The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
Barriers of Electrochemical CO2 Reduction on Transition Metals
Abstract
Theoretical investigations of electrochemical CO 2 reduction have received increasing interest due its potential impact on renewable energy storage. We use density functional theory with an explicit solvent model of the electrochemical interface to calculate activation energy barriers for various proton–electron transfer elementary reactions steps for CO 2 reduction on Au, Cu, and Pt surfaces. We find the protonation of unhydrogenated oxygen to be trivial compared to the protonation of carbon and R–OH species, which induces C–O scission. Our revised free energy diagram for the reduction of CO 2 to methane on Cu(211) includes these observations and suggests that the dominant pathway includes *CHOH and *CH as intermediates rather than *OCH 3 .
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Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Self-citationHow copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Self-citationNew insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
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Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Self-citationElectrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Skúlason, E., Tripkovic, V., Björketun, M. E., Gudmundsdóttir, S., Karlberg, G., Rossmeisl, J., Bligaard, T., Jónsson, H., & Nørskov, J. K. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1048887 · Cited by 1,271
Self-citationTrends in electrochemical CO2 reduction activity for open and close-packed metal surfaces
Shi, C., Hansen, H. A., Lausche, A. C., & Nørskov, J. K. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp54822h · Cited by 465
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Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Self-citationAdvances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
Understanding trends in electrochemical carbon dioxide reduction rates
Liu, X., Xiao, J., Peng, H., Hong, X., Chan, K., & Nørskov, J. K. (2017) · Nature Communications · doi:10.1038/ncomms15438 · Cited by 804
Self-citationRecent advances in carbon dioxide utilization
Zhang, Z., Pan, S.-Y., Li, H., Cai, J., Olabi, A. G., Anthony, E. J., & Manovic, V. (2020) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2020.109799 · Cited by 732
Electric Field Effects in Electrochemical CO 2 Reduction
Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702
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Metadata
- Authors
- Shi, C., Chan, K., Yoo, J. S., & Nørskov, J. K.
- Venue
- Organic Process Research & Development
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-08
- Volume
- 20
- Issue
- 8
- Pages
- 1424-1430
- ISSN
- 1083-6160 (ISSN-L)
- 1520-586X
- OpenAlex
- W2525343124
- Cited by
- 184
- References
- 14
- FWCI
- 5.27
- Type
- journal article
- Language
- en
- Open access
- closed
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