Cited by 320CO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisCatalysts for Methane Reforming

Electrocatalytic Production of C3‐C4 Compounds by Conversion of CO 2 on a Chloride‐Induced Bi‐Phasic Cu 2 O‐Cu Catalyst

Lee, Seunghwa, Kim, Dahee, Lee, Jaeyoung·2015·Angewandte Chemie International Edition

Abstract

Electrocatalytic conversion of carbon dioxide (CO 2 ) has recently received considerable attention as one of the most feasible CO 2 utilization techniques. In particular, copper and copper‐derived catalysts have exhibited the ability to produce a number of organic molecules from CO 2 . Herein, we report a chloride (Cl)‐induced bi‐phasic cuprous oxide (Cu 2 O) and metallic copper (Cu) electrode (Cu 2 O Cl ) as an efficient catalyst for the formation of high‐carbon organic molecules by CO 2 conversion, and identify the origin of electroselectivity toward the formation of high‐carbon organic compounds. The Cu 2 O Cl electrocatalyst results in the preferential formation of multi‐carbon fuels, including n ‐propanol and n ‐butane C3–C4 compounds. We propose that the remarkable electrocatalytic conversion behavior is due to the favorable affinity between the reaction intermediates and the catalytic surface.

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Crossref · 10.1002/anie.201505730

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Authors
Lee, S., Kim, D., & Lee, J.
Affiliations
Gwangju Institute of Science and Technology (KR)
Corresponding author
Lee, Jaeyoung
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2015-10-16
Volume
54
Issue
49
Pages
14701-14705
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2144904466
Cited by
320
References
40
Citations by year
2026: 14 · 2025: 32 · 2024: 23 · 2023: 29 · 2022: 31 · 2021: 51 · 2020: 40 · 2019: 37 · 2018: 31 · 2017: 21 · 2016: 11
FWCI
6.22
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Funders
Ministry of Education (NRF2013R1A1A2A10063010)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Keywords
copper oxide, cuprous oxide, 1-propanol, butane, reaction intermediates, copper catalysts

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