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Polymer/Carbon Nanotube Nano Composite Fibers–A Review
Abstract
Carbon nanotubes (CNTs) are regarded as ideal filler materials for polymeric fiber reinforcement due to their exceptional mechanical properties and 1D cylindrical geometry (nanometer-size diameter and very high aspect ratio). The reported processing conditions and property improvements of CNT reinforced polymeric fiber are summarized in this review. Because of CNT polymer interaction, polymer chains in CNTs' vicinity (interphase) have been observed to have more compact packing, higher orientation, and better mechanical properties than bulk polymer. Evidences of the existence of interphase polymers in composite fibers, characterizations of their structures, and fiber properties are summarized and discussed. Implications of interphase phenomena on a broader field of fiber and polymer processing to make much stronger materials are now in the early stages of exploration. Beside improvements in tensile properties, the presence of CNTs in polymeric fibers strongly affects other properties, such as thermal stability, thermal transition temperature, fiber thermal shrinkage, chemical resistance, electrical conductivity, and thermal conductivity. This paper will be helpful to better understand the current status of polymer/CNT fibers, especially high-performance fibers, and to find the most suitable processing techniques and conditions.
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Citations
Cites
Helical microtubules of graphitic carbon
Iijima, S. (1991) · Nature · doi:10.1038/354056a0 · Cited by 43,098
Advances in the science and technology of carbon nanotubes and their composites: a review
Thostenson, E. T., Ren, Z., & Chou, T.-W. (2001) · Composites Science and Technology · doi:10.1016/s0266-3538(01)00094-x · Cited by 5,005
Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites
Coleman, J. N., Khan, U., Blau, W. J., & Gun’ko, Y. K. (2006) · Carbon · doi:10.1016/j.carbon.2006.02.038 · Cited by 4,071
The elasticity and strength of paper and other fibrous materials
Cox, H. L. (1952) · British Journal of Applied Physics · doi:10.1088/0508-3443/3/3/302 · Cited by 3,586
Polymer Nanocomposites Containing Carbon Nanotubes
Moniruzzaman, M., & Winey, K. I. (2006) · Macromolecules · doi:10.1021/ma060733p · Cited by 3,416
Thermal Transport Measurements of Individual Multiwalled Nanotubes
Kim, P., Shi, L., Majumdar, A., & McEuen, P. L. (2001) · Physical Review Letters · doi:10.1103/physrevlett.87.215502 · Cited by 3,378
Carbon nanotube–polymer composites: Chemistry, processing, mechanical and electrical properties
Spitalsky, Z., Tasis, D., Papagelis, K., & Galiotis, C. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.09.003 · Cited by 3,125
Unusually High Thermal Conductivity of Carbon Nanotubes
Berber, S., Kwon, Y.-K., & Tománek, D. (2000) · Physical Review Letters · doi:10.1103/physrevlett.84.4613 · Cited by 3,087
Thermal conductivity of carbon nanotubes and their polymer nanocomposites: A review
Han, Z., & Fina, A. (2011) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2010.11.004 · Cited by 2,603
Specific surface area of carbon nanotubes and bundles of carbon nanotubes
Peigney, A., Laurent, C., Flahaut, E., Bacsa, R. R., & Rousset, A. (2001) · Carbon · doi:10.1016/s0008-6223(00)00155-x · Cited by 2,040
Macroscopic Fibers and Ribbons of Oriented Carbon Nanotubes
Vigolo, B., Pénicaud, A., Coulon, C., Sauder, C., Pailler, R., Journet, C., Bernier, P., & Poulin, P. (2000) · Science · doi:10.1126/science.290.5495.1331 · Cited by 1,851
Multifunctional Carbon Nanotube Yarns by Downsizing an Ancient Technology
Zhang, M., Atkinson, K. R., & Baughman, R. H. (2004) · Science · doi:10.1126/science.1104276 · Cited by 1,721
Elastic and Shear Moduli of Single-Walled Carbon Nanotube Ropes
Salvetat, J.-P., Briggs, G., Bonard, J.-M., Bacsa, R., Kulik, A., Stöckli, T., Burnham, N., & Forró, L. (1999) · Physical Review Letters · doi:10.1103/physrevlett.82.944 · Cited by 1,488
Direct Spinning of Carbon Nanotube Fibers from Chemical Vapor Deposition Synthesis
Li, Y.-L., Kinloch, I. A., & Windle, A. H. (2004) · Science · doi:10.1126/science.1094982 · Cited by 1,474
Nanotube Networks in Polymer Nanocomposites: Rheology and Electrical Conductivity
Du, F., Scogna, R. C., Zhou, W., Brand, S., Fischer, J. E., & Winey, K. I. (2004) · Macromolecules · doi:10.1021/ma049164g · Cited by 1,307
Gojny, F. H., Wichmann, M. H. G., Fiedler, B., Kinloch, I. A., Bauhofer, W., Windle, A. H., & Schulte, K. (2006) · Polymer · doi:10.1016/j.polymer.2006.01.029 · Cited by 1,113
High-Performance Carbon Nanotube Fiber
Koziol, K., Vilatela, J., Moisala, A., Motta, M., Cunniff, P., Sennett, M., & Windle, A. (2007) · Science · doi:10.1126/science.1147635 · Cited by 1,038
Macroscopic, Neat, Single-Walled Carbon Nanotube Fibers
Ericson, L. M., Fan, H., Peng, H., Davis, V. A., Zhou, W., Sulpizio, J., Wang, Y., Booker, R., Vavro, J., Guthy, C., et al. (2004) · Science · doi:10.1126/science.1101398 · Cited by 863
Fu, S. (1996) · Composites Science and Technology · doi:10.1016/s0266-3538(96)00072-3 · Cited by 847
Electrospinning of Continuous Carbon Nanotube‐Filled Nanofiber Yarns
Ko, F., Gogotsi, Y., Ali, A., Naguib, N., Ye, H., Yang, G. L., Li, C., & Willis, P. (2003) · Advanced Materials · doi:10.1002/adma.200304955 · Cited by 752
Crystallization and orientation studies in polypropylene/single wall carbon nanotube composite
Bhattacharyya, A. R., Sreekumar, T. V., Liu, T., Kumar, S., Ericson, L. M., Hauge, R. H., & Smalley, R. E. (2003) · Polymer · doi:10.1016/s0032-3861(03)00073-9 · Cited by 725
Self-citationEffect of nanotube alignment on percolation conductivity in carbon nanotube/polymer composites
Du, F., Fischer, J. E., & Winey, K. I. (2005) · Physical Review B · doi:10.1103/physrevb.72.121404 · Cited by 641
Thermal and electrical conductivity of single- and multi-walled carbon nanotube-epoxy composites
Moisala, A., Li, Q., Kinloch, I. A., & Windle, A. H. (2006) · Composites Science and Technology · doi:10.1016/j.compscitech.2005.10.016 · Cited by 569
Measurement of carbon nanotube–polymer interfacial strength
Barber, A. H., Cohen, S. R., & Wagner, H. D. (2003) · Applied Physics Letters · doi:10.1063/1.1579568 · Cited by 540
Carbon Nanotubes Embedded in Oriented Polymer Nanofibers by Electrospinning
Dror, Y., Salalha, W., Khalfin, R. L., Cohen, Y., Yarin, A. L., & Zussman, E. (2003) · Langmuir · doi:10.1021/la034234i · Cited by 530
Choi, E. S., Brooks, J. S., Eaton, D. L., Al-Haik, M. S., Hussaini, M. Y., Garmestani, H., Li, D., & Dahmen, K. (2003) · Journal of Applied Physics · doi:10.1063/1.1616638 · Cited by 526
Du, F., Fischer, J. E., & Winey, K. I. (2003) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.10701 · Cited by 495
Organizing Carbon Nanotubes with Liquid Crystals
Lynch, M., & Patrick, D. L. (2002) · Nano Letters · doi:10.1021/nl025694j · Cited by 490
Reinforcement of Polymers with Carbon Nanotubes: The Role of Nanotube Surface Area
Cadek, M., Coleman, J. N., Ryan, K. P., Nicolosi, V., Bister, G., Fonseca, A., Nagy, J. B., Szostak, K., Béguin, F., & Blau, W. J. (2004) · Nano Letters · doi:10.1021/nl035009o · Cited by 487
Crystal Structure of Polyvinyl Alcohol
BUNN, C. W. (1948) · Nature · doi:10.1038/161929a0 · Cited by 456
Hou, H., Ge, J. J., Zeng, J., Li, Q., Reneker, D. H., Greiner, A., & Cheng, S. Z. D. (2005) · Chemistry of Materials · doi:10.1021/cm0484955 · Cited by 449
Continuous Spinning of a Single-Walled Carbon Nanotube−Nylon Composite Fiber
Gao, J., Itkis, M. E., Yu, A., Bekyarova, E., Zhao, B., & Haddon, R. C. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0446193 · Cited by 398
Fibers from polypropylene/nano carbon fiber composites
Kumar, S., Doshi, H., Srinivasarao, M., Park, J. O., & Schiraldi, D. A. (2002) · Polymer · doi:10.1016/s0032-3861(01)00744-3 · Cited by 381
Self-citationPolymer Crystallization-Driven, Periodic Patterning on Carbon Nanotubes
Li, L., Li, C. Y., & Ni, C. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056923h · Cited by 375
Nucleation of Polypropylene Crystallization by Single-Walled Carbon Nanotubes
Grady, B. P., Pompeo, F., Shambaugh, R. L., & Resasco, D. E. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp014622y · Cited by 357
Chae, H. G., & Kumar, S. (2006) · Journal of Applied Polymer Science · doi:10.1002/app.22680 · Cited by 354
Self-citationChae, H. G., & Kumar, S. (2008) · Science · doi:10.1126/science.1153911 · Cited by 323
Self-citationHot-Drawing of Single and Multiwall Carbon Nanotube Fibers for High Toughness and Alignment
Miaudet, P., Badaire, S., Maugey, M., Derré, A., Pichot, V., Launois, P., Poulin, P., & Zakri, C. (2005) · Nano Letters · doi:10.1021/nl051419w · Cited by 323
Haggenmueller, R., Fischer, J. E., & Winey, K. I. (2006) · Macromolecules · doi:10.1021/ma0527698 · Cited by 316
Carbon nanotubes in liquid crystals
Lagerwall, J. P. F., & Scalia, G. (2008) · Journal of Materials Chemistry · doi:10.1039/b802707b · Cited by 278
Carbon‐Nanotube‐Reinforced Polyaniline Fibers for High‐Strength Artificial Muscles
Spinks, G. M., Mottaghitalab, V., Bahrami‐Samani, M., Whitten, P. G., & Wallace, G. G. (2006) · Advanced Materials · doi:10.1002/adma.200502366 · Cited by 278
Mechanical properties and interfacial characteristics of carbon-nanotube-reinforced epoxy thin films
Xu, X., Thwe, M. M., Shearwood, C., & Liao, K. (2002) · Applied Physics Letters · doi:10.1063/1.1511532 · Cited by 276
Chae, H. G., Sreekumar, T. V., Uchida, T., & Kumar, S. (2005) · Polymer · doi:10.1016/j.polymer.2005.08.092 · Cited by 271
Self-citationScratch-Resistant, Highly Conductive, and High-Strength Carbon Nanotube-Based Composite Yarns
Liu, K., Sun, Y., Lin, X., Zhou, R., Wang, J., Fan, S., & Jiang, K. (2010) · ACS Nano · doi:10.1021/nn1017318 · Cited by 271
Electrical and thermophysical behaviour of PVC-MWCNT nanocomposites
MAMUNYA, Y., BOUDENNE, A., LEBOVKA, N., IBOS, L., CANDAU, Y., & LISUNOVA, M. (2008) · Composites Science and Technology · doi:10.1016/j.compscitech.2007.11.014 · Cited by 241
Orientation of multiwalled carbon nanotubes in composites with polycarbonate by melt spinning
Pötschke, P., Brünig, H., Janke, A., Fischer, D., & Jehnichen, D. (2005) · Polymer · doi:10.1016/j.polymer.2005.07.106 · Cited by 229
Piezoelectric properties of PVDF/MWCNT nanofiber using near-field electrospinning
Liu, Z. H., Pan, C. T., Lin, L. W., & Lai, H. W. (2013) · Sensors and Actuators A: Physical · doi:10.1016/j.sna.2013.01.007 · Cited by 223
Ultra-strong gel-spun UHMWPE fibers reinforced using multiwalled carbon nanotubes
Ruan, S., Gao, P., & Yu, T. X. (2006) · Polymer · doi:10.1016/j.polymer.2006.01.020 · Cited by 207
Single wall carbon nanotube templated oriented crystallization of poly(vinyl alcohol)
Minus, M. L., Chae, H. G., & Kumar, S. (2006) · Polymer · doi:10.1016/j.polymer.2006.03.076 · Cited by 205
Self-citationNucleation of polyvinyl alcohol crystallization by single-walled carbon nanotubes
Probst, O., Moore, E. M., Resasco, D. E., & Grady, B. P. (2004) · Polymer · doi:10.1016/j.polymer.2004.04.031 · Cited by 184
Fabrication and property prediction of conductive and strain sensing TPU/CNT nanocomposite fibres
Bilotti, E., Zhang, R., Deng, H., Baxendale, M., & Peijs, T. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm01827a · Cited by 171
Pötschke, P., Andres, T., Villmow, T., Pegel, S., Brünig, H., Kobashi, K., Fischer, D., & Häussler, L. (2010) · Composites Science and Technology · doi:10.1016/j.compscitech.2009.11.005 · Cited by 169
Reinforcement and rupture behavior of carbon nanotubes–polymer nanofibers
Ye, H., Lam, H., Titchenal, N., Gogotsi, Y., & Ko, F. (2004) · Applied Physics Letters · doi:10.1063/1.1787892 · Cited by 163
Rheological characterization of melt processed polycarbonate-multiwalled carbon nanotube composites
Abdel‐Goad, M. A. ‐., & Pötschke, P. (2005) · Journal of Non-Newtonian Fluid Mechanics · doi:10.1016/j.jnnfm.2005.01.008 · Cited by 163
Gel spinning of PVA/SWNT composite fiber
Zhang, X., Liu, T., Sreekumar, T. V., et al. (2004) · Polymer · doi:10.1016/j.polymer.2004.10.048 · Cited by 153
Spontaneous Dissolution of Ultralong Single- and Multiwalled Carbon Nanotubes
Parra‐Vasquez, A. N. G., Behabtu, N., Green, M. J., Pint, C. L., Young, C. C., Schmidt, J., Kesselman, E., Goyal, A., Ajayan, P. M., Cohen, Y., et al. (2010) · ACS Nano · doi:10.1021/nn100864v · Cited by 150
Carbon nanotubes induced crystallization of poly(ethylene terephthalate)
Anoop Anand, K., Agarwal, U. S., & Joseph, R. (2006) · Polymer · doi:10.1016/j.polymer.2006.03.079 · Cited by 148
Morphology and mechanical and electrical properties of oriented PVA–VGCF and PVA–MWNT composites
Bin, Y., Mine, M., Koganemaru, A., et al. (2006) · Polymer · doi:10.1016/j.polymer.2005.12.032 · Cited by 143
Electrically conductive yarns based on PVA/carbon nanotubes
Xue, P., Park, K. H., Tao, X., Chen, W., & Cheng, X. (2005) · Composite Structures · doi:10.1016/j.compstruct.2005.10.016 · Cited by 134
Solution spinning of cellulose carbon nanotube composites using room temperature ionic liquids
Rahatekar, S. S., Rasheed, A., Jain, R., Zammarano, M., Koziol, K. K., Windle, A. H., Gilman, J. W., & Kumar, S. (2009) · Polymer · doi:10.1016/j.polymer.2009.07.015 · Cited by 120
Self-citationRheology of multi‐walled carbon nanotube/poly(butylene terephthalate) composites
Wu, D., Wu, L. K., & Zhang, M. (2007) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.21233 · Cited by 114
Minus, M. L., Chae, H. G., & Kumar, S. (2009) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200900223 · Cited by 107
Self-citationShape‐memory polyurethane/multiwalled carbon nanotube fibers
Meng, Q., Hu, J., & Zhu, Y. (2007) · Journal of Applied Polymer Science · doi:10.1002/app.26517 · Cited by 103
Polypropylene/carbon nanotube nanocomposite fibers: Process–morphology–property relationships
Jose, M. V., Dean, D. R., Tyner, J., et al. (2006) · Journal of Applied Polymer Science · doi:10.1002/app.25475 · Cited by 93
Miyauchi, M., Miao, J., Simmons, T. J., Lee, J., Doherty, T. V., Dordick, J. S., & Linhardt, R. J. (2010) · Biomacromolecules · doi:10.1021/bm1006129 · Cited by 87
Young, K., Blighe, F. M., Vilatela, J. J., Windle, A. H., Kinloch, I. A., Deng, L., Young, R. J., & Coleman, J. N. (2010) · ACS Nano · doi:10.1021/nn102059c · Cited by 85
Effects of MWNT nanofillers on structures and properties of PVA electrospun nanofibres
Naebe, M., Lin, T., Tian, W., et al. (2007) · Nanotechnology · doi:10.1088/0957-4484/18/22/225605 · Cited by 82
Thermo-electrical properties of PVA–nanotube composite fibers
Miaudet, P., Bartholome, C., Derré, A., et al. (2007) · Polymer · doi:10.1016/j.polymer.2007.05.028 · Cited by 80
Preparation of high performance conductive polymer fibres from double percolated structure
Gao, X. S., Zhang, S., Mai, F., Lin, L., Deng, Y., Deng, H., & Fu, Q. (2011) · Journal of Materials Chemistry · doi:10.1039/c0jm04543h · Cited by 77
Meng, Q., & Hu, J. (2007) · Composites Part A Applied Science and Manufacturing · doi:10.1016/j.compositesa.2007.10.007 · Cited by 77
Conducting MWNT/poly(vinyl acetate) composite nanofibres by electrospinning
Wang, G., Tan, Z., Liu, X., Chawda, S., Koo, J., Samuilov, V. A., & Dudley, M. (2006) · Nanotechnology · doi:10.1088/0957-4484/17/23/019 · Cited by 61
Ojha, S. S., Stevens, D. R., Stano, K. L., et al. (2008) · Macromolecules · doi:10.1021/ma702634a · Cited by 44
Moon, J., Weaver, K., Feng, B., Chae, H. G., Kumar, S., Baek, J., & Peterson, G. P. (2012) · Review of Scientific Instruments · doi:10.1063/1.3676650 · Cited by 36
Self-citationFabrication of water‐soluble polyaniline/poly(ethylene oxide)/carbon nanotube electrospun fibers
Lin, Y., & Wu, T. (2012) · Journal of Applied Polymer Science · doi:10.1002/app.36744 · Cited by 34
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Chien, A., Gulgunje, P. V., Chae, H. G., et al. (2013) · Polymer · doi:10.1016/j.polymer.2013.08.061 · Cited by 32
Yeh, J., Lai, Y., Liu, H., Shu, Y., Huang, C., Huang, K., & Chen, K. (2010) · Polymer International · doi:10.1002/pi.2911 · Cited by 24
Via, M. D., Morrison, F. A., King, J. A., Caspary, J. A., Mills, O. P., & Bogucki, G. R. (2011) · Journal of Applied Polymer Science · doi:10.1002/app.33722 · Cited by 20
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Metadata
- Authors
- Liu, Y., & Kumar, S.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-02-12
- Volume
- 6
- Issue
- 9
- Pages
- 6069-6087
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2329691817
- Cited by
- 552
- References
- 77
- FWCI
- 26.51
- Type
- journal article
- Language
- en
- Open access
- closed
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