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Cited by 237

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Sulfur and Nitrogen Dual-Doped Molybdenum Phosphide Nanocrystallites as an Active and Stable Hydrogen Evolution Reaction Electrocatalyst in Acidic and Alkaline Media

Anjum, Mohsin Ali Raza, Lee, Jae Sung·2017·ACS Catalysis

Abstract

Sulfur and nitrogen dual-doped molybdenum phosphides (MoP/SN) are synthesized via a (thio)urea-phosphate-assisted strategy in which the reductant (thio)urea acts as S and N source and phosphoric acid provides the P atom. The MoP/SN nanoparticles are generated by in situ phosphidation of indigenously synthesized ammonium phosphate-coated P-doped MoS x nanoparticles in a hydrogen atmosphere. Then, MoP/SN is anchored on graphene to obtain a hybrid electrocatalyst (MoP/SNG) that exhibits high activity and stability for electrochemical hydrogen evolution from water in both acidic and basic electrolytes, outperforming most MoP-based electrocatalysts reported in the literature. The dual doping and hybridization with graphene enhance electron conductivity of MoP and stabilize small MoP nanoparticles to increase activity and stability, especially in acid electrolytes.

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Metadata

Authors
Anjum, M. A. R., & Lee, J. S.
Venue
ACS Catalysis
Published
2017-03-29
Volume
7
Issue
4
Pages
3030-3038
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2596312462
Cited by
237
References
12
FWCI
8.61
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Sulfur and Nitrogen Dual-Doped Molybdenum Phosphide Nanocrystallites as an Active and Stable Hydrogen Evolution Reaction Electrocatalyst in Acidic and Alkaline Media. https://app.cochat.ai/papers/10.1021/acscatal.7b00555
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Anjum, M. A. R., & Lee, J. S. (2017). Sulfur and Nitrogen Dual-Doped Molybdenum Phosphide Nanocrystallites as an Active and Stable Hydrogen Evolution Reaction Electrocatalyst in Acidic and Alkaline Media. ACS Catalysis. https://doi.org/10.1021/acscatal.7b00555

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