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Controlled Lithium Dendrite Growth by a Synergistic Effect of Multilayered Graphene Coating and an Electrolyte Additive
Abstract
Lithium (Li) metal is the most ideal anode material in lithium ion batteries due to its large theoretical capacity (3860 mAh g –1 ) and low redox potential (−3.04 V vs standard hydrogen potential, H 2 /H + ). Nevertheless, surface dendrite formation during repeated charge–discharge cycles limits the cycle life and thus its practical use. The research efforts engaging polymer/ceramic coating or electrolyte additives have made noticeable progress, but further improvement is still desirable. Here, we report significantly improved performance by a synergistic effect of multilayered graphene (MLG) coating and Cs + additive in the electrolyte. MLG separates solid-electrolyte-interphase (SEI) formation from Li dendrites and thus stabilizes Coulombic efficiency in each cycle. Cs ions facilitate efficient interlayer diffusion of Li ions by enlarging the interlayer distance of MLG and also assists further for suppression of Li dendrite growth by electrostatic repulsion against Li ions. When paired with a stable sulfur–carbon composite electrode as a high capacity cathode, the Li–sulfur cell delivers an areal capacity of 4.0 mAh cm –2, a value comparable to those of current commercial lithium ion batteries, with 81.0% capacity retention after 200 cycles.
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Liang, X., Pang, Q., Kochetkov, I. R., Sempere, M. S., Huang, H., Sun, X., & Nazar, L. F. (2017) · Nature Energy · doi:10.1038/nenergy.2017.119 · Cited by 1,083
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Fan, X., Chen, L., Ji, X., Deng, T., Hou, S., Chen, J., Zheng, J., Wang, F., Jiang, J., Xu, K., et al. (2018) · Chem · doi:10.1016/j.chempr.2017.10.017 · Cited by 961
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Lee, B., Paek, E., Mitlin, D., & Lee, S. W. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00642 · Cited by 940
Zhang, R., Cheng, X., Zhao, C., Peng, H., Shi, J., Huang, J., Wang, J., Wei, F., & Zhang, Q. (2016) · Advanced Materials · doi:10.1002/adma.201504117 · Cited by 686
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Ye, H., Xin, S., Yin, Y.-X., Li, J.-Y., Guo, Y.-G., & Wan, L.-J. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01763 · Cited by 451
Graphene-based materials for electrochemical energy storage devices: Opportunities and challenges
Lv, W., Li, Z., Deng, Y., Yang, Q.-H., & Kang, F. (2016) · Energy Storage Materials · doi:10.1016/j.ensm.2015.10.002 · Cited by 433
Structural Design of Lithium–Sulfur Batteries: From Fundamental Research to Practical Application
Yang, X., Li, X., Adair, K., Zhang, H., & Sun, X. (2018) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0010-3 · Cited by 411
Wang, X., Zhang, M., Alvarado, J., Wang, S., Sina, M., Lu, B., Bouwer, J., Xu, W., Xiao, J., Zhang, J.-G., et al. (2017) · Nano Letters · doi:10.1021/acs.nanolett.7b03606 · Cited by 409
Lim, E., Jo, C., Kim, M. S., Kim, M., Chun, J., Kim, H., Park, J., Roh, K. C., Kang, K., Yoon, S., et al. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201505548 · Cited by 408
Li, C., Liu, S., Shi, C., Liang, G., Lu, Z., Fu, R., & Wu, D. (2019) · Nature Communications · doi:10.1038/s41467-019-09211-z · Cited by 384
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Ghazi, Z. A., Sun, Z., Sun, C., Qi, F., An, B., Li, F., & Cheng, H. (2019) · Small · doi:10.1002/smll.201900687 · Cited by 382
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Understanding and suppression strategies toward stable Li metal anode for safe lithium batteries
Yasin, G., Arif, M., Mehtab, T., Lu, X., Yu, D., Muhammad, N., Nazir, M. T., & Song, H. (2020) · Energy Storage Materials · doi:10.1016/j.ensm.2019.09.020 · Cited by 317
Assegie, A. A., Cheng, J.-H., Kuo, L.-M., Su, W.-N., & Hwang, B.-J. (2018) · Nanoscale · doi:10.1039/c7nr09058g · Cited by 309
Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode
Xie, J., Liao, L., Gong, Y., Li, Y., Shi, F., Pei, A., Sun, J., Zhang, R., Kong, B., Subbaraman, R., et al. (2017) · Science Advances · doi:10.1126/sciadv.aao3170 · Cited by 308
A review on anode for lithium-sulfur batteries: Progress and prospects
Zhao, H., Deng, N., Yan, J., Kang, W., Ju, J., Ruan, Y., Wang, X., Zhuang, X., Li, Q., & Cheng, B. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.04.112 · Cited by 299
Advances in Interfaces between Li Metal Anode and Electrolyte
Zhang, X., Cheng, X., & Zhang, Q. (2018) · Advanced Materials Interfaces · doi:10.1002/admi.201701097 · Cited by 287
Lin, W., Zhu, M., Fan, Y., Wang, H., Tao, G., Ding, M., Liu, N., Yang, H., Wu, J., Fang, J., et al. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.164163 · Cited by 64
Metadata
- Authors
- Kim, J.-S., Kim, D. W., Jung, H. T., & Choi, J. W.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-04-08
- Volume
- 27
- Issue
- 8
- Pages
- 2780-2787
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2322346598
- Cited by
- 199
- References
- 0
- FWCI
- 12.67
- Type
- journal article
- Language
- en
- Open access
- closed
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