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Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons

Hill, Megan R., Carmean, R. Nicholas, Sumerlin, Brent S.·2015·Macromolecules

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Abstract

Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer chemistry over the past two decades, thus laying the groundwork for the synthesis of complex macromolecules and enabling the preparation of previously inaccessible materials. Reversible addition-fragmentation chain transfer (RAFT) polymerization has emerged as one of the most promising techniques because of its functional group tolerance, applicability to a wide range of vinyl monomers, and its nondemanding experimental conditions. However, despite the promise and clearly demonstrated utility of RAFT, limitations of the method sometimes still exist, including the occasional need for extended polymerization times, limited access to high molecular weight polymers, low “livingness” due to unavoidable radical termination events, etc. This Perspective focuses on recent advances that have been specifically designed to address many of these perceived limitations to reinforce the promise of RAFT for the synthesis of complex and well-defined polymers under facile conditions.

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See all 494

Authors: Hill, M. R., Carmean, R. N., & Sumerlin, B. S.
Venue: Macromolecules
Publisher: American Chemical Society (ACS)
Published: 2015-07-28
Volume: 48
Issue: 16
Pages: 5459-5469
ISSN: 0024-9297 (ISSN-L)
1520-5835
DOI: 10.1021/acs.macromol.5b00342
OpenAlex: W2338096747
Cited by: 494
References: 90
FWCI: 26.67
Type: journal article
Language: en
Open access: closed

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Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

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Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.

Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons

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