Tuning of CO2 Reduction Selectivity on Metal Electrocatalysts
Abstract
Climate change, caused by heavy CO 2 emissions, is driving new demands to alleviate the rising concentration of atmospheric CO 2 levels. Enlightened by the photosynthesis of green plants, photo(electro)chemical catalysis of CO 2 reduction, also known as artificial photosynthesis, is emerged as a promising candidate to address these demands and is widely investigated during the past decade. Among various artificial photosynthetic systems, solar‐driven electrochemical CO 2 reduction is widely recognized to possess high efficiencies and potentials for practical application. The efficient and selective electroreduction of CO 2 is the key to the overall solar‐to‐chemical efficiency of artificial photosynthesis. Recent studies show that various metallic materials possess the capability to play as electrocatalysts for CO 2 reduction. In order to achieve high selectivity for CO 2 reduction products, various efforts are made including studies on electrolytes, crystal facets, oxide‐derived catalysts, electronic and geometric structures, nanostructures, and mesoscale phenomena. In this Review, these methods for tuning the selectivity of CO 2 electrochemical reduction of metallic catalysts are summarized. The challenges and perspectives in this field are also discussed.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Larger, less hydrated cations adsorb easier on the catalyst surface, making the potential at the outer Helmholtz plane more positive and thereby reducing the concentration of H+ ions and impeding the formation of H2 and CH4.
“The larger, less hydrated, cations adsorb easier on the catalyst surface making the potential at the outer Helmholtz plane more positive and thereby reducing the concentration of H + ions and impeding the formation of H2 and CH4.[205,209,211,212,214]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [211]
Larger cation concentrations can greatly reduce charge transfer resistances by helping to stabilize the *CO2- anion radical and leading to higher current densities at the same applied potentials.
“Moreover, larger cation concentrations can greatly reduce charge transfer resistances by helping to stabilize the *CO2 -anion radical and leading to higher current densities at the same applied potentials.[190,210,211]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [211]
Larger cations Cs+ and K+ can suppress the HER.
“suppress the HER, [205,211]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [211]
Cites
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784 · see citing works
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160 · see citing works
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990 · see citing works
Effect of Strain on the Reactivity of Metal Surfaces
Mavrikakis, M., Hammer, B., & Nørskov, J. K. (1998) · Physical Review Letters · doi:10.1103/physrevlett.81.2819 · Cited by 2,385 · see citing works
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140 · see citing works
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000 · see citing works
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000 · see citing works
A vacuum flash–assisted solution process for high-efficiency large-area perovskite solar cells
Li, X., Bi, D., Yi, C., Decoppet, J., Luo, J., Zakeeruddin, S. M., Hagfeldt, A., & Grätzel, M. (2016) · Science · doi:10.1126/science.aaf8060 · Cited by 1,910 · see citing works
Electrochemical CO2 Reduction on Metal Electrodes
Hori, Y. (2008) · Springer eBooks · doi:10.1007/978-0-387-49489-0_3 · Cited by 1,904 · see citing works
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865 · see citing works
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728 · see citing works
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
Chen, Y., Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309317u · Cited by 1,661 · see citing works
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649 · see citing works
Hori, Y., Murata, A., & Takahashi, R. (1989) · Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · doi:10.1039/f19898502309 · Cited by 1,644 · see citing works
Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement
Blankenship, R. E., Tiede, D. M., Barber, J., Brudvig, G. W., Fleming, G., Ghirardi, M., Gunner, M. R., Junge, W., Kramer, D. M., Melis, A., et al. (2011) · Science · doi:10.1126/science.1200165 · Cited by 1,638 · see citing works
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594 · see citing works
Self-citationIonic Liquid–Mediated Selective Conversion of CO <sub>2</sub> to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558 · see citing works
A selective and efficient electrocatalyst for carbon dioxide reduction
Lu, Q., Rosen, J., Zhou, Y., Hutchings, G. S., Kimmel, Y. C., Chen, J. G., & Jiao, F. (2014) · Nature Communications · doi:10.1038/ncomms4242 · Cited by 1,474 · see citing works
Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles
Reske, R., Mistry, H., Behafarid, F., Cuenya, B. R., & Strasser, P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500328k · Cited by 1,435 · see citing works
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO 2 to CO
Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,379 · see citing works
Kim, D., Resasco, J., Yu, Y., Asiri, A. M., & Yang, P. (2014) · Nature Communications · doi:10.1038/ncomms5948 · Cited by 1,374 · see citing works
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate
Zhang, S., Kang, P., & Meyer, T. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4113885 · Cited by 1,150 · see citing works
What is the maximum efficiency with which photosynthesis can convert solar energy into biomass?
Zhu, X.-G., Long, S. P., & Ort, D. R. (2008) · Current Opinion in Biotechnology · doi:10.1016/j.copbio.2008.02.004 · Cited by 1,145 · see citing works
Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles
Gao, D., Zhou, H., Wang, J., Miao, S., Yang, F., Wang, G., Wang, J., & Bao, X. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00046 · Cited by 1,096 · see citing works
Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction
Escudero-Escribano, M., Malacrida, P., Hansen, M. H., Vej-Hansen, U. G., Velázquez-Palenzuela, A., Tripkovic, V., Schiøtz, J., Rossmeisl, J., Stephens, I. E. L., & Chorkendorff, I. (2016) · Science · doi:10.1126/science.aad8892 · Cited by 1,057 · see citing works
Singh, M. R., Kwon, Y., Lum, Y., Ager, J. W., & Bell, A. T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07612 · Cited by 985 · see citing works
Water splitting–biosynthetic system with CO 2 reduction efficiencies exceeding photosynthesis
Liu, C., Colón, B. C., Ziesack, M., Silver, P. A., & Nocera, D. G. (2016) · Science · doi:10.1126/science.aaf5039 · Cited by 972 · see citing works
Schouten, K. J. P., Kwon, Y., van der Ham, C. J. M., Qin, Z., & Koper, M. T. M. (2011) · Chemical Science · doi:10.1039/c1sc00277e · Cited by 960 · see citing works
Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941 · see citing works
Ren, D., Deng, Y., Handoko, A. D., Chen, C. S., Malkhandi, S., & Yeo, B. S. (2015) · ACS Catalysis · doi:10.1021/cs502128q · Cited by 930 · see citing works
Selectivity of CO 2 Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps
Nie, X., Esopi, M. R., Janik, M. J., & Asthagiri, A. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201208320 · Cited by 927 · see citing works
Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid
Asadi, M., Kim, K., Liu, C., Addepalli, V. A., Abbasi, P., Yasaei, P., Phillips, P., Behranginia, A., Cerrato, J. M., Haasch, R. T., et al. (2016) · Science · doi:10.1126/science.aaf4767 · Cited by 903 · see citing works
Tailoring Copper Nanocrystals towards C2 Products in Electrochemical CO2 Reduction
Loiudice, A., Lobaccaro, P., Kamali, E. A., Thao, T., Huang, B. H., Ager, J. W., & Buonsanti, R. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201601582 · Cited by 896 · see citing works
Nanostructured electrocatalysts with tunable activity and selectivity
Mistry, H., Varela, A. S., Kühl, S., Strasser, P., & Cuenya, B. R. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.9 · Cited by 867 · see citing works
Active and Selective Conversion of CO <sub>2</sub> to CO on Ultrathin Au Nanowires
Zhu, W., Zhang, Y.-J., Zhang, H., Lv, H., Li, Q., Michalsky, R., Peterson, A. A., & Sun, S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5095099 · Cited by 860 · see citing works
Ma, S., Sadakiyo, M., Heima, M., Luo, R., Haasch, R. T., Gold, J. I., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b10740 · Cited by 855 · see citing works
Rausch, B., Symes, M. D., Chisholm, G., & Cronin, L. (2014) · Science · doi:10.1126/science.1257443 · Cited by 770 · see citing works
Direct and continuous strain control of catalysts with tunable battery electrode materials
Wang, H., Xu, S., Tsai, C., Li, Y., Liu, C., Zhao, J., Liu, Y., Yuan, H., Abild‐Pedersen, F., Prinz, F. B., et al. (2016) · Science · doi:10.1126/science.aaf7680 · Cited by 710 · see citing works
Shape-Dependent Electrocatalytic Reduction of CO2 to CO on Triangular Silver Nanoplates
Liu, S., Tao, H., Zeng, L., Liu, Q., Xu, Z., Liu, Q., & Luo, J. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12103 · Cited by 703 · see citing works
Kim, C., Jeon, H. S., Eom, T., Jee, M. S., Kim, H., Friend, C. M., Min, B. K., & Hwang, Y. J. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06568 · Cited by 702 · see citing works
Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction
Kumar, B., Asadi, M., Pisasale, D., Sinha‐Ray, S., Rosen, B. A., Haasch, R. T., Abiade, J. T., Yarin, A. L., & Salehi‐Khojin, A. (2013) · Nature Communications · doi:10.1038/ncomms3819 · Cited by 698 · see citing works
Grain-Boundary-Dependent CO <sub>2</sub> Electroreduction Activity
Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5130513 · Cited by 694 · see citing works
Mistry, H., Reske, R., Zeng, Z., Zhao, Z.-J., Greeley, J., Strasser, P., & Cuenya, B. R. (2014) · Journal of the American Chemical Society · doi:10.1021/ja508879j · Cited by 690 · see citing works
Huang, Y., Handoko, A. D., Hirunsit, P., & Yeo, B. S. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03147 · Cited by 689 · see citing works
Hori, Y., Takahashi, I., Koga, O., & Hoshi, N. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp013478d · Cited by 679 · see citing works
Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lü, G., Zhu, J., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00261 · Cited by 676 · see citing works
Lei, F., Liu, W., Sun, Y., Xu, J., Liu, K., Liang, L., Yao, T., Pan, B., Wei, S., & Xie, Y. (2016) · Nature Communications · doi:10.1038/ncomms12697 · Cited by 672 · see citing works
Wu, J., Ma, S., Sun, J., Gold, J. I., Tiwary, C., Kim, B., Zhu, L., Chopra, N., Odeh, I. N., Vajtai, R., et al. (2016) · Nature Communications · doi:10.1038/ncomms13869 · Cited by 658 · see citing works
Ligand effects in heterogeneous catalysis and electrochemistry
Bligaard, T., & Nørskov, J. K. (2007) · Electrochimica Acta · doi:10.1016/j.electacta.2007.02.041 · Cited by 633 · see citing works
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201608279 · Cited by 631 · see citing works
Enhancing CO2 Electroreduction with the Metal–Oxide Interface
Gao, D., Zhang, Y., Zhou, Z., Cai, F., Zhao, X., Huang, W., Li, Y., Zhu, J., Liu, P., Yang, F., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00102 · Cited by 610 · see citing works
Kaş, R., Kortlever, R., Milbrat, A., Koper, M. T. M., Mul, G., & Baltrušaitis, J. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp01520g · Cited by 550 · see citing works
Murata, A., & Hori, Y. (1991) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.64.123 · Cited by 544 · see citing works
Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530 · see citing works
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
Roberts, F. S., Kuhl, K. P., & Nilsson, A. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201412214 · Cited by 517 · see citing works
Rasul, S., Anjum, D. H., Jedidi, A., Minenkov, Y. V., Cavallo, L., & Takanabe, K. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201410233 · Cited by 514 · see citing works
Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide
Chen, L., Dong, X., Wang, Y., & Xia, Y. (2016) · Nature Communications · doi:10.1038/ncomms11741 · Cited by 514 · see citing works
Self-citationZhang, Y.-J., Sethuraman, V., Michalsky, R., & Peterson, A. A. (2014) · ACS Catalysis · doi:10.1021/cs5012298 · Cited by 509 · see citing works
Mesostructure-Induced Selectivity in CO2 Reduction Catalysis
Hall, A. S., Yoon, Y., Wuttig, A., & Surendranath, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08259 · Cited by 505 · see citing works
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts
Roberts, F. S., Kuhl, K. P., & Nilsson, A. (2015) · Angewandte Chemie · doi:10.1002/ange.201412214 · Cited by 491 · see citing works
One-step electrosynthesis of ethylene and ethanol from CO2 in an alkaline electrolyzer
Ma, S., Sadakiyo, M., Luo, R., Heima, M., Yamauchi, M., & Kenis, P. J. A. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.09.124 · Cited by 488 · see citing works
Azuma, M., Hashimoto, K., Hiramoto, M., Watanabe, M., & Sakata, T. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086796 · Cited by 482 · see citing works
Li, Y., Cui, F., Ross, M. B., Kim, D., Sun, Y., & Yang, P. (2017) · Nano Letters · doi:10.1021/acs.nanolett.6b05287 · Cited by 465 · see citing works
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00022 · Cited by 460 · see citing works
Kauffman, D. R., Alfonso, D. R., Matranga, C., Qian, H., & Jin, R. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303259q · Cited by 450 · see citing works
Kumar, B., Atla, V., Brian, J. P., Kumari, S., Nguyen, T. Q., Sunkara, M. K., & Spurgeon, J. M. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612194 · Cited by 450 · see citing works
Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO 2 Reduction
Rosen, J., Hutchings, G. S., Lu, Q., Forest, R. V., Moore, A. R., & Jiao, F. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00922 · Cited by 443 · see citing works
Amatore, C. A., & Savéant, J. M. (1981) · Journal of the American Chemical Society · doi:10.1021/ja00407a008 · Cited by 434 · see citing works
Singh, M. R., Clark, E. L., & Bell, A. T. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03283k · Cited by 416 · see citing works
Huang, H., Jia, H., Liu, Z., Gao, P., Zhao, J., Luo, Z., Yang, J., & Zeng, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612617 · Cited by 404 · see citing works
Ikeda, S., Takagi, T., & Ito, K. (1987) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.60.2517 · Cited by 371 · see citing works
Stable and selective electrochemical reduction of carbon dioxide to ethylene on copper mesocrystals
Chen, C. S., Handoko, A. D., Wan, J. H., Ma, L., Ren, D., & Yeo, B. S. (2014) · Catalysis Science & Technology · doi:10.1039/c4cy00906a · Cited by 348 · see citing works
Rational Design of Efficient Palladium Catalysts for Electroreduction of Carbon Dioxide to Formate
Klinkova, A., De Luna, P., Dinh, C.-T., Voznyy, O., Larin, E. M., Kumacheva, E., & Sargent, E. H. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01719 · Cited by 342 · see citing works
Controlling H + vs CO 2 Reduction Selectivity on Pb Electrodes
Lee, C. H., & Kanan, M. W. (2014) · ACS Catalysis · doi:10.1021/cs5017672 · Cited by 341 · see citing works
Electrolysis of CO<sub>2</sub> to Syngas in Bipolar Membrane-Based Electrochemical Cells
Li, Y. C., Zhou, D., Yan, Z., Gonçalves, R. H., Salvatore, D. A., Berlinguette, C. P., & Mallouk, T. E. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00475 · Cited by 313 · see citing works
Tuning of Silver Catalyst Mesostructure Promotes Selective Carbon Dioxide Conversion into Fuels
Yoon, Y., Hall, A. S., & Surendranath, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201607942 · Cited by 310 · see citing works
Electrochemical reduction of CO2 on single crystal electrodes of silver Ag(111), Ag(100) and Ag(110)
Hoshi, N., Kato, M., & Hori, Y. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00447-6 · Cited by 304 · see citing works
Modern Aspects of Electrochemistry
Conway, B. E., Bockris, J. O., & White, R. E. (1989) · Modern aspects of electrochemistry · doi:10.1007/978-1-4684-8667-4 · Cited by 296 · see citing works
Rosen, B. A., Haan, J. L., Mukherjee, P., Braunschweig, B., Zhu, W. D., Salehi‐Khojin, A., Dlott, D. D., & Masel, R. I. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp210542v · Cited by 270 · see citing works
Nanostructured Metallic Electrocatalysts for Carbon Dioxide Reduction
Lu, Q., Rosen, J., & Jiao, F. (2014) · ChemCatChem · doi:10.1002/cctc.201402669 · Cited by 269 · see citing works
Wang, Y., Chen, L., Yu, X., Wang, Y., & Zheng, G. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201601390 · Cited by 260 · see citing works
Self-citationCO 2 reduction: the quest for electrocatalytic materials
Khezri, B., Fisher, A. C., & Pumera, M. (2017) · Journal of Materials Chemistry A · doi:10.1039/c6ta09875d · Cited by 254 · see citing works
Medina-Ramos, J., Pupillo, R. C., Keane, T. P., DiMeglio, J. L., & Rosenthal, J. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5121088 · Cited by 246 · see citing works
Nanostructured nonprecious metal catalysts for electrochemical reduction of carbon dioxide
Wang, Z., Li, C., & Yamauchi, Y. (2016) · Nano Today · doi:10.1016/j.nantod.2016.05.007 · Cited by 236 · see citing works
Jia, F., Yu, X., & Zhang, L. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.12.002 · Cited by 228 · see citing works
Kim, D., Lee, S., Ocon, J. D., Jeong, B., Lee, J. K., & Lee, J. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp03172e · Cited by 223 · see citing works
Electrochemical Reduction of Carbon Dioxide at a Platinum Electrode in Acetonitrile-Water Mixtures
Tomita, Y., Teruya, S., Koga, O., & Hori, Y. (2000) · Journal of The Electrochemical Society · doi:10.1149/1.1394035 · Cited by 216 · see citing works
Handoko, A. D., Ong, C. W., Huang, Y., Lee, Z. G., Lin, L., Panetti, G. B., & Yeo, B. S. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b07128 · Cited by 209 · see citing works
High-Density Nanosharp Microstructures Enable Efficient CO 2 Electroreduction
Safaei, T. S., Mepham, A. H., Zheng, X. R., Pang, Y., Dinh, C., Liu, M., Sinton, D. A., Kelley, S. O., & Burdyny, T. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b03615 · Cited by 198 · see citing works
Electrochemical reduction of CO2 on platinum electrodes in acid solutions
Giner, J. (1963) · Electrochimica Acta · doi:10.1016/0013-4686(63)80054-7 · Cited by 197 · see citing works
Controlling Catalytic Selectivities during CO2 Electroreduction on Thin Cu Metal Overlayers
Reske, R., Duca, M., Oezaslan, M., Schouten, K. J. P., Koper, M. T. M., & Strasser, P. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz401087q · Cited by 187 · see citing works
Photosynthesis and Related Processes
RABINOWITCH, E. I. (1951) · Soil Science · doi:10.1097/00010694-195112000-00019 · Cited by 166 · see citing works
Tuning Catalytic Selectivity at the Mesoscale via Interparticle Interactions
Mistry, H., Behafarid, F., Reske, R., Varela, A. S., Strasser, P., & Cuenya, B. R. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b02202 · Cited by 163 · see citing works
High‐Throughput Synthesis of Mixed‐Metal Electrocatalysts for CO2 Reduction
He, J., Dettelbach, K. E., Salvatore, D. A., Li, T., & Berlinguette, C. P. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612038 · Cited by 161 · see citing works
Ambient-stable tetragonal phase in silver nanostructures
Sun, Y., Ren, Y., Liu, Y., Wen, J., Okasinski, J., & Miller, D. J. (2012) · Nature Communications · doi:10.1038/ncomms1963 · Cited by 152 · see citing works
Li Electrochemical Tuning of Metal Oxide for Highly Selective CO2 Reduction
Jiang, K. P., Wang, H., Cai, W., & Wang, H. (2017) · ACS Nano · doi:10.1021/acsnano.7b03029 · Cited by 147 · see citing works
Zhao, Y. S., Wang, C., & Wallace, G. G. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta04155h · Cited by 145 · see citing works
CO 2 Electroreduction on Well-Defined Bimetallic Surfaces: Cu Overlayers on Pt(111) and Pt(211)
Varela, A. S., Schlaup, C., Jovanov, Z. P., Malacrida, P., Horch, S., Stephens, I. E. L., & Chorkendorff, I. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp406913f · Cited by 136 · see citing works
Choi, S., Herron, J. A., Scaranto, J., Huang, H., Wang, Y., Xia, X., Lv, T., Park, J., Peng, H., Mavrikakis, M., et al. (2015) · ChemCatChem · doi:10.1002/cctc.201500094 · Cited by 135 · see citing works
Self-citationMesoscopic mass transport effects in electrocatalytic processes
Seidel, Y. E., Schneider, A., Jusys, Z., Wickman, B., Kasemo, B., & Behm, R. J. (2008) · Faraday Discussions · doi:10.1039/b806437g · Cited by 130 · see citing works
Wu, J., Sharma, P. P., Harris, B., & Zhou, X. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.02.014 · Cited by 128 · see citing works
Electrocatalytic reduction of carbon dioxide over reduced nanoporous zinc oxide
Jiang, X., Cai, F., Gao, D., Dong, J., Miao, S., Wang, G., & Bao, X. (2016) · Electrochemistry Communications · doi:10.1016/j.elecom.2016.05.003 · Cited by 122 · see citing works
Kyriacou, G., & Anagnostopoulos, A. (1993) · Journal of Applied Electrochemistry · doi:10.1007/bf00707626 · Cited by 119 · see citing works
Electrochemistry of carbon dioxide in dimethyl sulfoxide at gold and mercury electrodes
Haynes, L. V., & Sawyer, D. T. (1967) · Analytical Chemistry · doi:10.1021/ac60247a013 · Cited by 115 · see citing works
Ono, L. K., & Cuenya, B. R. (2007) · Catalysis Letters · doi:10.1007/s10562-007-9027-7 · Cited by 111 · see citing works
Probabilistic assessment of “dangerous” climate change and emissions pathways
Schneider, S. H., & Mastrandrea, M. D. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0506356102 · Cited by 105 · see citing works
Bumroongsakulsawat, P., & Kelsall, G. H. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2014.07.057 · Cited by 102 · see citing works
Wang, L., Zhao, S., Liu, C., Li, C., Li, X., Li, H., Wang, Y., Ma, C., Li, Z., & Zeng, J. (2015) · Nano Letters · doi:10.1021/nl5045132 · Cited by 98 · see citing works
Self-citationDefining dangerous anthropogenic interference
MANN, M. E. (2009) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0901303106 · Cited by 95 · see citing works
Some cathodic organic syntheses involving carbon dioxide
Tyssee, D. A., Wagenknecht, J. H., Baizer, M. M., & Chruma, J. L. (1972) · Tetrahedron Letters · doi:10.1016/s0040-4039(01)94435-1 · Cited by 88 · see citing works
Electrochemical Reduction of CO2at Cu Nanocluster / (1010) ZnO Electrodes
Andrews, E. M., Ren, M., Wang, F., Zhang, Z., Sprunger, P. T., Kurtz, R. L., & Flake, J. C. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.105311jes · Cited by 85 · see citing works
Structural effect on the rate of CO2 reduction on single crystal electrodes of palladium
Hoshi, N., Noma, M., Suzuki, T., & Hori, Y. (1997) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(96)01023-6 · Cited by 83 · see citing works
Electrochemical reduction of carbon dioxide on hydrogenstoring materials
Ohkawa, K., Hashimoto, K., Fujishima, A., Noguchi, Y., & Nakayama, S. (1993) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(93)80495-4 · Cited by 82 · see citing works
Friebel, D., Mbuga, F., Rajasekaran, S., Miller, D. J., Ogasawara, H., Alonso‐Mori, R., Sokaras, D., Nordlund, D. L., Weng, T., & Nilsson, A. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp412000j · Cited by 82 · see citing works
Electrochemical Reduction of CO2 with High Current Density in a CO2-Methanol Medium
Saeki, T., Hashimoto, K., Fujishima, A., Kimura, N., & Omata, K. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100020a083 · Cited by 76 · see citing works
CO2 Electroreduction on Au/TiC: Enhanced Activity Due to Metal–Support Interaction
Kim, J., Woo, H., Choi, J., Jung, H.-W., & Kim, Y. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03706 · Cited by 76 · see citing works
Saeki, T., Hashimoto, K., Kimura, N., Omata, K., & Fujishima, A. (1996) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)04374-8 · Cited by 71 · see citing works
Kyriacou, D., & Jahngen, E. G. E. (1993) · Journal of Applied Electrochemistry · doi:10.1007/bf00625595 · Cited by 69 · see citing works
Electrochemical reduction of carbon dioxide in methanol at low temperature
Naitoh, A., Ohta, K., Mizuno, T., Yoshida, H., Sakai, M., & Noda, H. (1993) · Electrochimica Acta · doi:10.1016/0013-4686(93)80095-h · Cited by 65 · see citing works
Electrochemical reduction of CO2 on Au in KOH + methanol at low temperature
Kaneco, S., Iiba, K., Ohta, K., Mizuno, T., & Saji, A. (1998) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(97)00438-5 · Cited by 62 · see citing works
Electrochemical reduction of carbon dioxide in methanol at ambient temperature and pressure
Ohta, K., Kawamoto, M., Mizuno, T., & Löwy, D. A. (1998) · Journal of Applied Electrochemistry · doi:10.1023/a:1003298212137 · Cited by 51 · see citing works
Ohkawa, K., Noguchi, Y., Nakayama, S., Hashimoto, K., & Fujishima, A. (1994) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(94)87105-1 · Cited by 23 · see citing works
Electrochemical reduction of CO2 on hydrogen-enriched and hydrogen-depleted surfaces
Yoshitake, H., Takahashi, K., & Ota, K. (1994) · Journal of the Chemical Society Faraday Transactions · doi:10.1039/ft9949000155 · Cited by 19 · see citing works
Yoshitake, H., Kikkawa, T., & Ota, K. (1995) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(95)03948-g · Cited by 10 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331 · see citing works
Product selectivity of photocatalytic CO2 reduction reactions
Fu, J., Jiang, K., Qiu, X., Yu, J., & Liu, M. (2019) · Materials Today · doi:10.1016/j.mattod.2019.06.009 · Cited by 1,282 · see citing works
Vasileff, A., Xu, C., Jiao, Y., Zheng, Y., & Qiao, S. (2018) · Chem · doi:10.1016/j.chempr.2018.05.001 · Cited by 902 · see citing works
Goyal, A., Marcandalli, G., Mints, V. A., & Koper, M. T. M. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b10061 · Cited by 647 · see citing works
Multifunctional Transition Metal‐Based Phosphides in Energy‐Related Electrocatalysis
Li, Y., Dong, Z., & Jiao, L. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902104 · Cited by 603 · see citing works
Recent Advances in Electrochemical CO 2 ‐to‐CO Conversion on Heterogeneous Catalysts
Zheng, T., Jiang, K., & Wang, H. (2018) · Advanced Materials · doi:10.1002/adma.201802066 · Cited by 582 · see citing works
Defect engineering in earth-abundant electrocatalysts for CO 2 and N 2 reduction
Wang, Q., Lei, Y., Wang, D. S., & Li, Y. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03781g · Cited by 573 · see citing works
Cu-based nanocatalysts for electrochemical reduction of CO2
Xie, H., Wang, T., Liang, J., Li, Q., & Sun, S. (2018) · Nano Today · doi:10.1016/j.nantod.2018.05.001 · Cited by 562 · see citing works
Wang, Y., Wang, Z., Dinh, C., Li, J., Ozden, A., Kibria, M. G., Seifitokaldani, A., Tan, C., Gabardo, C. M., Luo, M., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0397-1 · Cited by 559 · see citing works
Self-citationGarg, S., Li, M., Weber, A. Z., Ge, L., Li, L., Rudolph, V., Wang, G., & Rufford, T. E. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta13298h · Cited by 482 · see citing works
Highly Efficient CO 2 Electroreduction on ZnN 4 ‐based Single‐Atom Catalyst
Fa, Y., Song, P., Liu, X., Mei, B., Xing, W., Jiang, Z. R., Gu, L., & Xu, W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201805871 · Cited by 456 · see citing works
Ringe, S., Morales‐Guio, C. G., Chen, L. D., Fields, M. G., Jaramillo, T. F., Hahn, C., & Chan, K. (2020) · Nature Communications · doi:10.1038/s41467-019-13777-z · Cited by 376 · see citing works
Yang, Y., Luo, M., Zhang, W., Sun, Y., Xu, C., & Guo, S. (2018) · Chem · doi:10.1016/j.chempr.2018.05.019 · Cited by 351 · see citing works
Designing Copper‐Based Catalysts for Efficient Carbon Dioxide Electroreduction
Wang, Y., Liu, J., & Zheng, G. (2021) · Advanced Materials · doi:10.1002/adma.202005798 · Cited by 351 · see citing works
Self-citationDesign of Local Atomic Environments in Single‐Atom Electrocatalysts for Renewable Energy Conversions
Sun, T., Mitchell, S. J., Li, J., Lyu, P., Wu, X., Pérez‐Ramírez, J., & Lu, J. (2020) · Advanced Materials · doi:10.1002/adma.202003075 · Cited by 338 · see citing works
One-Dimensional Metal Nanostructures: From Colloidal Syntheses to Applications
Huo, D., Kim, M. J., Lyu, Z., Shi, Y., Wiley, B. J., & Younan Xia, A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00745 · Cited by 335 · see citing works
Guo, J., Huo, J., Liu, Y., Wu, W., Wang, Y., Wu, M., Liu, H., & Wang, G. (2019) · Small Methods · doi:10.1002/smtd.201900159 · Cited by 325 · see citing works
Self-citationRecent advances in understanding Li–CO 2 electrochemistry
Liu, B., Sun, Y., Liu, L., Chen, J., Yang, B., Xu, S., & Yan, X. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03417f · Cited by 315 · see citing works
Pu, Z., Amiinu, I. S., Cheng, R., Wang, P., Zhang, C., Mu, S. C., Zhao, W., Su, F., Zhang, G., Liao, S., et al. (2020) · Nano-Micro Letters · doi:10.1007/s40820-019-0349-y · Cited by 290 · see citing works
Su, J., Ge, R., Yan, D., Fei, H., & Chen, L. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta04064h · Cited by 286 · see citing works
Advances in Sn-Based Catalysts for Electrochemical CO2 Reduction
Zhao, S., Li, S., Guo, T., Zhang, S., Wang, J., Wu, Y., & Chen, Y. (2019) · Nano-Micro Letters · doi:10.1007/s40820-019-0293-x · Cited by 276 · see citing works
Wu, Q., Xie, R., Mao, M., Chai, G., Yi, J., Zhao, S., Huang, Y., & Cao, R. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.9b02756 · Cited by 258 · see citing works
Tan, X., Yu, C., Zhao, C., Huang, H., Yao, X., Han, X., Guo, W., Cui, S., Huang, H., & Qiu, J. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b19111 · Cited by 245 · see citing works
Electrochemical CO2reduction to C2+products using Cu-based electrocatalysts: A review
Ahmad, T., Liu, S., Sajid, M., Li, K., Ali, M., Liu, L., & Chen, W. (2022) · Nano Research Energy · doi:10.26599/nre.2022.9120021 · Cited by 224 · see citing works
Efficient electrochemical reduction of CO2 into CO promoted by sulfur vacancies
Qin, B., Li, Y., Wang, H., Yang, G., Cao, Y., Yu, H., Zhang, Q., Liang, H., & Peng, F. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.03.024 · Cited by 205 · see citing works
Li, J., Pršlja, P., Shinagawa, T., Martín, A. J., Krumeich, F., Artyushkova, K., Atanassov, P. B., Zitolo, A., Zhou, Y., García‐Muelas, R., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02594 · Cited by 197 · see citing works
Towards highly efficient electrochemical CO2 reduction: Cell designs, membranes and electrocatalysts
Tufa, R. A., Chanda, D., Ma, M., Aili, D., Demissie, T. B., Vaes, J., Li, Q., Liu, S., & Pant, D. (2020) · Applied Energy · doi:10.1016/j.apenergy.2020.115557 · Cited by 191 · see citing works
Nanostructured Copper‐Based Electrocatalysts for CO 2 Reduction
Gu, Z., Shen, H. F., Shang, L., Lv, X., Qian, L., & Zheng, G. (2018) · Small Methods · doi:10.1002/smtd.201800121 · Cited by 188 · see citing works
Self-citationP-block metal-based (Sn, In, Bi, Pb) electrocatalysts for selective reduction of CO2 to formate
Yang, Z., Oropeza, F. E., & Zhang, K. H. L. (2020) · APL Materials · doi:10.1063/5.0004194 · Cited by 188 · see citing works
Size‐Dependent Nickel‐Based Electrocatalysts for Selective CO2 Reduction
Li, Z., He, D., Yan, X., Dai, S., Younan, S. M., Ke, Z., Pan, X. Q., Xiao, X., Wu, H., & Gu, J. H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202000318 · Cited by 187 · see citing works
Qin, B., Li, Y., Fu, H., Wang, H., Chen, S., Liu, Z., & Peng, F. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b04809 · Cited by 185 · see citing works
Wang, Z., Zhou, Y., Xia, C., Guo, W., You, B., & Xia, B. Y. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202107523 · Cited by 184 · see citing works
Daiyan, R., Saputera, W. H., Masood, H., Leverett, J., Lu, X., & Amal, R. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902106 · Cited by 172 · see citing works
Guo, C., Guo, Y., Shi, Y., Lan, X., Wang, Y., Yu, Y., & Zhang, B. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202205909 · Cited by 166 · see citing works
Self-citationXie, H., Zhang, T., Xie, R., Hou, Z., Ji, X., Pang, Y., Chen, S., Titirici, M., Weng, H., & Chai, G. (2021) · Advanced Materials · doi:10.1002/adma.202008373 · Cited by 165 · see citing works
Catalysts in electro-, photo- and photoelectrocatalytic CO2 reduction reactions
Wang, Y., He, D., Chen, H., & Wang, D. (2019) · Journal of Photochemistry and Photobiology C Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2019.02.002 · Cited by 164 · see citing works
Self-citationRecent Progress in Electrocatalytic Methanation of CO 2 at Ambient Conditions
Zhao, R., Ding, P., Wei, P., Zhang, L., Liu, Q., Luo, Y., Li, T., Lu, S., Shi, X., Gao, S., et al. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202009449 · Cited by 163 · see citing works
Wu, Q., Mao, M., Wu, Q., Liang, J., Huang, Y., & Cao, R. (2020) · Small · doi:10.1002/smll.202004933 · Cited by 162 · see citing works
Hu, C., Bai, S., Gao, L., Liang, S., Yang, J., Cheng, S., Mi, S., & Qiu, J. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b03175 · Cited by 157 · see citing works
Ma, L., Hu, W., Mei, B., Liu, H., Yuan, B., Zang, J., Chen, T., Zou, L., Zou, Z., Yang, B., et al. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c00243 · Cited by 155 · see citing works
MOFs‐Derived Carbon‐Based Metal Catalysts for Energy‐Related Electrocatalysis
Wang, T., Cao, X., & Jiao, L. (2021) · Small · doi:10.1002/smll.202004398 · Cited by 151 · see citing works
Photoelectrocatalytic carbon dioxide reduction: Fundamental, advances and challenges
Chen, P., Zhang, Y., Zhou, Y., & Dong, F. (2021) · Nano Materials Science · doi:10.1016/j.nanoms.2021.05.003 · Cited by 147 · see citing works
Duarah, P., Haldar, D., Yadav, V., & Purkait, M. K. (2021) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2021.106394 · Cited by 145 · see citing works
Ma, D.-D., & Zhu, Q. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213483 · Cited by 142 · see citing works
Recent progress on hybrid electrocatalysts for efficient electrochemical CO2 reduction
Zhang, B., Jiang, Y., Gao, M., Ma, T., Sun, W., & Pan, H. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.105504 · Cited by 139 · see citing works
Directing the reactivity of metal hydrides for selective CO 2 reduction
Ceballos, B. M., & Yang, J. Y. (2018) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1811396115 · Cited by 133 · see citing works
CO2 transformation to multicarbon products by photocatalysis and electrocatalysis
Du, C., Wang, X., Chen, W., Feng, S., Wen, J. Z., & Wu, Y. A. (2020) · Materials Today Advances · doi:10.1016/j.mtadv.2020.100071 · Cited by 127 · see citing works
Heterogeneous catalysts for catalytic CO2 conversion into value-added chemicals
Whang, H. S., Lim, J., Choi, M. S., Lee, J., & Lee, H. (2019) · BMC Chemical Engineering · doi:10.1186/s42480-019-0007-7 · Cited by 119 · see citing works
Carbon-based single-atom catalysts for CO 2 electroreduction: progress and optimization strategies
Lu, X., Rong, X., Zhang, C., & Lu, T. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta01955k · Cited by 118 · see citing works
Electrochemical reduction of carbon dioxide (CO 2 ): bismuth-based electrocatalysts
Guan, Y., Liu, M., Rao, X., Liu, Y., & Zhang, J. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta01516h · Cited by 116 · see citing works
Electronic Tuning of Co, Ni‐Based Nanostructured (Hydr)oxides for Aqueous Electrocatalysis
Kuang, M., Han, P., Huang, L., Cao, N., Qian, L., & Zheng, G. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201804886 · Cited by 110 · see citing works
Self-citationWang, X., Hu, Q. L., Li, G., Yang, H., & He, C. (2022) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00171-5 · Cited by 108 · see citing works
Mechanistic View of the Main Current Issues in Photocatalytic CO2 Reduction
Fresno, F., Villar‐García, I. J., Collado, L., Alfonso‐González, E., Reñones, P., Barawi, M., & O’Shea, V. A. D. L. P. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b02336 · Cited by 104 · see citing works
A porous Zn cathode for Li–CO 2 batteries generating fuel-gas CO
Xie, J., Liu, Q., Huang, Y., Wu, M., & Wang, Y. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta02771d · Cited by 102 · see citing works
Self-citationDaele, K. V., Mot, B. D., Pupo, M. M. D. S., Daems, N., Pant, D., Kortlever, R., & Breugelmans, T. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c02049 · Cited by 101 · see citing works
Highly Efficient CO2 Electroreduction on ZnN4‐based Single‐Atom Catalyst
Fa, Y., Song, P., Liu, X., Mei, B., Xing, W., Jiang, Z. R., Gu, L., & Xu, W. (2018) · Angewandte Chemie · doi:10.1002/ange.201805871 · Cited by 101 · see citing works
Ni, Z., Liang, H., Yi, Z., Guo, R., Liu, C., Liu, Y., Sun, H., & Liu, X. (2021) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2021.213983 · Cited by 93 · see citing works
Li, H., Wen, P., Itanze, D. S., Hood, Z. D., Ma, X., Kim, M., Adhikari, S. P., Lu, C. H., Dun, C., Chi, M., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-13388-8 · Cited by 85 · see citing works
RetractedPhotoelectrocatalytic Reduction of CO 2 to Syngas via SnO x ‐Enhanced Cu 2 O Nanowires Photocathodes
Zhang, Y., Pan, D., Tao, Y., Shang, H., Zhang, D., Li, G., & Li, H. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202109600 · Cited by 80 · see citing works
Carbon dioxide photo/electroreduction with cobalt
Li, C., Tong, X., Yu, P., Du, W., Wu, J., Rao, H., & Wang, Z. M. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta03892b · Cited by 78 · see citing works
Fundamentals, On-Going Advances and Challenges of Electrochemical Carbon Dioxide Reduction
Kou, Z., Li, X., Wang, T., Ma, Y., Zang, W., Nie, G., & Wang, J. (2021) · Electrochemical Energy Reviews · doi:10.1007/s41918-021-00096-5 · Cited by 74 · see citing works
Highly selective electrocatalytic reduction of CO2 to formate over Tin(IV) sulfide monolayers
He, J., Liu, X., Liu, H., Zhao, Z., Ding, Y., & Luo, J. (2018) · Journal of Catalysis · doi:10.1016/j.jcat.2018.05.005 · Cited by 73 · see citing works
Selective carbon dioxide electroreduction to ethylene and ethanol by core-shell copper/cuprous oxide
Shang, L., Lv, X., Shen, H. F., Shao, Z., & Zheng, G. (2019) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2019.05.073 · Cited by 72 · see citing works
Self-citationReview on Long-Term Stability of Electrochemical CO2 Reduction
Álvarez-Gómez, J. M., & Varela, A. S. (2023) · Energy & Fuels · doi:10.1021/acs.energyfuels.3c01847 · Cited by 72 · see citing works
Electrochemical CO 2 Reduction: Commercial Innovations and Prospects
Varhade, S., Guruji, A., Singh, C., Cicero, G., Melchor, M. G., Helsen, J., & Pant, D. (2024) · ChemElectroChem · doi:10.1002/celc.202400512 · Cited by 72 · see citing works
Engstfeld, A. K., Maagaard, T., Horch, S., Chorkendorff, I., & Stephens, I. E. L. (2018) · Chemistry - A European Journal · doi:10.1002/chem.201803418 · Cited by 70 · see citing works
Bismuth-based Z-scheme structure for photocatalytic CO2 reduction: A review
Hu, X., Guo, R., Chen, X., Bi, Z., Wang, J., & Pan, W. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.108582 · Cited by 69 · see citing works
Blau, S. M., Patel, H. D., Spotte‐Smith, E. W. C., Xie, X., Dwaraknath, S., & Persson, K. A. (2021) · Chemical Science · doi:10.1039/d0sc05647b · Cited by 68 · see citing works
Valorizing carbon dioxide via electrochemical reduction on gas‐diffusion electrodes
Luo, Y., Zhang, K., Li, Y., & Wang, Y. (2021) · InfoMat · doi:10.1002/inf2.12253 · Cited by 68 · see citing works
Self-citationSelective Electroreduction of CO2 to C2 Products over Cu3N‐Derived Cu Nanowires
Mi, Y., Shen, S., Peng, X., Bao, H., Liu, X., & Luo, J. (2019) · ChemElectroChem · doi:10.1002/celc.201801826 · Cited by 68 · see citing works
Recent progress in electrochemical reduction of CO2 by oxide-derived copper catalysts
Wang, S., Kou, T., Baker, S. E., Duoss, E. B., & Li, Y. (2020) · Materials Today Nano · doi:10.1016/j.mtnano.2020.100096 · Cited by 66 · see citing works
Recent progress in structural modulation of metal nanomaterials for electrocatalytic CO 2 reduction
Yang, C., Nosheen, F., & Zhang, Z. (2020) · Rare Metals · doi:10.1007/s12598-020-01600-4 · Cited by 66 · see citing works
Synthesis and Applications of Nanostructured Hollow Transition Metal Chalcogenides
Dai, M., & Wang, R. (2021) · Small · doi:10.1002/smll.202006813 · Cited by 66 · see citing works
Ye, J., Gu, W., Hu, J. R., Chen, L., Yang, C., Gao, J., & Zhou, S. (2025) · Chemical Reviews · doi:10.1021/acs.chemrev.5c00658 · Cited by 66 · see citing works
Formation of 1-Butanol from CO2 without *CO Dimerization on a Phosphorus-Rich Copper Cathode
Choi, M., Bong, S., Kim, J. W., & Lee, J. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c00723 · Cited by 65 · see citing works
Wang, Z., Shi, Y., Liu, C., Kang, Y., & Wu, L. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120803 · Cited by 65 · see citing works
Electrochemical reduction of carbon dioxide into valuable chemicals: a review
Farooqi, S. A., Farooqi, A. S., Sajjad, S., Yan, C., & Victor, A. B. (2023) · Environmental Chemistry Letters · doi:10.1007/s10311-023-01565-7 · Cited by 65 · see citing works
Nguyen, V., Cho, K., Choi, Y., Hwang, B. W., Park, Y., Nam, H., & Lee, D. (2024) · Biochar · doi:10.1007/s42773-024-00388-1 · Cited by 63 · see citing works
Lu, X., Yu, T., Wang, H., Qian, L., & Lei, P. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c00627 · Cited by 63 · see citing works
Single Entity Electrocatalysis
Clarke, T. B., Krushinski, L. E., Vannoy, K. J., Colón-Quintana, G. S., Roy, K., Rana, A., Renault, C., Hill, M. L., & Dick, J. E. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00723 · Cited by 62 · see citing works
Yang, C., Shen, H., Guan, A., Liu, J., Li, T., Ji, Y., Al‐Enizi, A. M., Zhang, L., Qian, L., & Zheng, G. (2020) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2020.03.017 · Cited by 60 · see citing works
Self-citationCao, S.-M., Chen, H.-B., Dong, B., Zheng, Q.-H., Ding, Y.-X., Liu, M., Qian, S.-L., Teng, Y., Li, Z., & Liu, W. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.06.038 · Cited by 59 · see citing works
Goyal, A., Bondue, C. J., Graf, M., & Koper, M. T. M. (2022) · Chemical Science · doi:10.1039/d1sc05743j · Cited by 59 · see citing works
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries
Hu, F., Abeyweera, S. C., Yu, J., Zhang, D., Wang, Y., Yan, Q., & Sun, Y. (2020) · Chem · doi:10.1016/j.chempr.2020.07.026 · Cited by 58 · see citing works
Self-citationChen, Y., Zhang, J., Yang, L., Wang, X., Wu, Q., & Hu, Z. (2022) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00156-4 · Cited by 55 · see citing works
Understanding mass transport influenced electrocatalysis at the nanoscale via numerical simulation
Lin, C., & Compton, R. G. (2018) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2018.08.001 · Cited by 55 · see citing works
Wang, X., Lv, J., Zhang, J., Wang, X., Xue, C., Bian, G., Li, D., Wang, Y., & Wu, T. (2019) · Nanoscale · doi:10.1039/c9nr08726e · Cited by 55 · see citing works
Self-citationAbdelkader-Fernández, V. K., Fernandes, D. M., & Freire, C. (2020) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2020.101350 · Cited by 55 · see citing works
Photoelectrochemical CO2 electrolyzers: From photoelectrode fabrication to reactor configuration
Abarca, J. A., Díaz‐Sainz, G., Merino‐Garcia, I., Irabien, Á., & Albo, J. (2023) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2023.06.032 · Cited by 54 · see citing works
Stable Surface-Anchored Cu Nanocubes for CO2 Electroreduction to Ethylene
Kuang, S., Li, M., Xia, R., Xing, L., Su, Y., Fan, Q., Liu, J., Hensen, E. J. M., Ma, X., & Zhang, S. (2020) · ACS Applied Nano Materials · doi:10.1021/acsanm.0c01745 · Cited by 54 · see citing works
Self-citationLiu, K., Cao, P., Chen, W., Ezeh, C. I., Chen, Z., Luo, Y., Liu, Q., Zhao, H., Rui, Z., Gao, S., et al. (2021) · Materials Advances · doi:10.1039/d1ma00814e · Cited by 53 · see citing works
Coupling Atomically Dispersed Fe–N5 Sites with Defective N‐Doped Carbon Boosts CO2 Electroreduction
Zhao, L., Jiang, J., Liu, X., Zhu, Z., Wang, J., He, Q., Kong, Q., Niu, X., Chen, J. S., Wang, J., et al. (2022) · Small · doi:10.1002/smll.202203495 · Cited by 53 · see citing works
Wu, Y., Xu, W., Tang, W., Wang, Z., Wang, Y., Lv, Z., Zhang, Y., Zhong, W., Cai, H., Yang, R., et al. (2021) · Nano Energy · doi:10.1016/j.nanoen.2021.106532 · Cited by 53 · see citing works
Self-citationTwo-dimensional materials: synthesis and applications in the electro-reduction of carbon dioxide
Yin, Y., Kang, X., & Han, B. (2022) · Chemical Synthesis · doi:10.20517/cs.2022.20 · Cited by 52 · see citing works
Liu, Q., Bai, C., Zhu, C., Guo, W., Li, G., Guo, S., Kripalani, D. R., Zhou, K., & Chen, R. (2024) · Advanced Science · doi:10.1002/advs.202400934 · Cited by 51 · see citing works
Size‐Dependent Nickel‐Based Electrocatalysts for Selective CO2 Reduction
Li, Z., He, D., Yan, X., Dai, S., Younan, S. M., Ke, Z., Pan, X. Q., Xiao, X., Wu, H., & Gu, J. H. (2020) · Angewandte Chemie · doi:10.1002/ange.202000318 · Cited by 51 · see citing works
Electrode Engineering for Electrochemical CO2 Reduction
Li, G., Yan, T., Chen, X., Liu, H., Zhang, S., & Ma, X. (2022) · Energy & Fuels · doi:10.1021/acs.energyfuels.2c00271 · Cited by 51 · see citing works
Single-atom-based catalysts for photoelectrocatalysis: challenges and opportunities
Liu, D., Wan, X., Kong, T., Han, W., & Xiong, Y. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta08252c · Cited by 50 · see citing works
High‐Performance Gel Polymer Electrolyte Based on Chitosan–Lignocellulose for Lithium‐Ion Batteries
Han, J., Huang, Y., Chen, Y., Song, A., Deng, X., Liu, B., Li, X., & Wang, M. (2020) · ChemElectroChem · doi:10.1002/celc.202000007 · Cited by 49 · see citing works
Jiang, X., Li, X., Kong, Y., Deng, C., Li, X., Hu, Q. L., Yang, H., & He, C. (2022) · Small · doi:10.1002/smll.202204148 · Cited by 49 · see citing works
- Authors
- Wang, Y., Liu, J., Wang, Y., Al‐Enizi, A. M., & Zheng, G.
- Affiliations
- Fudan University (CN)
- King Saud University (SA)
- Corresponding author
- Zheng, Gengfeng
- Venue
- Small
- Publisher
- Wiley
- Published
- 2017-09-14
- Volume
- 13
- Issue
- 43
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2756379113
- Cited by
- 241
- References
- 124
- Citations by year
- 2026: 6 · 2025: 26 · 2024: 19 · 2023: 23 · 2022: 34 · 2021: 42 · 2020: 38 · 2019: 32 · 2018: 20
- FWCI
- 0.99
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Small (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21473038, 21773036)
- Science and Technology Commission of Shanghai Municipality (17JC1402000)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, product selectivity, artificial photosynthesis, solar-to-chemical energy conversion, crystal facets, electronic structure, geometric structure, nanostructures, electrolyte effects, mesoscale phenomena
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review