Spillover in Heterogeneous Catalysis: New Insights and Opportunities
Abstract
Spillover is a well-known phenomenon in heterogeneous catalysis and is involved in many important reactions. The establishment of the spillover concept opened up a new research field for an in-depth understanding of the dynamic behavior of migrated species on a catalyst surface. However, a comprehensive understanding of spillover remains lacking. In recent years, the development of advanced characterization techniques in combination with well-controlled synthesis methodologies has provided us with increasing worthwhile information about spillover. This Review mainly describes recent progress on the characterization and mechanism of hydrogen spillover and how to effectively utilize the spillover effect for enhanced catalytic performance. Additionally, the challenges remaining in this research area are discussed, and possible research directions for the future are proposed.
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Adsorbed reaction intermediates in heterostructures can undergo spillover between adjacent components once a critical surface coverage is reached.
“adsorbed reaction intermediates in heterostructures can undergo spillover between adjacent components once a critical surface coverage is reached.16−18”
From High-Entropy Alloy Aerogels with High-Density Solid–Solid Heterointerfaces for Alkaline Hydrogen Evolution (2026) · cites this paper as [16]
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Flagged first, then by citations
Cited by
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- Authors
- Xiong, M., Gao, Z., & Qin, Y.
- Affiliations
- Chinese Academy of Sciences (CN)
- Corresponding author
- Gao, Zhe
- Qin, Yong
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-02-24
- Volume
- 11
- Issue
- 5
- Pages
- 3159-3172
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W3131303146
- Semantic Scholar
- dc5a86fee666997303c55fe9d207dd821843a4d0
- Cited by
- 454
- References
- 127
- Citations by year
- 2026: 112 · 2025: 105 · 2024: 78 · 2023: 81 · 2022: 65 · 2021: 13
- FWCI
- 18.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Catalysis (publishedVersion)
- Funders
- Ministry of Science and Technology of the People's Republic of China (2017YFA0700101)
- Natural Science Foundation of Shanxi Province (201801D211011)
- Youth Innovation Promotion Association of the Chinese Academy of Sciences (2018208)
- National Natural Science Foundation of China (21773282, 21825204, U1832208, U1932131)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- spillover effects, hydrogen spillover, heterogeneous catalysis, catalytic surfaces, species migration, spillover mechanism, catalyst characterization, catalytic performance enhancement
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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