The DOI matches its Crossref record; 57 of the 57 references it cites were found in a registry or an index.
Noble Metal-Free Nanoporous High-Entropy Alloys as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction
Abstract
Developing highly efficient catalysts for oxygen evolution reactions (OER) is a key step for rechargeable metal–oxygen batteries and water splitting. Usually, binary NiFe or ternary NiCoFe nano-alloys are used as the OER catalysts. Herein, combining the precursor alloy design with chemical etching, a simple dealloying route is developed to controllably incorporate five or more nonprecious metals into one nanostructured alloy with a naturally oxidized surface, that is, nanoporous high entropy alloys (np-HEAs) covered with high-entropy (oxy)hydroxides (HEOs). It is found that the alloy composition plays a dominant role in the OER activity enhancement with the np-AlNiCoFeX (X = Mo, Nb, Cr) combination showing the highest activity. Forming quinary HEAs also greatly enhances the electrochemical cycling stabilities compared with the ternary and quaternary counterparts. The result indicates the significance of synergistically incorporating five or more metal elements in one single-phase nanostructure, which provides more structural and chemical degrees of freedom to boost the catalytic performance, overcoming the restriction of normal binary or ternary alloys. Multinary transition metal-based np-HEA is a new class of promising catalyst for various important reactions.
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Citations
Cites
A critical review of high entropy alloys and related concepts
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Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
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Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction
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A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
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An Advanced Ni–Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation
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Homogeneously dispersed multimetal oxygen-evolving catalysts
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Carbothermal shock synthesis of high-entropy-alloy nanoparticles
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Self-citationA Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation
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Cited by
High-entropy energy materials: challenges and new opportunities
Ma, Y., Ma, Y., Wang, Q., Schweidler, S., Botros, M., Fu, T., Hahn, H., Brezesinski, T., & Breitung, B. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00505g · Cited by 963
High-entropy materials for catalysis: A new frontier
Sun, Y., & Dai, S. (2021) · Science Advances · doi:10.1126/sciadv.abg1600 · Cited by 942
Hao, J., Zhuang, Z., Cao, K., Gao, G., Wang, C., Lai, F., Lu, S., Ma, P., Dong, W., Liu, T., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-30379-4 · Cited by 757
Recent progress of high-entropy materials for energy storage and conversion
Amiri, A., & Shahbazian-Yassar, R. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta09578h · Cited by 592
Fan, L., Ji, Y., Wang, G., Chen, J., Chen, K., Liu, X., & Wen, Z. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c13740 · Cited by 554
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Metadata
- Authors
- Qiu, H.-J., Fang, G., Gao, J., Wen, Y., Lv, J., Li, H., Xie, G., Liu, X., & Sun, S.
- Venue
- ACS Materials Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-10-08
- Volume
- 1
- Issue
- 5
- Pages
- 526-533
- ISSN
- 2639-4979 (ISSN-L)
- OpenAlex
- W2980165457
- Cited by
- 422
- References
- 57
- FWCI
- 7.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Qiu, H.-J., Fang, G., Gao, J., Wen, Y., Lv, J., Li, H., Xie, G., Liu, X., & Sun, S. (2019). Noble Metal-Free Nanoporous High-Entropy Alloys as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction. ACS Materials Letters. https://doi.org/10.1021/acsmaterialslett.9b00414
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