The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Mechanistic Investigation of Biomass Oxidation Using Nickel Oxide Nanoparticles in a CO2-Saturated Electrolyte for Paired Electrolysis
Abstract
A highly efficient CO 2 electrolysis system could be created by introducing biomass oxidation as an alternative anodic reaction to the sluggish oxygen evolution reaction in a CO 2 -saturated and near-neutral electrolyte. Here, we successfully demonstrate anodic biomass oxidation by synthesizing 5 nm nickel oxide nanoparticles (NiO NPs). NiO NPs show a unique electrocatalytic activity for 5-hydroxymethylfurfural (HMF) oxidation under near-neutral conditions, exhibiting an anodic current onset (1 mA cm –2 ) at 1.524 V versus the reversible hydrogen electrode and a total Faradaic efficiency of ≤70%. Electrokinetic and in situ ultraviolet–visible spectroscopic analyses suggest that a redox active nickel hydroxide species is formed on the surface of NiO electrocatalysts during HMF oxidation, and this oxidation of Ni(II) hydroxide to Ni(III) oxyhydroxide could be the rate-determining step. This mechanistic study of biomass oxidation in a CO 2 -saturated electrolyte provides insight into constructing a highly efficient system for the paired electrolysis of CO 2 reduction and biomass oxidation.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
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Sustainable polymers from renewable resources
Zhu, Y., Romain, C., & Williams, C. K. (2016) · Nature · doi:10.1038/nature21001 · Cited by 2,762
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
Eerhart, A. J. J. E., Faaij, A. P. C., & Patel, M. K. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02480b · Cited by 666
Lee, C. W., Hong, J. S., Yang, K. D., Jin, K., Lee, J. H., Ahn, H.-Y., Seo, H., Sung, N.-E., & Nam, K. T. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03242 · Cited by 228
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Yang, Y., & Mu, T. (2021) · Green Chemistry · doi:10.1039/d1gc00914a · Cited by 539
Lu, Y., Liu, T., Huang, Y.-C., Zhou, L., Li, Y., Chen, W., Yang, L., Zhou, B., Wu, Y., Kong, Z., et al. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c00174 · Cited by 282
Metadata
- Authors
- Choi, S., Balamurugan, M., Lee, K.-G., Cho, K. H., Park, S., Seo, H., & Nam, K. T.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-03-29
- Volume
- 11
- Issue
- 8
- Pages
- 2941-2948
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W3013777139
- Cited by
- 164
- References
- 7
- FWCI
- 3.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Choi, S., Balamurugan, M., Lee, K.-G., Cho, K. H., Park, S., Seo, H., & Nam, K. T. (2020). Mechanistic Investigation of Biomass Oxidation Using Nickel Oxide Nanoparticles in a CO2-Saturated Electrolyte for Paired Electrolysis. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/acs.jpclett.0c00425
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