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Cited by 671

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General Predictive Syntheses of Cubic, Hexagonal, and Lamellar Silica and Titania Mesostructured Thin Films

Alberius, Peter C. A., Frindell, Karen L., Hayward, Ryan C., Kramer, Edward J., Stucky, Galen D., Chmelka, Bradley F.·2002·Chemistry of Materials

Abstract

Well-ordered mesostructured silica and titania films were prepared using poly(ethylene oxide)−poly(propylene oxide)−poly(ethylene oxide) triblock copolymer species (Pluronic P123) as the structure-directing agents. By varying the volume ratio between the copolymer and inorganic components of the precursor solution, silica and titania thin films with cubic, 2D hexagonal, and lamellar mesostructures were prepared. The regions over which the three phases were obtained correspond well with those of the water−block copolymer binary phase diagram when considered in terms of the volume fraction of copolymer incorporated. In particular, a cubic mesostructure with crystalline TiO 2 (anatase) in the walls, stable to 400 °C, was synthesized.

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Crossref · 10.1021/cm011209u

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Metadata

Authors
Alberius, P. C. A., Frindell, K. L., Hayward, R. C., Kramer, E. J., Stucky, G. D., & Chmelka, B. F.
Venue
Chemistry of Materials
Published
2002-07-13
Volume
14
Issue
8
Pages
3284-3294
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W1998945181
Cited by
671
References
2
FWCI
29.01
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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