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Ultrathin MoS2 Nanoplates with Rich Active Sites as Highly Efficient Catalyst for Hydrogen Evolution
Abstract
Well-defined ultrathin MoS2 nanoplates are developed by a facile solvent-dependent control route from single-source precursor for the first time. The obtained ultrathin nanoplate with a thickness of ~ 5 nm features high density of basal edges and abundant unsaturated active S atoms. The multistage growth process is investigated and the formation mechanism is proposed. Ultrathin MoS2 nanoplates exhibit an excellent activity for hydrogen evolution reaction (HER) with a small onset potential of 0.09 V, a low Tafel slope of 53 mV dec(-1), and remarkable stability. This work successfully demonstrates that the introduction of unsaturated active S atoms into ultrathin MoS2 nanoplates for enhanced electrocatalytic properties is feasible through a facial one-step solvent control method, and that this may open up a potential way for designing more efficient MoS2-based catalysts for HER.
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Metadata
- Authors
- Yan, Y., Xia, B., Ge, X., Liu, Z., Wang, J.-Y., & Wang, X.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-05
- Volume
- 5
- Issue
- 24
- Pages
- 12794-12798
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2325461697
- Cited by
- 427
- References
- 13
- FWCI
- 16.35
- Type
- journal article
- Language
- en
- Open access
- closed
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