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Pyrolysis-Ultrasonic-Assisted Flotation Technology for Recovering Graphite and LiCoO2 from Spent Lithium-Ion Batteries

Zhang, Guangwen, He, Yaqun, Feng, Yi, Wang, Haifeng, Zhu, Xiangnan·2018·ACS Sustainable Chemistry & Engineering

Abstract

An environmentally-friendly technology of pyrolysis-ultrasonic-assisted flotation for recovering graphite and LiCoO 2 from spent lithium-ion batteries has been evaluated in this paper. Surface properties and morphology of graphite and LiCoO 2 derived from spent lithium-ion batteries were carefully studied, and on this basis, their pyrolysis characteristics were investigated by thermogravimetry–gas chromatography–mass spectroscopy. Advanced analysis techniques, scanning electron microscopy, X-ray fluorescence spectrometry, and X-ray photoelectron spectroscopy, were utilized to analyze the effect of pyrolysis and ultrasound on the surface properties and morphology of graphite and LiCoO 2 . Flotation tests were conducted to evaluate the reinforcing effect of pyrolysis–ultrasound on flotation behavior. Results show that organic binder and electrolyte are the main reasons that graphite and LiCoO 2 are hard to separate by flotation; meanwhile, pyrolysis can effectively decompose organic binders at a pyrolysis temperature of 500 °C, and ultrasonic cleaning can effectively remove residual pyrolysis products. Pyrolysis-ultrasonic-assisted flotation can make the LiCoO 2 grade improve from 67.25% to 93.89% with the recovery improving from 74.62% to 96.88%. This research work may provide an alternative process for the preparation of high purity LiCoO 2 particles for the subsequent chemical metallurgy.

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Metadata

Authors
Zhang, G., He, Y., Feng, Y., Wang, H., & Zhu, X.
Venue
ACS Sustainable Chemistry & Engineering
Published
2018-07-03
Volume
6
Issue
8
Pages
10896-10904
ISSN
2168-0485 (ISSN-L)
OpenAlex
W2810772578
Cited by
237
References
2
FWCI
11.51
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Pyrolysis-Ultrasonic-Assisted Flotation Technology for Recovering Graphite and LiCoO2 from Spent Lithium-Ion Batteries. https://app.cochat.ai/papers/10.1021/acssuschemeng.8b02186
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Zhang, G., He, Y., Feng, Y., Wang, H., & Zhu, X. (2018). Pyrolysis-Ultrasonic-Assisted Flotation Technology for Recovering Graphite and LiCoO2 from Spent Lithium-Ion Batteries. ACS Sustainable Chemistry & Engineering. https://doi.org/10.1021/acssuschemeng.8b02186

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