Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

Lyons, T. W., & Sanford, M. S. (2010) · Chemical Reviews · doi:10.1021/cr900184e · Cited by 6,119

Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality

Chen, X., Engle, K. M., Wang, D., & Yu, J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806273 · Cited by 4,121

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

Colby, D. A., Bergman, R. G., & Ellman, J. A. (2010) · Chemical Reviews · doi:10.1021/cr900005n · Cited by 3,682

Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation

Alberico, D., Scott, M. E., & Lautens, M. (2007) · Chemical Reviews · doi:10.1021/cr0509760 · Cited by 3,640

Activation of C−H Bonds by Metal Complexes

Shilov, A. E., & Shul'pin, G. B. (1997) · Chemical Reviews · doi:10.1021/cr9411886 · Cited by 2,859

Understanding and exploiting C–H bond activation

Labinger, J. A., & Bercaw, J. E. (2002) · Nature · doi:10.1038/417507a · Cited by 2,768

C-H Bond Functionalization in Complex Organic Synthesis

Godula, K., & Sames, D. (2006) · Science · doi:10.1126/science.1114731 · Cited by 2,161

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

Dobereiner, G. E., & Crabtree, R. H. (2010) · Chemical Reviews · doi:10.1021/cr900202j · Cited by 1,658

C–H activation

Bergman, R. G. (2007) · Nature · doi:10.1038/446391a · Cited by 1,470

Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

Arndtsen, B. A., Bergman, R. G., Mobley, T. A., & Peterson, T. H. (1995) · Accounts of Chemical Research · doi:10.1021/ar00051a009 · Cited by 1,451

Efficient catalytic addition of aromatic carbon-hydrogen bonds to olefins

Murai, S., Kakiuchi, F., Sekine, S., Tanaka, Y., Kamatani, A., Sonoda, M., & Chatani, N. (1993) · Nature · doi:10.1038/366529a0 · Cited by 1,406

Catalytic Functionalization of Arenes and Alkanes via C−H Bond Activation

Jia, C., Kitamura, T., & Fujiwara, Y. (2001) · Accounts of Chemical Research · doi:10.1021/ar000209h · Cited by 1,398

The Potential of Palladacycles: More Than Just Precatalysts

Dupont, J., Consorti, C. S., & Spencer, J. (2005) · Chemical Reviews · doi:10.1021/cr030681r · Cited by 1,300

Copper‐Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

Wendlandt, A. E., Suess, A. M., & Stahl, S. S. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103945 · Cited by 1,292

C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents

Beccalli, E. M., Broggini, G., Martinelli, M., & Sottocornola, S. (2007) · Chemical Reviews · doi:10.1021/cr068006f · Cited by 1,196

Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation

Jazzar, R., Hitce, J., Renaudat, A., Sofack‐Kreutzer, J., & Baudoin, O. (2010) · Chemistry – A European Journal · doi:10.1002/chem.200902374 · Cited by 1,092

Catalytic Methods for CH Bond Functionalization: Application in Organic Synthesis

Kakiuchi, F., & Chatani, N. (2003) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200303094 · Cited by 1,080

C—H Bond Activation in Transition Metal Species from a Computational Perspective

Balcells, D., Clot, E., & Eisenstein, O. (2010) · Chemical Reviews · doi:10.1021/cr900315k · Cited by 1,059

Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

Choi, J., MacArthur, A. H. R., Brookhart, M., & Goldman, A. S. (2011) · Chemical Reviews · doi:10.1021/cr1003503 · Cited by 1,028

Carbon–heteroatom bond formation catalysed by organometallic complexes

Hartwig, J. F. (2008) · Nature · doi:10.1038/nature07369 · Cited by 1,007

Catalytic Intermolecular Direct Arylation of Perfluorobenzenes

Lafrance, M., Rowley, C. N., Woo, T. K., & Fagnou, K. (2006) · Journal of the American Chemical Society · doi:10.1021/ja062509l · Cited by 855

Direct sp3C–H bond activation adjacent to nitrogen in heterocycles

Campos, K. R. (2007) · Chem. Soc. Rev. · doi:10.1039/b607547a · Cited by 773

Mechanistic Aspects of C−H Activation by Pt Complexes

Lersch, M., & Tilset, M. (2005) · Chemical Reviews · doi:10.1021/cr030710y · Cited by 750

Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect

Crabtree, R. H. (2001) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/b103147n · Cited by 716

C−H Bond Activations by Metal Oxo Compounds

Gunay, A., & Theopold, K. H. (2010) · Chemical Reviews · doi:10.1021/cr900269x · Cited by 563

Iridium Bis(phosphinite) p-XPCP Pincer Complexes: Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes

Göttker-Schnetmann, I., White, P., & Brookhart, M. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0385235 · Cited by 426

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

Ackermann, L., Vicente, R., & Althammer, A. (2008) · Organic Letters · doi:10.1021/ol800773x · Cited by 395

Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes

Flegeau, E. F., Bruneau, C., Dixneuf, P. H., & Jutand, A. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201462n · Cited by 375

Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages

Ackermann, L., Pospech, J., Graczyk, K., & Rauch, K. (2012) · Organic Letters · doi:10.1021/ol2034614 · Cited by 271

CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems

Arockiam, P. B., Fischmeister, C., Bruneau, C., & Dixneuf, P. H. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201002870 · Cited by 256

Regioselective synthesis of isocoumarins by ruthenium-catalyzed aerobic oxidative cyclization of aromatic acids with alkynes

Chinnagolla, R. K., & Jeganmohan, M. (2012) · Chemical Communications · doi:10.1039/c2cc16916a · Cited by 241

Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group

Mochida, S., Hirano, K., Satoh, T., & Miura, M. (2011) · The Journal of Organic Chemistry · doi:10.1021/jo200509m · Cited by 235

Synthesis of Stilbene and Distyrylbenzene Derivatives through Rhodium-Catalyzed Ortho-Olefination and Decarboxylation of Benzoic Acids

Mochida, S., Hirano, K., Satoh, T., & Miura, M. (2010) · Organic Letters · doi:10.1021/ol1027392 · Cited by 207

Ru(II) Catalysts Supported by Hydridotris(pyrazolyl)borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies, and Guides for the Development of Improved Catalysts

Foley, N. A., Lee, J. P., Ke, Z., Gunnoe, T. B., & Cundari, T. R. (2009) · Accounts of Chemical Research · doi:10.1021/ar800183j · Cited by 201

Ruthenium-Catalyzed Heck-Type Olefination and Suzuki Coupling Reactions: Studies on the Nature of Catalytic Species

Na, Y., Park, S., Han, S. B., Han, H., Ko, S., & Chang, S. (2003) · Journal of the American Chemical Society · doi:10.1021/ja038742q · Cited by 152

C−C Bond Formation via C−H Bond Activation Using an in Situ-Generated Ruthenium Catalyst

Martinez, R., Simon, M., Chevalier, R., Pautigny, C., Genêt, J., & Darses, S. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9017489 · Cited by 149

A Versatile Ruthenium Catalyst for CC Bond Formation by CH Bond Activation

Martinez, R., Chevalier, R., Darses, S., & Genêt, J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200603786 · Cited by 138

Transition metal catalyzed hydroarylation of olefins using unactivated substrates: Recent developments and challenges

Andreatta, J. R., McKeown, B. A., & Gunnoe, T. B. (2010) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2010.09.030 · Cited by 122

Preparative Scale Synthesis of the Biaryl Core of Anacetrapib via a Ruthenium-Catalyzed Direct Arylation Reaction: Unexpected Effect of Solvent Impurity on the Arylation Reaction

Ouellet, S. G., Roy, A., Molinaro, C., Angelaud, R., Marcoux, J.-F., O’Shea, P., & Davies, I. W. (2011) · The Journal of Organic Chemistry · doi:10.1021/jo1018574 · Cited by 99

Autocatalytic Oxidative Addition of PhBr to Pd(PtBu3)2via Pd(PtBu3)2(H)(Br)

Barrios‐Landeros, F., Carrow, B. P., & Hartwig, J. F. (2008) · Journal of the American Chemical Society · doi:10.1021/ja711159y · Cited by 98

Anti-Markovnikov hydroarylation of styrenes catalyzed by an in situ generated ruthenium complex

Martinez, R., Genêt, J., & Darses, S. (2008) · Chemical Communications · doi:10.1039/b806121a · Cited by 78

Aromatic C−H Activation and Catalytic Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt}(NCMe)Ph

Foley, N. A., Ke, Z., Gunnoe, T. B., Cundari, T. R., & Petersen, J. L. (2008) · Organometallics · doi:10.1021/om800275b · Cited by 67

3d Transition Metals for C–H Activation

Gandeepan, P., Müller, T., Zell, D., Cera, G., Warratz, S., & Ackermann, L. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00507 · Cited by 2,332

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

Ackermann, L. (2014) · Accounts of Chemical Research · doi:10.1021/ar3002798 · Cited by 1,640

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Chen, Z., Wang, B., Zhang, J., Yu, W., Liu, Z., & Zhang, Y. (2015) · Organic Chemistry Frontiers · doi:10.1039/c5qo00004a · Cited by 1,533

Synthetic Organic Electrochemistry: An Enabling and Innately Sustainable Method

Horn, E. J., Rosen, B. R., & Baran, P. S. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00091 · Cited by 1,068

Organocatalysis in Inert C–H Bond Functionalization

Qin, Y., Zhu, L., & Luo, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00657 · Cited by 785