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Catalytic Strategies for the Cycloaddition of Pure, Diluted, and Waste CO2 to Epoxides under Ambient Conditions

Shaikh, Rafik Rajjak, Pornpraprom, Suriyaporn, D’Elia, Valerio·2018·ACS Catalysis

Abstract

Cyclic organic carbonates represent a relevant class of chemicals that can be prepared from CO 2 by cycloaddition to epoxides. The application of efficient catalysts is crucial in allowing the cycloaddition reaction to proceed under very mild conditions of temperature, pressure, and CO 2 concentration, thus resulting in a sustainable and carbon-balanced approach to CO 2 conversion. This is particularly the case if impure waste CO 2 could be employed as a feedstock. In this Review, we have critically analyzed the burgeoning literature on the cycloaddition of CO 2 to epoxides with the aim to provide state-of-the-art knowledge on the catalysts that can convert CO 2 to carbonates under ambient conditions. These have been systematically organized in families of compounds and critically scrutinized in terms of catalytic activity, availability and mechanistic features. Finally, we provide an overview on the catalytic systems able to function using diluted and impure CO 2 as a feedstock.

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Metadata

Authors
Shaikh, R. R., Pornpraprom, S., & D’Elia, V.
Venue
ACS Catalysis
Published
2017-12-12
Volume
8
Issue
1
Pages
419-450
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2770577765
Cited by
729
References
6
FWCI
20.46
Type
journal article
Language
en
Open access
closed

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