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Cited by 339

The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.

Mixed-Node Metal–Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction

Zhao, Xiaohua, Pattengale, Brian, Fan, Donghua, Zou, Zehua, Zhao, Yongqing, Du, Jing, Huang, Jier, Xu, Cailing·2018·ACS Energy Letters

Abstract

Metal organic frameworks (MOFs), an emerging class of nanoporous crystalline materials, have become increasingly attractive for solar energy applications. In this work, we report a newly designed mixed-node MOF catalyst, Co x Fe 1– x -MOF-74 (0 < x ≤ 1), which acts as a highly efficient electrocatalyst for oxygen evolution reaction (OER) in alkaline solution with remarkably low overpotential (280 mV at a current density of 10 mA/cm 2 ), small Tafel slope (56 mV/dec), and high faradic efficiency (91%) and can deliver a current density of 20 mA/cm 2 at 1.58 V for overall water splitting. Moreover, using the combination of multiple spectroscopic methods, including X-ray absorption, electron spin resonance, and X-ray photoelectron spectroscopy, etc., we unraveled the mechanistic origin of the enhanced catalytic performance of Co x Fe 1– x -MOF-74 compared to its single-metal counterparts. We show the mixed-node MOF can provide more open metal sites and an enhanced electron-rich environment, which facilitates efficient charge transfer and results in significantly enhanced OER activity.

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  1. 10.1039/C6RA21320K · doi:10.1039/c6ra21320k
  2. 10.1039/C6CE00187D · doi:10.1039/c6ce00187d

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Metadata

Authors
Zhao, X., Pattengale, B., Fan, D., Zou, Z., Zhao, Y., Du, J., Huang, J., & Xu, C.
Venue
ACS Energy Letters
Published
2018-09-20
Volume
3
Issue
10
Pages
2520-2526
ISSN
2380-8195 (ISSN-L)
OpenAlex
W2889724802
Cited by
339
References
41
FWCI
8.26
Type
journal article
Language
en
Open access
closed
Funders
  • National Natural Science Foundation of China (21673105, 21701071, 21503102)
  • Gansu Province (17JR5RA194)

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CoChat. (2026). Citation check: Mixed-Node Metal–Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction. https://app.cochat.ai/papers/10.1021/acsenergylett.8b01540
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Zhao, X., Pattengale, B., Fan, D., Zou, Z., Zhao, Y., Du, J., Huang, J., & Xu, C. (2018). Mixed-Node Metal–Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b01540

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