The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Tuning Perovskite Morphology by Polymer Additive for High Efficiency Solar Cell
Abstract
Solution processable planar heterojunction perovskite solar cell is a very promising new technology for low cost renewable energy. One of the most common cell structures is FTO/TiO2/CH3NH3PbI3-xClx/spiro-OMeTAD/Au. The main issues of this type of solar cell are the poor coverage and morphology control of the perovskite CH3NH3PbI3-xClx film on TiO2. For the first time, we demonstrate that the problems can be easily resolved by using a polymer additive in perovskite precursor solution during the film formation process. A 25% increase in power conversion efficiency at a value of 13.2% is achieved by adding 1 wt % of poly(ethylene glycol) in the perovskite layer using a 150 °C processed TiO2 nanoparticle layer. The morphology of this new perovskite was carefully studied by SEM, XRD, and AFM. The results reveal that the additive controls the size and aggregation of perovskite crystals and helps the formation of smooth film over TiO2 completely. Thus, the Voc and Jsc are greatly increased for a high efficiency solar cell. The amount of additive is optimized at 1 wt % due to its insulating characteristics. This research provides a facile way to fabricate a high efficiency perovskite solar cell by the low temperature solution process (<150 °C), which has the advancement of conserving energy over the traditional high temperature sintering TiO2 compact layer device.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
Cited by
Kim, M., Kim, G.-H., Lee, T. K., Choi, I. W., Choi, H. W., Jo, Y., Yoon, Y. J., Kim, J. W., Lee, J., Huh, D., et al. (2019) · Joule · doi:10.1016/j.joule.2019.06.014 · Cited by 1,753
Han, T.-H., Lee, J.-W., Choi, C., Tan, S., Lee, C., Zhao, Y., Dai, Z., De Marco, N., Lee, S.-J., Bae, S.-H., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-08455-z · Cited by 588
Self-citationPlanar heterojunction organometal halide perovskite solar cells: roles of interfacial layers
Kim, H., Lim, K.-G., & Lee, T.-W. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02194d · Cited by 507
Device stability of perovskite solar cells – A review
Asghar, M. I., Zhang, J., Wang, H., & Lund, P. D. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.04.003 · Cited by 423
Controllable Perovskite Crystallization by Water Additive for High‐Performance Solar Cells
Gong, X., Li, M., Shi, X., Ma, H., Wang, Z., & Liao, L. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201503559 · Cited by 366
Metadata
- Authors
- Chang, C.-Y., Chu, C.-Y., Huang, Y.-C., Huang, C.-W., Chang, S.-Y., Chen, C.-A., Chao, C.-Y., & Su, W.-F.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-23
- Volume
- 7
- Issue
- 8
- Pages
- 4955-4961
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2323322674
- Cited by
- 325
- References
- 2
- FWCI
- 19.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chang, C.-Y., Chu, C.-Y., Huang, Y.-C., Huang, C.-W., Chang, S.-Y., Chen, C.-A., Chao, C.-Y., & Su, W.-F. (2015). Tuning Perovskite Morphology by Polymer Additive for High Efficiency Solar Cell. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.5b00052
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