The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Role of Acid–Base Equilibria in the Size, Shape, and Phase Control of Cesium Lead Bromide Nanocrystals
Open accessAbstract
Abstract A binary ligand system composed of aliphatic carboxylic acids and primary amines of various chain lengths is commonly employed in diverse synthesis methods for CsPbBr3 nanocrystals (NCs). In this work, we have carried out a systematic study examining how the concentration of ligands (oleylamine and oleic acid) and the resulting acidity (or basicity) affects the hot-injection synthesis of CsPbBr3 NCs. We devise a general synthesis scheme for cesium lead bromide NCs which allows control over size, size distribution, shape, and phase (CsPbBr3 or Cs4PbBr6) by combining key insights on the acid–base interactions that rule this ligand system. Furthermore, our findings shed light upon the solubility of PbBr2 in this binary ligand system, and plausible mechanisms are suggested in order to understand the ligand-mediated phase control and structural stability of CsPbBr3 NCs.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
Kojima, A., Teshima, K., Shirai, Y., & Miyasaka, T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809598r · Cited by 23,090
Protesescu, L., Yakunin, S., Bodnarchuk, M. I., Krieg, F., Caputo, R., Hendon, C. H., Yang, R. X., Walsh, A., & Kovalenko, M. V. (2015) · Nano Letters · doi:10.1021/nl5048779 · Cited by 9,209
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells
Yang, W. S., Park, B.-W., Jung, E. H., Jeon, N. J., Kim, Y. C., Lee, D. U., Shin, S. S., Seo, J., Kim, E. K., Noh, J. H., et al. (2017) · Science · doi:10.1126/science.aan2301 · Cited by 5,445
Nedelcu, G., Protesescu, L., Yakunin, S., Bodnarchuk, M. I., Grotevent, M. J., & Kovalenko, M. V. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b02404 · Cited by 2,356
De Roo, J., Ibáñez, M., Geiregat, P., Nedelcu, G., Walravens, W., Maes, J., Martins, J. C., Van Driessche, I., Kovalenko, M. V., & Hens, Z. (2016) · ACS Nano · doi:10.1021/acsnano.5b06295 · Cited by 1,947
Sutherland, B. R., & Sargent, E. H. (2016) · Nature Photonics · doi:10.1038/nphoton.2016.62 · Cited by 1,730
23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability
Bush, K. A., Palmstrom, A. F., Yu, Z. J., Boccard, M., Cheacharoen, R., Mailoa, J. P., McMeekin, D. P., Hoye, R. L. Z., Bailie, C. D., Leijtens, T., et al. (2017) · Nature Energy · doi:10.1038/nenergy.2017.9 · Cited by 1,545
Towards stable and commercially available perovskite solar cells
Park, N.-G., Grätzel, M., Miyasaka, T., Zhu, K., & Emery, K. (2016) · Nature Energy · doi:10.1038/nenergy.2016.152 · Cited by 1,182
Bekenstein, Y., Koscher, B. A., Eaton, S. W., Yang, P., & Alivisatos, A. P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11199 · Cited by 1,169
Sun, S., Yuan, D., Xu, Y., Wang, A., & Deng, Z. (2016) · ACS Nano · doi:10.1021/acsnano.5b08193 · Cited by 1,073
Quantum Size Effect in Organometal Halide Perovskite Nanoplatelets
Sichert, J. A., Tong, Y., Mutz, N., Vollmer, M., Fischer, S., Milowska, K. Z., García Cortadella, R., Nickel, B., Cardenas-Daw, C., Stolarczyk, J. K., et al. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b02985 · Cited by 936
Akkerman, Q. A., Motti, S. G., Srimath Kandada, A. R., Mosconi, E., D’Innocenzo, V., Bertoni, G., Marras, S., Kamino, B. A., Miranda, L., De Angelis, F., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12124 · Cited by 903
Self-citationPan, A., He, B., Fan, X., Liu, Z., Urban, J. J., Alivisatos, A. P., He, L., & Liu, Y. (2016) · ACS Nano · doi:10.1021/acsnano.6b03863 · Cited by 900
Self-Assembly of Broadband White-Light Emitters
Dohner, E. R., Hoke, E. T., & Karunadasa, H. I. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411045r · Cited by 784
Akkerman, Q. A., Park, S., Radicchi, E., Nunzi, F., Mosconi, E., De Angelis, F., Brescia, R., Rastogi, P., Prato, M., & Manna, L. (2017) · Nano Letters · doi:10.1021/acs.nanolett.6b05262 · Cited by 600
Self-citationSize-Tunable, Bright, and Stable PbS Quantum Dots: A Surface Chemistry Study
Moreels, I., Justo, Y., De Geyter, B., Haustraete, K., Martins, J. C., & Hens, Z. (2011) · ACS Nano · doi:10.1021/nn103050w · Cited by 578
Self-citationShamsi, J., Dang, Z., Bianchini, P., Canale, C., Di Stasio, F., Brescia, R., Prato, M., & Manna, L. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b03166 · Cited by 503
Self-citationLiu, Z., Bekenstein, Y., Ye, X., Nguyen, S. C., Swabeck, J., Zhang, D., Lee, S.-T., Yang, P., Ma, W., & Alivisatos, A. P. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01409 · Cited by 463
Noel, N. K., Habisreutinger, S. N., Wenger, B., Klug, M. T., Hörantner, M. T., Johnston, M. B., Nicholas, R. J., Moore, D. T., & Snaith, H. J. (2017) · Energy & Environmental Science · doi:10.1039/c6ee02373h · Cited by 413
Surface Chemistry of Colloidal PbSe Nanocrystals
Moreels, I., Fritzinger, B., Martins, J. C., & Hens, Z. (2008) · Journal of the American Chemical Society · doi:10.1021/ja803994m · Cited by 390
Self-citationRavi, V. K., Santra, P. K., Joshi, N., Chugh, J., Singh, S. K., Rensmo, H., Ghosh, P., & Nag, A. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b02192 · Cited by 380
Coetzee, J. F., & Padmanabhan, G. R. (1965) · Journal of the American Chemical Society · doi:10.1021/ja00950a006 · Cited by 286
Colloidal Halide Perovskite Nanoplatelets: An Exciting New Class of Semiconductor Nanomaterials
Weidman, M. C., Goodman, A. J., & Tisdale, W. A. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b01384 · Cited by 285
Mechanism for rapid growth of organic–inorganic halide perovskite crystals
Nayak, P. K., Moore, D. T., Wenger, B., Nayak, S., Haghighirad, A. A., Fineberg, A., Noel, N. K., Reid, O. G., Rumbles, G., Kukura, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms13303 · Cited by 266
Koolyk, M., Amgar, D., Aharon, S., & Etgar, L. (2016) · Nanoscale · doi:10.1039/c5nr09127f · Cited by 202
Noel, N. K., Congiu, M., Ramadan, A. J., Fearn, S., McMeekin, D. P., Patel, J. B., Johnston, M. B., Wenger, B., & Snaith, H. J. (2017) · Joule · doi:10.1016/j.joule.2017.09.009 · Cited by 191
Palazon, F., Almeida, G., Akkerman, Q. A., De Trizio, L., Dang, Z., Prato, M., & Manna, L. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b00895 · Cited by 158
Self-citationExistence of a Size-Dependent Stokes Shift in CsPbBr3 Perovskite Nanocrystals
Brennan, M. C., Zinna, J., & Kuno, M. K. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00383 · Cited by 129
Mayer Bond Order as a Metric of Complexation Effectiveness in Lead Halide Perovskite Solutions
Stevenson, J., Sorenson, B. A., Subramaniam, V. H., et al. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b04327 · Cited by 113
Cited by
Dong, Y., Qiao, T., Kim, D., Parobek, D., Rossi, D., & Son, D. H. (2018) · Nano Letters · doi:10.1021/acs.nanolett.8b00861 · Cited by 580
Bodnarchuk, M. I., Boehme, S. C., ten Brinck, S., Bernasconi, C., Shynkarenko, Y., Krieg, F., Widmer, R., Aeschlimann, B., Günther, D., Kovalenko, M. V., et al. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01669 · Cited by 466
Dutta, A., Behera, R. K., Pal, P., Baitalik, S., & Pradhan, N. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201900374 · Cited by 361
Mourdikoudis, S., Menelaou, M., Fiuza-Maneiro, N., Zheng, G., Wei, S., Pérez-Juste, J., Polavarapu, L., & Sofer, Z. (2022) · Nanoscale Horizons · doi:10.1039/d2nh00111j · Cited by 259
Zero-Dimensional Cesium Lead Halides: History, Properties, and Challenges
Akkerman, Q. A., Abdelhady, A. L., & Manna, L. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b00572 · Cited by 258
Self-citation
Metadata
- Authors
- Almeida, G., Goldoni, L., Akkerman, Q., Dang, Z., Khan, A. H., Marras, S., Moreels, I., & Manna, L.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-02-13
- Volume
- 12
- Issue
- 2
- Pages
- 1704-1711
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2787179633
- Cited by
- 553
- References
- 29
- FWCI
- 21.36
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
