The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Mixed-Node Metal–Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction
Abstract
Metal organic frameworks (MOFs), an emerging class of nanoporous crystalline materials, have become increasingly attractive for solar energy applications. In this work, we report a newly designed mixed-node MOF catalyst, Co x Fe 1– x -MOF-74 (0 < x ≤ 1), which acts as a highly efficient electrocatalyst for oxygen evolution reaction (OER) in alkaline solution with remarkably low overpotential (280 mV at a current density of 10 mA/cm 2 ), small Tafel slope (56 mV/dec), and high faradic efficiency (91%) and can deliver a current density of 20 mA/cm 2 at 1.58 V for overall water splitting. Moreover, using the combination of multiple spectroscopic methods, including X-ray absorption, electron spin resonance, and X-ray photoelectron spectroscopy, etc., we unraveled the mechanistic origin of the enhanced catalytic performance of Co x Fe 1– x -MOF-74 compared to its single-metal counterparts. We show the mixed-node MOF can provide more open metal sites and an enhanced electron-rich environment, which facilitates efficient charge transfer and results in significantly enhanced OER activity.
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Cites
The Chemistry and Applications of Metal-Organic Frameworks
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Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
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Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
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Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
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Research works printed but not linked: 2
- 10.1039/C6RA21320K · doi:10.1039/c6ra21320k
- 10.1039/C6CE00187D · doi:10.1039/c6ce00187d
Cited by
Metal–organic frameworks as a platform for clean energy applications
Li, X., Yang, X., Xue, H., Pang, H., & Xu, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100027 · Cited by 706
Metal–organic frameworks and their derivatives as electrocatalysts for the oxygen evolution reaction
Du, J., Li, F., & Sun, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01191f · Cited by 578
Self-citationThangavel, P., Ha, M., Kumaraguru, S., Meena, A., Singh, A. N., Harzandi, A. M., & Kim, K. S. (2020) · Energy & Environmental Science · doi:10.1039/d0ee00877j · Cited by 303
Optimized Metal Chalcogenides for Boosting Water Splitting
Yin, J., Jin, J., Lin, H., Yin, Z., Li, J., Lu, M., Guo, L., Xi, P., Tang, Y., & Yan, C. (2020) · Advanced Science · doi:10.1002/advs.201903070 · Cited by 292
Noufal, M., Puente Santiago, A. R., Tolba, S. A., Ahsan, M. A., Fernandez-Delgado, O., Shawky Adly, M., Hashem, E. M., Mahrous Abodouh, M., El-Shall, M. S., Sreenivasan, S. T., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c01096 · Cited by 282
Metadata
- Authors
- Zhao, X., Pattengale, B., Fan, D., Zou, Z., Zhao, Y., Du, J., Huang, J., & Xu, C.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-09-20
- Volume
- 3
- Issue
- 10
- Pages
- 2520-2526
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2889724802
- Cited by
- 339
- References
- 41
- FWCI
- 8.26
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- National Natural Science Foundation of China (21673105, 21701071, 21503102)
- Gansu Province (17JR5RA194)
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- Zhao, X., Pattengale, B., Fan, D., Zou, Z., Zhao, Y., Du, J., Huang, J., & Xu, C. (2018). Mixed-Node Metal–Organic Frameworks as Efficient Electrocatalysts for Oxygen Evolution Reaction. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b01540
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