The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Pyrolysis-Ultrasonic-Assisted Flotation Technology for Recovering Graphite and LiCoO2 from Spent Lithium-Ion Batteries
Abstract
An environmentally-friendly technology of pyrolysis-ultrasonic-assisted flotation for recovering graphite and LiCoO 2 from spent lithium-ion batteries has been evaluated in this paper. Surface properties and morphology of graphite and LiCoO 2 derived from spent lithium-ion batteries were carefully studied, and on this basis, their pyrolysis characteristics were investigated by thermogravimetry–gas chromatography–mass spectroscopy. Advanced analysis techniques, scanning electron microscopy, X-ray fluorescence spectrometry, and X-ray photoelectron spectroscopy, were utilized to analyze the effect of pyrolysis and ultrasound on the surface properties and morphology of graphite and LiCoO 2 . Flotation tests were conducted to evaluate the reinforcing effect of pyrolysis–ultrasound on flotation behavior. Results show that organic binder and electrolyte are the main reasons that graphite and LiCoO 2 are hard to separate by flotation; meanwhile, pyrolysis can effectively decompose organic binders at a pyrolysis temperature of 500 °C, and ultrasonic cleaning can effectively remove residual pyrolysis products. Pyrolysis-ultrasonic-assisted flotation can make the LiCoO 2 grade improve from 67.25% to 93.89% with the recovery improving from 74.62% to 96.88%. This research work may provide an alternative process for the preparation of high purity LiCoO 2 particles for the subsequent chemical metallurgy.
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Citations
Cites
Sun, L., & Qiu, K. (2011) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2011.07.114 · Cited by 493
Zhang, T., He, Y., Wang, F., Ge, L., Zhu, X., & Li, H. (2014) · Waste Management · doi:10.1016/j.wasman.2014.01.002 · Cited by 246
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Cited by
Neumann, J., Petranikova, M., Meeus, M., Gamarra, J. D., Younesi, R., Winter, M., & Nowak, S. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202102917 · Cited by 805
Progresses in Sustainable Recycling Technology of Spent Lithium‐Ion Batteries
Du, K., Ang, E. H., Wu, X., & Liu, Y. (2022) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12271 · Cited by 458
A comprehensive review on the pretreatment process in lithium-ion battery recycling
Kim, S., Bang, J., Yoo, J., Shin, Y., Bae, J., Jeong, J., Kim, K., Dong, P., & Kwon, K. (2021) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2021.126329 · Cited by 394
Martins, L. S., Guimarães, L. F., Botelho Junior, A. B., Tenório, J. A. S., & Espinosa, D. C. R. (2021) · Journal of Environmental Management · doi:10.1016/j.jenvman.2021.113091 · Cited by 361
Jin, S., Mu, D., Lu, Z., Li, R., Liu, Z., Wang, Y., Tian, S., & Dai, C. (2022) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2022.130535 · Cited by 361
Metadata
- Authors
- Zhang, G., He, Y., Feng, Y., Wang, H., & Zhu, X.
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-07-03
- Volume
- 6
- Issue
- 8
- Pages
- 10896-10904
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W2810772578
- Cited by
- 237
- References
- 2
- FWCI
- 11.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, G., He, Y., Feng, Y., Wang, H., & Zhu, X. (2018). Pyrolysis-Ultrasonic-Assisted Flotation Technology for Recovering Graphite and LiCoO2 from Spent Lithium-Ion Batteries. ACS Sustainable Chemistry & Engineering. https://doi.org/10.1021/acssuschemeng.8b02186
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