Electrocatalytic Production of C3‐C4 Compounds by Conversion of CO 2 on a Chloride‐Induced Bi‐Phasic Cu 2 O‐Cu Catalyst
Abstract
Electrocatalytic conversion of carbon dioxide (CO 2 ) has recently received considerable attention as one of the most feasible CO 2 utilization techniques. In particular, copper and copper‐derived catalysts have exhibited the ability to produce a number of organic molecules from CO 2 . Herein, we report a chloride (Cl)‐induced bi‐phasic cuprous oxide (Cu 2 O) and metallic copper (Cu) electrode (Cu 2 O Cl ) as an efficient catalyst for the formation of high‐carbon organic molecules by CO 2 conversion, and identify the origin of electroselectivity toward the formation of high‐carbon organic compounds. The Cu 2 O Cl electrocatalyst results in the preferential formation of multi‐carbon fuels, including n ‐propanol and n ‐butane C3–C4 compounds. We propose that the remarkable electrocatalytic conversion behavior is due to the favorable affinity between the reaction intermediates and the catalytic surface.
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Xu et al. found that the incorporation of Au not only stabilizes Cu nanoparticles, but also lowers the overpotential for CO2RR.
“In addition, Xu et al. found that the incorporation of Au not only stabilizes Cu nanoparticles, but also lowers the overpotential for CO2RR.[115]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [115]
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- Authors
- Lee, S., Kim, D., & Lee, J.
- Affiliations
- Gwangju Institute of Science and Technology (KR)
- Corresponding author
- Lee, Jaeyoung
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-10-16
- Volume
- 54
- Issue
- 49
- Pages
- 14701-14705
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2144904466
- Cited by
- 320
- References
- 40
- Citations by year
- 2026: 14 · 2025: 32 · 2024: 23 · 2023: 29 · 2022: 31 · 2021: 51 · 2020: 40 · 2019: 37 · 2018: 31 · 2017: 21 · 2016: 11
- FWCI
- 6.22
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Ministry of Education (NRF2013R1A1A2A10063010)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- copper oxide, cuprous oxide, 1-propanol, butane, reaction intermediates, copper catalysts
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