The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Preparation of Covalently Functionalized Graphene Using Residual Oxygen-Containing Functional Groups
Abstract
When fabricated by thermal exfoliation, graphene can be covalently functionalized more easily by applying a direct ring-opening reaction between the residual epoxide functional groups on the graphene and the amine-bearing molecules. Investigation by X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and transmission electron microscopy (TEM) all confirm that these molecules were covalently grafted to the surface of graphene. The resulting dispersion in an organic solvent demonstrated a long-term homogeneous stability of the products. Furthermore, comparison with traditional free radical functionalization shows the extent of the defects characterized by TEM and Raman spectroscopy and reveals that direct functionalization enables graphene to be covalently functionalized on the surface without causing any further damage to the surface structure. Thermogravmetric analysis (TGA) shows that the nondestroyed graphene structure provides greater thermal stability not only for the grafted molecules but also, more importantly, for the graphene itself, compared to the free-radical grafting method.
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Cites
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Cited by
A Facile Microwave Avenue to Electrochemiluminescent Two‐Color Graphene Quantum Dots
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Highly Efficient Enrichment of Radionuclides on Graphene Oxide-Supported Polyaniline
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How Do the Electrical Properties of Graphene Change with its Functionalization?
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Metadata
- Authors
- Hsiao, M.-C., Liao, S.-H., Yen, M.-Y., Liu, P.-I., Pu, N.-W., Wang, C.-A., & Ma, C.-C. M.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-10-15
- Volume
- 2
- Issue
- 11
- Pages
- 3092-3099
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2086361343
- Cited by
- 414
- References
- 45
- FWCI
- 12.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hsiao, M.-C., Liao, S.-H., Yen, M.-Y., Liu, P.-I., Pu, N.-W., Wang, C.-A., & Ma, C.-C. M. (2010). Preparation of Covalently Functionalized Graphene Using Residual Oxygen-Containing Functional Groups. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am100597d
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