The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Atomically Dispersed Indium Sites for Selective CO2 Electroreduction to Formic Acid
Open accessAbstract
An atomically dispersed structure is attractive for electrochemically converting carbon dioxide (CO 2 ) to fuels and feedstock due to its unique properties and activity. Most single-atom electrocatalysts are reported to reduce CO 2 to carbon monoxide (CO). Herein, we develop atomically dispersed indium (In) on a nitrogen-doped carbon skeleton (In–N–C) as an efficient catalyst to produce formic acid/formate in aqueous media, reaching a turnover frequency as high as 26771 h –1 at −0.99 V relative to a reversible hydrogen electrode (RHE). Electrochemical measurements show that trace amounts of In loaded on the carbon matrix significantly improve the electrocatalytic behavior for the CO 2 reduction reaction, outperforming conventional metallic In catalysts. Further experiments and density functional theory (DFT) calculations reveal that the formation of intermediate *OCHO on isolated In sites plays a pivotal role in the efficiency of the CO 2 -to-formate process, which has a lower energy barrier than that on metallic In.
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Cites
What would it take for renewably powered electrosynthesis to displace petrochemical processes?
De Luna, P., Hahn, C., Higgins, D., Jaffer, S. A., Jaramillo, T. F., & Sargent, E. H. (2019) · Science · doi:10.1126/science.aav3506 · Cited by 3,052
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331
Xia, C., Zhu, P., Jiang, Q., Pan, Y., Liang, W., Stavitski, E., Alshareef, H. N., & Wang, H. (2019) · Nature Energy · doi:10.1038/s41560-019-0451-x · Cited by 782
Jiang, B., Zhang, X.-G., Jiang, K., Wu, D.-Y., & Cai, W.-B. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.7b12506 · Cited by 402
Cited by
Shan, J., Ye, C., Chen, S., Sun, T., Jiao, Y., Liu, L., Zhu, C., Song, L., Han, Y., Jaroniec, M., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c01525 · Cited by 567
Jiang, M., Wang, H., Zhu, M., Luo, X., He, Y., Wang, M., Wu, C., Zhang, L., Li, X., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 299
Self-citation
Metadata
- Authors
- Lu, P., Tan, X., Zhao, H., Xiang, Q., Liu, K., Zhao, X., Yin, X., Li, X., Hai, X., Xi, S., Wee, A. T. S., Pennycook, S. J., Yu, X., Yuan, M., Wu, J., Zhang, G., Smith, S. C., & Yin, Z.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-02-15
- Volume
- 15
- Issue
- 3
- Pages
- 5671-5678
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W3129738768
- Cited by
- 211
- References
- 7
- FWCI
- 6.67
- Type
- journal article
- Language
- en
- Open access
- green
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