The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Three-Dimensional Heterostructured NiCoP@NiMn-Layered Double Hydroxide Arrays Supported on Ni Foam as a Bifunctional Electrocatalyst for Overall Water Splitting
Abstract
Herein, the rational design and preparation of three-dimensional heterostructured NiCoP@NiMn-layered double hydroxide arrays supported on Ni foam (NiCoP@NiMn LDH/NF) is reported as a new bifunctional water-splitting electrocatalyst with high performance. Prepared with facile hydrothermal reactions and phosphorization, the NiCoP@NiMn LDH/NF is simultaneously highly active toward oxygen evolution reaction (OER) (100, 300, and 600 mA cm –2 at overpotentials of 293, 315, and 327 mV, respectively) and hydrogen evolution reaction (HER) (100, 200, and 300 mA cm –2 at overpotentials of 116, 130, and 136 mV, respectively). Interestingly, with cell voltages of 1.519, 1.642, 1.671, and 1.687 V at 10, 100, 200, and 300 mA cm –2, respectively, for overall water splitting, this electrocatalyst achieves 95.2% faradaic efficiency for OER, suggesting a relatively high contribution of water splitting in the apparent current in spite of the existence of partial catalyst oxidation. The heterostructure arrays supported on Ni foam have some advantages, acting as a bifunctional water-splitting electrocatalyst: (1) heterostructured NCoP@NiMn LDH combines the intrinsic properties of individual NiCoP (excellent activity for HER) and NiMn LDH (high activity for OER) via the effective interface engineering between the two phases; (2) the NiCoP core material serves as a fast electron transfer channel to enhance the electrode’s electrical conductivity; and (3) Ni foam with a three-dimensional-network structure as a support is beneficial to exposing more active sites and ensures efficient gas bubble release and electron/mass transfer.
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Cites
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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
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Plasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting
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Cited by
Xu, Q., Zhang, J., Zhang, H., Zhang, L., Chen, L., Hu, Y., Jiang, H., & Li, C. (2021) · Energy & Environmental Science · doi:10.1039/d1ee02105b · Cited by 469
Self-citationSahoo, D. P., Das, K. K., Mansingh, S., Sultana, S., & Parida, K. (2022) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214666 · Cited by 414
Riyajuddin, S., Azmi, K., Pahuja, M., Kumar, S., Maruyama, T., Bera, C., & Ghosh, K. (2021) · ACS Nano · doi:10.1021/acsnano.1c00647 · Cited by 353
Recent Progress on NiFe‐Based Electrocatalysts for the Oxygen Evolution Reaction
Zhao, J., Zhang, J., Li, Z., & Bu, X. (2020) · Small · doi:10.1002/smll.202003916 · Cited by 351
Riyajuddin, S., Pahuja, M., Sachdeva, P. K., Azmi, K., Kumar, S., Afshan, M., Ali, F., Sultana, J., Maruyama, T., Bera, C., et al. (2022) · ACS Nano · doi:10.1021/acsnano.2c00466 · Cited by 95
Metadata
- Authors
- Wang, P., Qi, J., Chen, X., Li, C., Li, W., Wang, T., & Liang, C.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-12-18
- Volume
- 12
- Issue
- 4
- Pages
- 4385-4395
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2996396872
- Cited by
- 176
- References
- 9
- FWCI
- 4.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, P., Qi, J., Chen, X., Li, C., Li, W., Wang, T., & Liang, C. (2020). Three-Dimensional Heterostructured NiCoP@NiMn-Layered Double Hydroxide Arrays Supported on Ni Foam as a Bifunctional Electrocatalyst for Overall Water Splitting. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.9b15208
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