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Cited by 236

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Prism-Shaped Cu Nanocatalysts for Electrochemical CO2 Reduction to Ethylene

Open access
Jeon, Hyo Sang, Kunze, Sebastian, Scholten, Fabian, Roldan Cuenya, Beatriz·2018·ACS Catalysis

Abstract

Electrochemical CO 2 reduction has attracted much attention, because of its advantageous ability to convert CO 2 gas to useful chemicals and fuels. Herein, we have developed prism-shaped Cu catalysts for efficient and stable CO 2 electroreduction by using an electrodeposition method. These Cu prism electrodes were characterized by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Electrochemical CO 2 reduction measurements show improved activities for C 2 H 4 production with a high partial current density of −11.8 mA/cm 2, which is over four times higher than that of the planar Cu sample (−2.8 mA/cm 2 ). We have demonstrated that the enhanced C 2 H 4 production is partially attributed to the higher density of defect sites available on the roughened Cu prism surface. Furthermore, stability tests show a drastic improvement in maintaining C 2 H 4 production over 12 h. The enhanced performance and durability of prism Cu catalysts hold promise for future industrial applications.

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Metadata

Authors
Jeon, H. S., Kunze, S., Scholten, F., & Roldan Cuenya, B.
Venue
ACS Catalysis
Published
2017-12-13
Volume
8
Issue
1
Pages
531-535
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2769548155
Cited by
236
References
9
FWCI
6.12
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Prism-Shaped Cu Nanocatalysts for Electrochemical CO2 Reduction to Ethylene. https://app.cochat.ai/papers/10.1021/acscatal.7b02959
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Jeon, H. S., Kunze, S., Scholten, F., & Roldan Cuenya, B. (2018). Prism-Shaped Cu Nanocatalysts for Electrochemical CO2 Reduction to Ethylene. ACS Catalysis. https://doi.org/10.1021/acscatal.7b02959

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