The Role of Adsorbed CN and Cl on an Au Electrode for Electrochemical CO2 Reduction
Abstract
Electrochemical CO 2 reduction is one of the promising ways to convert CO 2 to value-added products such as CO. Many studies have dealt with suppressing the hydrogen evolution reaction (HER) and increasing the CO 2 reduction reaction (CO 2 RR) through modification of the metal surface with additives such as anchoring agent, anion, etc. However, there are only a few studies about modifying the Au surface with additives. We present here a theoretical prediction that the addition of the CN and Cl species on an Au electrode would enhance the electrochemical CO 2 RR due to van der Waals interactions with these large anionic species. On the basis of this suggestion, we then prepared functionalized Au electrodes by electroplating in an aqueous solution containing CN – or Cl – and experimentally verified that the CO 2 RR of functionalized Au indeed shows exceptional CO 2 RR activity in comparison to pristine Au.
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OD Cu enhances CO2RR activity at lower overpotential.
“Similar to Au and Ag, a number of studies have explored the use of OD Cu for the enhancement of CO2RR activity at lower overpotential (Figure . 5C,D).[90,94,95]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [90]
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- Authors
- Cho, M., Song, J. T., Back, S., Jung, Y., & Oh, J.
- Affiliations
- Korea Advanced Institute of Science and Technology (KR)
- Corresponding author
- Jung, Yousung
- Oh, Jihun
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-01-16
- Volume
- 8
- Issue
- 2
- Pages
- 1178-1185
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2778166816
- Cited by
- 127
- References
- 56
- Citations by year
- 2026: 6 · 2025: 14 · 2024: 13 · 2023: 16 · 2022: 16 · 2021: 22 · 2020: 15 · 2019: 18 · 2018: 7
- FWCI
- 2.93
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Catalysis (publishedVersion)
- Funders
- National Research Foundation of Korea (2014R1A4A1003712, NRF-2014M1A8A1049303, NRF-2016M3D1A1021147)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, gold electrode, van der Waals interactions, surface functionalization, electroplating, hydrogen evolution suppression, anionic additives
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