3 · 2025: 2 · 2024: 3 · 2023: 5 · 2022: 1
- FWCI
- 0.63
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- The Journal of Physical Chemistry C (publishedVersion, cc-by-nc-nd)
- PubMed Central (publishedVersion, cc-by-nc-nd)
- PubMed (publishedVersion)
- Infoscience (Ecole Polytechnique Fédérale de Lausanne) (submittedVersion, cc-by-nc-nd)
- CINECA IRIS Institutial Research Information System (University of Genoa) (submittedVersion, other-oa)
- Funders
- Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
- China Scholarship Council
- H2020 European Research Council (695197 DYNAMOX)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
- Physical Sciences › Engineering › Biomedical Engineering › Plasmonic and Surface Plasmon Research
- Physical Sciences › Engineering › Biomedical Engineering › Laser-Ablation Synthesis of Nanoparticles
- Keywords
- colloidal gold nanoparticles, localized surface plasmon resonance, thermal effects, dielectric constant, interband absorption, temperature dependence, light-induced heating
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