The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Integration of Strong Electron Transporter Tetrathiafulvalene into Metalloporphyrin-Based Covalent Organic Framework for Highly Efficient Electroreduction of CO2
Abstract
Electroreduction of CO 2 (CO 2 RR) into value-added fuels is of significant importance but remains a big challenge because of poor selectivity, low current density, and large overpotential. Crystalline porous covalent organic frameworks (COFs) are promising alternative electrode materials for CO 2 RR owing to their tunable and accessible single active sites. However, the poor electron-transfer capability of COFs limits their application. Herein, a tetrathiafulvalene (TTF) strut was integrated into a two-dimensional cobalt porphyrin-based COF (TTF-Por(Co)-COF) to enhance its electron-transfer capability from the TTF to the porphyrin ring. Compared with COF-366-Co without TTF, TTF-Por(Co)-COF showed enhanced CO 2 RR performance in water with 95% Faradaic efficiency of the CO 2 -to-CO conversion at −0.7 V vs RHE and a partial current density of 6.88 mA cm –2 at −0.9 V vs RHE. This work provides a new insight for the rational design of porous organic framework materials for improving the activity of CO 2 RR.
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Cites
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Future CO 2 Emissions and Climate Change from Existing Energy Infrastructure
Davis, S. J., Caldeira, K., & Matthews, H. D. (2010) · Science · doi:10.1126/science.1188566 · Cited by 1,399
Domino electroreduction of CO2 to methanol on a molecular catalyst
Wu, Y., Jiang, Z., Lu, X., Liang, Y., & Wang, H. (2019) · Nature · doi:10.1038/s41586-019-1760-8 · Cited by 1,194
Tuning of CO2 Reduction Selectivity on Metal Electrocatalysts
Wang, Y., Liu, J., Wang, Y., Al‐Enizi, A. M., & Zheng, G. (2017) · Small · doi:10.1002/smll.201701809 · Cited by 241
Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Metadata
- Authors
- Wu, Q., Xie, R.-K., Mao, M.-J., Chai, G.-L., Yi, J.-D., Zhao, S.-S., Huang, Y.-B., & Cao, R.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-02-18
- Volume
- 5
- Issue
- 3
- Pages
- 1005-1012
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W3007500973
- Cited by
- 259
- References
- 5
- FWCI
- 8.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wu, Q., Xie, R.-K., Mao, M.-J., Chai, G.-L., Yi, J.-D., Zhao, S.-S., Huang, Y.-B., & Cao, R. (2020). Integration of Strong Electron Transporter Tetrathiafulvalene into Metalloporphyrin-Based Covalent Organic Framework for Highly Efficient Electroreduction of CO2. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.9b02756
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