The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Ion-Pairing Strength in Polyelectrolyte Complexes
Abstract
Polyelectrolyte complexes, PECs, are spontaneously formed blends of polyelectrolytes bearing positive, Pol +, and negative, Pol –, repeat units. Many interesting PEC morphologies have been observed, ranging from dense precipitates to liquidlike coacervates to quasi-stable nanoparticles, depending on the identity of the polymers and the preparation conditions. While the number of polyelectrolytes available to synthesize these materials is large and increasing, the corresponding number of Pol + /Pol – combinations is vast. This work quantitatively compares the binding strengths between a selection of positive and negative polyelectrolytes by evaluating the extent to which ion pairs between them are broken by a common salt, KBr. Comparison of association constants or Gibbs free energies between different classes of ionic functionality reveals that more “hydrophilic” PECs are more weakly associated, small primary amines bind strongly, carboxylates bind weakly, and aromatic sulfonates interact more strongly than aliphatic ones. The use of “charge density” to predict binding strength is shown not to be justified. Ion diffusion coefficients through PECs also approximately follow water content and are inversely related to interaction strength.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites
Decher, G. (1997) · Science · doi:10.1126/science.277.5330.1232 · Cited by 10,054
Encyclopedia of polymer science and technology
(2003) · Choice Reviews Online · doi:10.5860/choice.41-0674 · Cited by 5,095
Molecular basis for the explanation of the exponential growth of polyelectrolyte multilayers
Picart, C., Mutterer, J., Richert, L., Luo, Y., Prestwich, G. D., Schaaf, P., Voegel, J.-C., & Lavalle, P. (2002) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.202486099 · Cited by 904
Polyelectrolyte complexes: Bulk phases and colloidal systems
Gucht, J. V. D., Spruijt, E., Lemmers, M., & Cohen Stuart, M. A. (2011) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2011.05.080 · Cited by 611
The Polyelectrolyte Complex/Coacervate Continuum
Wang, Q., & Schlenoff, J. B. (2014) · Macromolecules · doi:10.1021/ma500500q · Cited by 585
Self-citationAnderson, D. E., Becktel, W. J., & Dahlquist, F. W. (1990) · Biochemistry · doi:10.1021/bi00461a025 · Cited by 509
Fu, J., & Schlenoff, J. B. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11878 · Cited by 493
Self-citationMichaels, A. S. (1965) · Industrial & Engineering Chemistry · doi:10.1021/ie50670a007 · Cited by 469
Hofmeister effects: interplay of hydration, nonelectrostatic potentials, and ion size
Parsons, D. F., Boström, M., Nostro, P. L., & Ninham, B. W. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp20538b · Cited by 453
Complex coacervate core micelles
Voets, I. K., de Keizer, A., & Cohen Stuart, M. A. (2009) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2008.09.012 · Cited by 427
Thünemann, A. F., Müller, M., Dautzenberg, H., Joanny, J.-F., & Löwen, H. (2012) · Advances in Polymer Science · doi:10.1007/b11350 · Cited by 371
Chirality-selected phase behaviour in ionic polypeptide complexes
Perry, S. L., Leon, L., Hoffmann, K. Q., Kade, M. J., Priftis, D., Black, K. A., Wong, D., Klein, R. A., Pierce, C. F., Margossian, K. O., et al. (2015) · Nature Communications · doi:10.1038/ncomms7052 · Cited by 300
Ion Transport and Equilibria in Polyelectrolyte Multilayers
Farhat, T. R., & Schlenoff, J. B. (2001) · Langmuir · doi:10.1021/la001298+ · Cited by 291
Self-citationPhase Behavior and Coacervation of Aqueous Poly(acrylic acid)−Poly(allylamine) Solutions
Chollakup, R., Smitthipong, W., Eisenbach, C. D., & Tirrell, M. (2010) · Macromolecules · doi:10.1021/ma902144k · Cited by 265
Formation of Micelles with Complex Coacervate Cores
Cohen Stuart, M. A., Besseling, N. A. M., & Fokkink, R. G. (1998) · Langmuir · doi:10.1021/la980778m · Cited by 234
Linear Viscoelasticity of Polyelectrolyte Complex Coacervates
Spruijt, E., Cohen Stuart, M. A., & van der Gucht, J. (2013) · Macromolecules · doi:10.1021/ma301730n · Cited by 222
Schlenoff, J. B., Rmaile, A. H., & Bucur, C. B. (2008) · Journal of the American Chemical Society · doi:10.1021/ja802054k · Cited by 205
Self-citationChollakup, R., Beck, J. B., Dirnberger, K., Tirrell, M., & Eisenbach, C. D. (2013) · Macromolecules · doi:10.1021/ma202172q · Cited by 197
A review of the early development of the thermodynamics of the complex coacervation phase separation
Veis, A. (2011) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2011.01.007 · Cited by 192
Kinetics and mechanism of interpolyelectrolyte exchange and addition reactions
Bakeev, K. N., Izumrudov, V. A., Kuchanov, S. I., Zezin, A. B., & Kabanov, V. A. (1992) · Macromolecules · doi:10.1021/ma00043a003 · Cited by 167
Linear viscoelasticity of complex coacervates
Liu, Y., Winter, H. H., & Perry, S. L. (2017) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2016.08.010 · Cited by 166
Optical Switching and Fluorescence Modulation in Photochromic Metal Complexes
Fernandez‐Acebes, A., & Lehn, J. (1998) · Advanced Materials · doi:10.1002/(sici)1521-4095(199812)10:18<1515::aid-adma1515>3.0.co;2-e · Cited by 148
Counteranion-Controlled Properties of Polyelectrolyte Multilayers
Salomäki, M., Laiho, T., & Kankare, J. J. (2004) · Macromolecules · doi:10.1021/ma048701u · Cited by 135
Hariri, H. H., Lehaf, A. M., & Schlenoff, J. B. (2012) · Macromolecules · doi:10.1021/ma302055m · Cited by 125
Self-citationReisch, A., Tirado, P., Roger, E., Boulmedais, F., Collin, D., Voegel, J., Frisch, B., Schaaf, P., & Schlenoff, J. B. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201201413 · Cited by 80
Self-citationReversibility and Relaxation Behavior of Polyelectrolyte Complex Micelle Formation
Lindhoud, S., Norde, W., & Stuart, M. A. C. (2009) · The Journal of Physical Chemistry B · doi:10.1021/jp809489f · Cited by 74
The Self-diffusion Coefficients of Potassium, Cesium, Iodide and Chloride Ions in Aqueous Solutions1
FRIEDMAN, A. M., & Kennedy, J. W. (1955) · Journal of the American Chemical Society · doi:10.1021/ja01622a016 · Cited by 54
Oikonomou, E. K., Bethani, A., Bokias, G., & Kallitsis, J. K. (2010) · European Polymer Journal · doi:10.1016/j.eurpolymj.2010.09.034 · Cited by 37
Dynamic Properties of Block Ionomer Complexes with Polyion Complex Cores
Li, Y., Bronich, T. K., Chelushkin, P. S., & Kabanov, A. V. (2008) · Macromolecules · doi:10.1021/ma702671w · Cited by 34
Cited by
Recent progress in the science of complex coacervation
Sing, C. E., & Perry, S. L. (2020) · Soft Matter · doi:10.1039/d0sm00001a · Cited by 676
Reversible generation of coacervate droplets in an enzymatic network
Nakashima, K. K., Baaij, J. F., & Spruijt, E. (2018) · Soft Matter · doi:10.1039/c7sm01897e · Cited by 194
Cakmak, F. P., Choi, S., Meyer, M. O., Bevilacqua, P. C., & Keating, C. D. (2020) · Nature Communications · doi:10.1038/s41467-020-19775-w · Cited by 185
Metadata
- Authors
- Fu, J., Fares, H. M., & Schlenoff, J. B.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-01-26
- Volume
- 50
- Issue
- 3
- Pages
- 1066-1074
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2581636885
- Cited by
- 288
- References
- 29
- FWCI
- 22.04
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
