The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Ternary FexCo1–xP Nanowire Array as a Robust Hydrogen Evolution Reaction Electrocatalyst with Pt-like Activity: Experimental and Theoretical Insight
Abstract
Replacement of precious Pt with earth-abundant electrocatalysts for the hydrogen evolution reaction (HER) holds great promise for clean energy devices, but the development of low-cost and durable HER catalysts with Pt-like activity is still a huge challenge. In this communication, we report on the development of self-standing ternary Fe x Co 1– x P nanowire array on carbon cloth (Fe x Co 1– x P/CC) as a Pt-free HER catalyst with activities being strongly related to Fe substitution ratio. Electrochemical tests show that Fe 0.5 Co 0.5 P/CC not only possesses Pt-like activity with the need of overpotential of only 37 mV to drive 10 mA cm –2, outperforming all non-noble-metal HER catalysts reported to date, but demonstrates superior long-term durability in 0.5 M H 2 SO 4 . Density functional theory calculations further reveal that Fe substitution of Co in CoP leads to more optimal free energy of hydrogen adsorption to the catalyst surface. This study offers us a promising flexible monolithic catalyst for practical applications.
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Cites
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
Self-citationHighly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Liu, P., & Rodriguez, J. A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0540019 · Cited by 1,240
Kibsgaard, J., Tsai, C., Chan, K., Benck, J. D., Nørskov, J. K., Abild-Pedersen, F., & Jaramillo, T. F. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02179k · Cited by 979
Jiao, L., Zhou, Y.-X., & Jiang, H.-L. (2016) · Chemical Science · doi:10.1039/c5sc04425a · Cited by 798
Callejas, J. F., Read, C. G., Popczun, E. J., McEnaney, J. M., & Schaak, R. E. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b01284 · Cited by 509
Cited by
Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133
Anantharaj, S., Ede, S. R., Sakthikumar, K., Karthick, K., Mishra, S., & Kundu, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02479 · Cited by 2,503
Tang, T., Jiang, W.-J., Niu, S., Liu, N., Luo, H., Chen, Y.-Y., Jin, S.-F., Gao, F., Wan, L.-J., & Hu, J.-S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03507 · Cited by 880
CoP‐Doped MOF‐Based Electrocatalyst for pH‐Universal Hydrogen Evolution Reaction
Liu, T., Li, P., Yao, N., Cheng, G., Chen, S., Luo, W., & Yin, Y. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901409 · Cited by 606
Liu, T., Liu, D., Qu, F., Wang, D., Zhang, L., Ge, R., Hao, S., Ma, Y., Du, G., Asiri, A. M., et al. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700020 · Cited by 601
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Metadata
- Authors
- Tang, C., Gan, L., Zhang, R., Lu, W., Jiang, X., Asiri, A. M., Sun, X., Wang, J., & Chen, L.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-09-27
- Volume
- 16
- Issue
- 10
- Pages
- 6617-6621
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2524072602
- Cited by
- 671
- References
- 6
- FWCI
- 31.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tang, C., Gan, L., Zhang, R., Lu, W., Jiang, X., Asiri, A. M., Sun, X., Wang, J., & Chen, L. (2016). Ternary FexCo1–xP Nanowire Array as a Robust Hydrogen Evolution Reaction Electrocatalyst with Pt-like Activity: Experimental and Theoretical Insight. Nano Letters. https://doi.org/10.1021/acs.nanolett.6b03332
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