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Cited by 218

The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.

Nitrogen-Doped Nanoporous Carbon Membranes with Co/CoP Janus-Type Nanocrystals as Hydrogen Evolution Electrode in Both Acidic and Alkaline Environments

Open access
Wang, Hong, Min, Shixiong, Wang, Qiang, Li, Debao, Casillas, Gilberto, Ma, Chun, Li, Yangyang, Liu, Zhixiong, Li, Lain-Jong, Yuan, Jiayin, Antonietti, Markus, Wu, Tom·2017·ACS Nano

Abstract

Self-supported electrocatalysts being generated and employed directly as electrodes for energy conversion has been intensively pursued in the fields of materials chemistry and energy. Herein, we report a synthetic strategy to prepare freestanding hierarchically structured, nitrogen-doped nanoporous graphitic carbon membranes functionalized with Janus-type Co/CoP nanocrystals (termed as HNDCM-Co/CoP), which were successfully applied as a highly efficient, binder-free electrode in the hydrogen evolution reaction (HER). Benefited from multiple structural merits, such as a high degree of graphitization, three-dimensionally interconnected micro/meso/macropores, uniform nitrogen doping, well-dispersed Co/CoP nanocrystals, as well as the confinement effect of the thin carbon layer on the nanocrystals, HNDCM-Co/CoP exhibited superior electrocatalytic activity and long-term operation stability for HER under both acidic and alkaline conditions. As a proof-of-concept of practical usage, a 5.6 cm × 4 cm × 60 μm macroscopic piece of HNDCM-Co/CoP was prepared in our laboratory. Driven by a solar cell, electroreduction of water in alkaline conditions (pH 14) was performed, and H 2 was produced at a rate of 16 mL/min, demonstrating its potential as real-life energy conversion systems.

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Crossref · 10.1021/acsnano.7b01946

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Metadata

Authors
Wang, H., Min, S., Wang, Q., Li, D., Casillas, G., Ma, C., Li, Y., Liu, Z., Li, L.-J., Yuan, J., Antonietti, M., & Wu, T.
Venue
ACS Nano
Published
2017-04-07
Volume
11
Issue
4
Pages
4358-4364
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W2601879081
Cited by
218
References
12
FWCI
10.03
Type
journal article
Language
en
Open access
green

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