The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Reworkable Epoxies: Thermosets with Thermally Cleavable Groups for Controlled Network Breakdown
Abstract
A series of new cycloaliphatic epoxies were synthesized which have either secondary or tertiary ester bonds between cross-link sites. Thermal analysis data shows that the anhydride-cured epoxies with tertiary ester bonds can decompose at ∼220 °C, while those with primary ester links decompose at ∼340 °C. Dynamic mechanical analysis reveals that these new thermosets retain moduli comparable to the non-reworkable commercial thermosets with similar structure.
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Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, thermomechanical degradation, or wholesale replacement of network components with degradable versions.
“Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, 3-8 thermomechanical degradation, 9 or wholesale replacement of network components with degradable versions. 10-13”
From Cleavable comonomers enable degradable, recyclable thermoset plastics (2020) · cites this paper as [10]
Citations
Cites
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N,N‐Dimethyl‐4‐pyridinamine, a Very Effective Acylation Catalyst
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Self-citation
Flagged first, then by citations
Research works printed but not linked: 9
- Sastri V. R., 1990, J. Appl. Polym. Sci., 39, 1457, 10.1002/app.1990.070390703 · DOI
- Buchwalter S. L., 1996, Part A: Polym. Chem
- Buchwalter S. L., 1996, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.), 37, 186
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- cyclohexane-1,4-dicarboxylic acid bis[1-methyl-1-(6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)ethyl] ester
Cited by
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Cleavable comonomers enable degradable, recyclable thermoset plastics
Shieh, P., Zhang, W., Husted, K. E. L., Kristufek, S. L., Xiong, B., Lundberg, D. J., Lem, J., Veysset, D., Sun, Y., Nelson, K. A., et al. (2020) · Nature · doi:10.1038/s41586-020-2495-2 · Cited by 498
Metadata
- Authors
- Yang, S., Chen, J.-S., Körner, H., Breiner, T., Ober, C. K., & Poliks, M. D.
- Affiliations
- Department of Materials Science and Engineering, Bard Hall, Cornell University, Ithaca, New York 14853-1501
- Cornell University (US)
- IBM (United States) (US)
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-05-15
- Volume
- 10
- Issue
- 6
- Pages
- 1475-1482
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2018958133
- Cited by
- 195
- References
- 12
- Citations by year
- 2026: 3 · 2025: 5 · 2024: 4 · 2023: 8 · 2022: 11 · 2021: 5 · 2020: 6 · 2019: 8 · 2018: 13 · 2017: 5 · 2016: 8 · 2015: 4 · 2014: 3 · 2013: 10 · 2012: 6
- FWCI
- 11.50
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemistry of Materials (publishedVersion)
- Funders
- Centers for Disease Control and Prevention
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Epoxy Resin Curing Processes
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Materials Chemistry › Silicone and Siloxane Chemistry
- Keywords
- thermosetting resins, cycloaliphatic epoxy resin, anhydride curing, thermal decomposition, dynamic mechanical properties, crosslinking
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