Cited by 195Epoxy Resin Curing ProcessesPolymer composites and self-healingSilicone and Siloxane Chemistry

The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.

Reworkable Epoxies: Thermosets with Thermally Cleavable Groups for Controlled Network Breakdown

Abstract

A series of new cycloaliphatic epoxies were synthesized which have either secondary or tertiary ester bonds between cross-link sites. Thermal analysis data shows that the anhydride-cured epoxies with tertiary ester bonds can decompose at ∼220 °C, while those with primary ester links decompose at ∼340 °C. Dynamic mechanical analysis reveals that these new thermosets retain moduli comparable to the non-reworkable commercial thermosets with similar structure.

Overview

Integrity signals

Registry

Crossref · 10.1021/cm970667t

Cites

12 of 12 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Verification

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

  • Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, thermomechanical degradation, or wholesale replacement of network components with degradable versions.

    “Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, 3-8 thermomechanical degradation, 9 or wholesale replacement of network components with degradable versions. 10-13”

Citations

Cites

Flagged first, then by citations

Research works printed but not linked: 9

  1. Sastri V. R., 1990, J. Appl. Polym. Sci., 39, 1457, 10.1002/app.1990.070390703 · DOI
  2. Buchwalter S. L., 1996, Part A: Polym. Chem
  3. Buchwalter S. L., 1996, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.), 37, 186
  4. Mertzel E., 1986, Adv. Polym. Sci., 75, 74
  5. Schneider H. A., 1983, New York, 1, 506
  6. Furniss, B. S.; Hannaford, A. J.; Smith, P. W. G.; Tatchell, A. R.VOGEL'sTextbook of Practical Organic Chemistry, 5th ed.; Wiley: New York, 1989; p 537, expt. 5.40.
  7. (a) Furniss, B. S.; Hannaford, A. J.; Smith, P. W. G.; Tatchell, A. R.VOGEL'sTextbook of Practical Organic Chemistry, 5th ed.; Wiley: New York, 1989; p 541, expt. 5.42.
  8. Furniss, B. S.; Hannaford, A. J.; Smith, P. W. G.; Tatchell, A. R.VOGEL's Textbook of Practical Organic Chemistry, 5th ed.; Wiley: New York, 1989; p 693, expt. 5.138.
  9. cyclohexane-1,4-dicarboxylic acid bis[1-methyl-1-(6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)ethyl] ester

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Metadata

Authors
Yang, S., Chen, J.-S., Körner, H., Breiner, T., Ober, C. K., & Poliks, M. D.
Affiliations
  • Department of Materials Science and Engineering, Bard Hall, Cornell University, Ithaca, New York 14853-1501
  • Cornell University (US)
  • IBM (United States) (US)
Venue
Chemistry of Materials
Published
1998-05-15
Volume
10
Issue
6
Pages
1475-1482
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2018958133
Cited by
195
References
12
Citations by year
2026: 3 · 2025: 5 · 2024: 4 · 2023: 8 · 2022: 11 · 2021: 5 · 2020: 6 · 2019: 8 · 2018: 13 · 2017: 5 · 2016: 8 · 2015: 4 · 2014: 3 · 2013: 10 · 2012: 6
FWCI
11.50
Type
journal article
Language
en
Open access
closed
Locations
Chemistry of Materials (publishedVersion)
Funders
Centers for Disease Control and Prevention
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Epoxy Resin Curing Processes
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
  • Physical Sciences › Materials Science › Materials Chemistry › Silicone and Siloxane Chemistry
Keywords
thermosetting resins, cycloaliphatic epoxy resin, anhydride curing, thermal decomposition, dynamic mechanical properties, crosslinking

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