The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Heterogeneous Bimetallic Phosphide/Sulfide Nanocomposite for Efficient Solar-Energy-Driven Overall Water Splitting
Abstract
Solar-driven overall water splitting is highly desirable for hydrogen generation with sustainable energy sources, which need efficient, earth-abundant, robust, and bifunctional electrocatalysts for both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Herein, we propose a heterogeneous bimetallic phosphide/sulfide nanocomposite electrocatalyst of NiFeSP on nickel foam (NiFeSP/NF), which shows superior electrocatalytic activity of low overpotentials of 91 mV at −10 mA cm –2 for HER and of 240 mV at 50 mA cm –2 for OER in 1 M KOH solution. In addition, the NiFeSP/NF presents excellent overall water splitting performance with a cell voltage as low as 1.58 V at a current density of 10 mA cm –2 . Combining with a photovoltaic device of a Si solar cell or integrating into photoelectrochemical (PEC) systems, the bifunctional NiFeSP/NF electrocatalyst implements unassisted solar-driven water splitting with a solar-to-hydrogen conversion efficiency of ∼9.2% and significantly enhanced PEC performance, respectively.
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Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
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Alternative energy technologies
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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Cited by
Non‐Noble‐Metal‐Based Electrocatalysts toward the Oxygen Evolution Reaction
Wu, Z., Lu, X. F., Zang, S., & Lou, X. W. (. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201910274 · Cited by 1,230
Yan, H., Xie, Y., Wu, A., Cai, Z., Wang, L., Tian, C., Zhang, X., & Fu, H. (2019) · Advanced Materials · doi:10.1002/adma.201901174 · Cited by 640
Water Splitting: From Electrode to Green Energy System
Li, X., Zhao, L., Yu, J., Liu, X., Zhang, X., Liu, H., & Zhou, W. (2020) · Nano-Micro Letters · doi:10.1007/s40820-020-00469-3 · Cited by 619
Multifunctional Transition Metal‐Based Phosphides in Energy‐Related Electrocatalysis
Li, Y., Dong, Z., & Jiao, L. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902104 · Cited by 603
Fe-Based Electrocatalysts for Oxygen Evolution Reaction: Progress and Perspectives
Feng, C., Faheem, M. B., Fu, J., Xiao, Y., Li, C., & Li, Y. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05445 · Cited by 587
Metadata
- Authors
- Xin, Y., Kan, X., Gan, L.-Y., & Zhang, Z.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-09-14
- Volume
- 11
- Issue
- 10
- Pages
- 10303-10312
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2754282157
- Cited by
- 224
- References
- 15
- FWCI
- 6.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xin, Y., Kan, X., Gan, L.-Y., & Zhang, Z. (2017). Heterogeneous Bimetallic Phosphide/Sulfide Nanocomposite for Efficient Solar-Energy-Driven Overall Water Splitting. ACS Nano. https://doi.org/10.1021/acsnano.7b05020
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