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Enzymatic Chemistry of Cyclopropane, Epoxide, and Aziridine Biosynthesis
Open accessAbstract
"Cyclopropane, epoxide, and aziridine groups are three-membered ring structural elements found in a wide variety of natural products, some of which are depicted in Figure 1.1 The antibiotic and antitumor properties of many of these compounds, including duocarmycin (1),2 dynemicin (2),3 epothilone (3),4 mitomycin (4),5–8 and azinomycin (5)9–11 are well known. The pharmacological activities of others are more diverse. For example, pentalenolactone P (6)12,13 has antineoplastic and antiviral activities,14 scopolamine (7) has a subduing effect on the central nervous system,15 azicemicin (8) is active against Gram-negative bacteria and mycobacteria,16 and ficellomycin (9) shows inhibitory activities towards Gram-positive bacteria.17,18 [...] "@eng
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Cites
Solubilization and partial characterization of rat liver squalene epoxidase
Ono, T., & Bloch, K. (1975) · Journal of Biological Chemistry · doi:10.1016/s0021-9258(19)41847-4 · Cited by 157
The manumycin-group metabolites
Sattler, I., Thiericke, R., & Zeeck, A. (1998) · Natural Product Reports · doi:10.1039/a815221y · Cited by 95
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Flavoenzymes: Versatile catalysts in biosynthetic pathways
Walsh, C. T., & Wencewicz, T. A. (2013) · Nat. Prod. Rep. · doi:10.1039/c2np20069d · Cited by 373
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Vizcaino, M. I., & Crawford, J. M. (2015) · Nature Chemistry · doi:10.1038/nchem.2221 · Cited by 247
Metadata
- Authors
- Thibodeaux, C. J., Chang, W.-C., & Liu, H.-W.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-10-21
- Volume
- 112
- Issue
- 3
- Pages
- 1681-1709
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2009956300
- Cited by
- 275
- References
- 2
- FWCI
- 1.59
- Type
- journal article
- Language
- en
- Open access
- green
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