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Cited by 291

The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.

CO2-Induced Phase Engineering: Protocol for Enhanced Photoelectrocatalytic Performance of 2D MoS2 Nanosheets

Qi, Yuhang, Xu, Qun, Wang, Yun, Yan, Bo, Ren, Yumei, Chen, Zhimin·2016·ACS Nano

Abstract

Molybdenum disulfide (MoS2) is a promising non-precious-metal catalyst, but its performance is limited by the density of active sites and poor electrical transport. Its metallic 1T phase possesses higher photoelectrocatalytic activity. Thus, how to efficiently increase the concentration of the 1T phase in the exfoliated two-dimensiaonal (2D) MoS2 nanosheets is an important premise. In this work, we propose a strategy to prepare a 2D heterostructure of MoS2 nanosheets using supercritical CO2-induced phase engineering to form metallic 1T-MoS2. Theoretical calculations and experimental results demonstrate that the introduced CO2 in the 2H-MoS2 host can prompt the transformation of partial 2H-MoS2 lattices into 1T-MoS2. Moreover, the electrical coupling and synergistic effect between 2H and 1T phases can greatly facilitate the efficient electron transfer from the active sites of MoS2, which significantly improves the photocatalytic performance.

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Metadata

Authors
Qi, Y., Xu, Q., Wang, Y., Yan, B., Ren, Y., & Chen, Z.
Venue
ACS Nano
Published
2016-02-04
Volume
10
Issue
2
Pages
2903-2909
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W2345915976
Cited by
291
References
6
FWCI
13.82
Type
journal article
Language
en
Open access
closed
Funders
  • National Natural Science Foundation of China (21101141, 51173170)
  • Zhengzhou Science and Technology Bureau (121PZDGG213)
  • Henan Province (114200510019)

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Qi, Y., Xu, Q., Wang, Y., Yan, B., Ren, Y., & Chen, Z. (2016). CO2-Induced Phase Engineering: Protocol for Enhanced Photoelectrocatalytic Performance of 2D MoS2 Nanosheets. ACS Nano. https://doi.org/10.1021/acsnano.6b00001

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