The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Contribution of Functional Groups to the Raman Spectrum of Nanodiamond Powders
Abstract
In depth understanding of Raman spectra of carbon nanomaterials led to the extension of this technique from simple carbon allotrope detection (fingerprinting) to analysis of the dimensions and ordering of graphene, graphite and nanotubes. In characterization of nanodiamond powders, which have been attracting attention as one of the most promising carbon nanomaterials, Raman spectroscopy is still mainly used only for detecting the diamond phase because of poor understanding of other spectral features. In this paper, we critically examine different explanations of the broad asymmetric Raman band between 1500 and 1800 cm −1 present in all nanodiamond powders and provide an assignment of the contributing peaks, solving one of the major remaining mysteries in Raman spectroscopy of nanodiamond. By using nanodiamond powders with different and well-controlled surface chemistries, as well as in situ Raman measurements at elevated temperatures, we show that these peaks originate from O−H bending vibrations either from the surface functional groups or adsorbed water with contributions (shoulders) coming from sp 2 carbon and C═O stretching vibrations. The observation of a strong O−H contribution to the Raman spectrum of nanodiamond raises concerns regarding the use of water as a coolant during the Raman spectra acquisition, because water may affect Raman spectra in the wavenumber ranges corresponding to bending and stretching O−H vibrations.
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Cites
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Cited by
The properties and applications of nanodiamonds
Mochalin, V. N., Shenderova, O., Ho, D., & Gogotsi, Y. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2011.209 · Cited by 2,745
Self-citationGeorgakilas, V., Perman, J. A., Tucek, J., & Zboril, R. (2015) · Chemical Reviews · doi:10.1021/cr500304f · Cited by 2,147
Functionality is Key: Recent Progress in the Surface Modification of Nanodiamond
Krueger, A., & Lang, D. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201102670 · Cited by 584
Wet Chemistry Route to Hydrophobic Blue Fluorescent Nanodiamond
Mochalin, V. N., & Gogotsi, Y. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9004514 · Cited by 403
Self-citationPhonon confinement effects in the Raman spectrum of nanodiamond
Osswald, S., Mochalin, V. N., Havel, M., Yushin, G., & Gogotsi, Y. (2009) · Physical Review B · doi:10.1103/physrevb.80.075419 · Cited by 256
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Metadata
- Authors
- Mochalin, V., Osswald, S., & Gogotsi, Y.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-12-30
- Volume
- 21
- Issue
- 2
- Pages
- 273-279
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1981581064
- Cited by
- 279
- References
- 17
- FWCI
- 3.37
- Type
- journal article
- Language
- en
- Open access
- closed
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