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Recyclable and Malleable Epoxy Thermoset Bearing Aromatic Imine Bonds
Abstract
A method for preparing reprocessable epoxy thermoset is presented. The process is composed of synthesis of a bisphenol monomer bridged by an imine bond, glycidylation of the bisphenol, and cross-linking with a hardener to form thermoset. The resulting epoxy thermoset possesses comparable properties to conventional high-performance thermosets made from bisphenol A. However, when treated by a stimulus like acid, temperature, and/or water, the described thermoset exhibits reprocessability. Degradation and recycling involve hydrolysis and re-formation of imine bonds; reshaping and repairing of the thermoset are realized through imine exchange reactions. All the described processes require no metal catalyst, press heating, or additional monomer, which significantly widens thermoset reprocessing.
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Metadata
- Authors
- Zhao, S., & Abu-Omar, M. M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-11-27
- Volume
- 51
- Issue
- 23
- Pages
- 9816-9824
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2902863502
- Cited by
- 435
- References
- 52
- FWCI
- 10.83
- Type
- journal article
- Language
- en
- Open access
- closed
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