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Cited by 359

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Rational Design of Three-Dimensional Graphene Encapsulated with Hollow FeP@Carbon Nanocomposite as Outstanding Anode Material for Lithium Ion and Sodium Ion Batteries

Wang, Xiujuan, Chen, Kai, Wang, Gang, Liu, Xiaojie, Wang, Hui·2017·ACS Nano

Abstract

, but their practical applications have been hindered by low electrical conductivity and dramatic volume variation during cycling. In this work, an interesting strategy for the rational design of graphene (GR) encapsulated with a hollow FeP@carbon nanocomposite (H-FeP@C@GR) via a combination of a hydrothermal route, a carbon-coating process, phosphidation treatment, and carbothermic reaction is reported. The hollow FeP (H-FeP) nanospheres shelled with thin carbon layers are wonderfully incorporated into the GR matrix, interconnecting to form a three-dimensional (3D) hierarchical architecture. Such a design offers distinct advantages for FeP-based anode materials for both lithium ion batteries (LIBs) and sodium ion batteries (SIBs). For example, the 3D omnibearing conductive networks from the GR skeleton and outer coating carbon can provide an open freeway for electron/ion transport, promoting the electrode reaction kinetics. In addition, the wrapping of an H-FeP nanosphere in a thin carbon layer enables the formation of a solid electrolyte interphase (SEI) on the carbon layer surface instead of on the individual H-FeP surface, preventing the continual re-forming of the SEI. When used as anode materials for LIBs and SIBs, H-FeP@C@GR exhibited excellent electrochemistry performances.

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Metadata

Authors
Wang, X., Chen, K., Wang, G., Liu, X., & Wang, H.
Venue
ACS Nano
Published
2017-10-24
Volume
11
Issue
11
Pages
11602-11616
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W2765154933
Cited by
359
References
38
FWCI
19.91
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Rational Design of Three-Dimensional Graphene Encapsulated with Hollow FeP@Carbon Nanocomposite as Outstanding Anode Material for Lithium Ion and Sodium Ion Batteries. https://app.cochat.ai/papers/10.1021/acsnano.7b06625
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Wang, X., Chen, K., Wang, G., Liu, X., & Wang, H. (2017). Rational Design of Three-Dimensional Graphene Encapsulated with Hollow FeP@Carbon Nanocomposite as Outstanding Anode Material for Lithium Ion and Sodium Ion Batteries. ACS Nano. https://doi.org/10.1021/acsnano.7b06625

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