Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes

The Chemistry of the Actinide and Transactinide Elements

(2006) · Springer eBooks · doi:10.1007/1-4020-3598-5 · Cited by 1,286

Ionic Liquids-Based Extraction: A Promising Strategy for the Advanced Nuclear Fuel Cycle

Sun, X., Luo, H., & Dai, S. (2012) · Chemical Reviews · doi:10.1021/cr200193x · Cited by 852

Lanthanides and Actinides in Ionic Liquids

Binnemans, K. (2007) · Chemical Reviews · doi:10.1021/cr050979c · Cited by 672

Chemistry of Diglycolamides: Promising Extractants for Actinide Partitioning

Ansari, S. A., Pathak, P., Mohapatra, P. K., & Manchanda, V. K. (2012) · Chemical Reviews · doi:10.1021/cr200002f · Cited by 647

Rational Design of Sequestering Agents for Plutonium and Other Actinides

Gorden, A. E. V., Xu, J., Raymond, K. N., & Durbin, P. (2003) · Chemical Reviews · doi:10.1021/cr990114x · Cited by 552

Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions

Kolarik, Z. J. (2008) · Chemical Reviews · doi:10.1021/cr078003i · Cited by 490

Towards uranium catalysts

Fox, A. R., Bart, S. C., Meyer, K., & Cummins, C. C. (2008) · Nature · doi:10.1038/nature07372 · Cited by 451

Oxo ligand functionalization in the uranyl ion (UO22+)

Fortier, S., & Hayton, T. W. (2010) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2009.06.003 · Cited by 335

The vitality of uranium molecular chemistry at the dawn of the XXIst century

Ephritikhine, M. (2006) · Dalton Transactions · doi:10.1039/b603463b · Cited by 314

Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes

Bart, S. C., Anthon, C., Heinemann, F. W., Bill, E., Edelstein, N. M., & Meyer, K. (2008) · Journal of the American Chemical Society · doi:10.1021/ja804263w · Cited by 244

Pentavalent uranyl complexes

Arnold, P. L., Love, J. B., & Patel, D. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2009.03.014 · Cited by 243

Synthesis of Imido Analogs of the Uranyl Ion

Hayton, T. W., Boncella, J. M., Scott, B. L., Palmer, P. D., Batista, E. R., & Hay, P. J. (2005) · Science · doi:10.1126/science.1120069 · Cited by 232

Bioreduction of Uranium: Environmental Implications of a Pentavalent Intermediate

Renshaw, J. C., Butchins, L. J. C., Livens, F. R., May, I., Charnock, J. M., & Lloyd, J. R. (2005) · Environmental Science & Technology · doi:10.1021/es048232b · Cited by 231

The coordination chemistry of actinides in ionic liquids: A review of experiment and simulation

Cocalia, V. A., Gutowski, K. E., & Rogers, R. D. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.09.019 · Cited by 226

Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR2)2]3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H)

Gaunt, A. J., Reilly, S. D., Enriquez, A. E., Scott, B. L., Ibers, J. A., Sekar, P., Ingram, K. I. M., Kaltsoyannis, N., & Neu, M. P. (2008) · Inorganic Chemistry · doi:10.1021/ic701618a · Cited by 201

Synthesis, Structure, and Bonding of Stable Complexes of Pentavalent Uranyl

Nocton, G., Horeglad, P., Vetere, V., Pécaut, J., Dubois, L., Maldivi, P., Edelstein, N. M., & Mazzanti, M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja9037164 · Cited by 158

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2000

Hyeon, J., Gottfriedsen, J., & Edelmann, F. T. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.03.001 · Cited by 137

Insights into the mechanism of carbonate formation through reductive cleavage of carbon dioxide with low-valent uranium centers

Lam, O. P., Bart, S. C., Kameo, H., Heinemann, F. W., & Meyer, K. (2010) · Chemical Communications · doi:10.1039/b927142b · Cited by 135

A Weak Interaction between Iron and Uranium in Uranium Alkyl Complexes Supported by Ferrocene Diamide Ligands

Monreal, M. J., & Diaconescu, P. L. (2008) · Organometallics · doi:10.1021/om700541u · Cited by 129

Influence of Dynamical Conditions on the Reduction of UVI at the Magnetite−Solution Interface

Ilton, E. S., Boily, J., Buck, E. C., Skomurski, F. N., Rosso, K. M., Cahill, C. L., Bargar, J., & Felmy, A. R. (2009) · Environmental Science & Technology · doi:10.1021/es9014597 · Cited by 123

Selective Recognition and Extraction of the Uranyl Ion

Sather, A. C., Berryman, O. B., & REBEK, J. J. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1035607 · Cited by 122

Synthesis, Structure, and Magnetic Behavior of a Series of Trinuclear Schiff Base Complexes of 5f (U IV , Th IV ) and 3d (Cu II , Zn II ) Ions

Salmon, L., Thuéry, P., Rivière, É., & Ephritikhine, M. (2005) · Inorganic Chemistry · doi:10.1021/ic0512375 · Cited by 121

Structural and Spectroscopic Characterization of a Charge-Separated Uranium Benzophenone Ketyl Radical Complex

Lam, O. P., Anthon, C., Heinemann, F. W., O'Connor, J. M., & Meyer, K. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801007q · Cited by 116

Probing the Reactivity and Electronic Structure of a Uranium(V) Terminal Oxo Complex

Fortier, S., Kaltsoyannis, N., Wu, G. X., & Hayton, T. W. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206083p · Cited by 112

Activation of elemental S, Se and Te with uranium(iii): bridging U–E–U (E = S, Se) and diamond-core complexes U–(E)2–U (E = O, S, Se, Te)

Lam, O. P., Heinemann, F. W., & Meyer, K. (2011) · Chemical Science · doi:10.1039/c1sc00151e · Cited by 110

U(SMes*)n, (n = 3, 4) and Ln(SMes*)3 (Ln = La, Ce, Pr, Nd): Lanthanide(III)/Actinide(III) Differentiation in Agostic Interactions and an Unprecedented η3 Ligation Mode of the Arylthiolate Ligand, from X-ray Diffraction and DFT Analysis

Roger, M., Barros, N., Arliguie, T., Thuéry, P., Maron, L., & Ephritikhine, M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0584830 · Cited by 109

Actinide speciation in the environment

Choppin, G. R. (2003) · Radiochimica Acta · doi:10.1524/ract.91.11.645.23469 · Cited by 108

A Trigonal Bipyramidal Uranyl Amido Complex: Synthesis and Structural Characterization of [Na(THF)2][UO2(N(SiMe3)2)3]

Burns, C. J., Clark, D. L., Donohoe, R. J., Duval, P. B., Scott, B. L., & Tait, C. D. (2000) · Inorganic Chemistry · doi:10.1021/ic0003168 · Cited by 107

Synthesis and Properties of a Fifteen‐Coordinate Complex: The Thorium Aminodiboranate [Th(H3BNMe2BH3)4]

Daly, S. R., Piccoli, P. M. B., Schultz, A. J., Todorova, T. K., Gagliardi, L., & Girolami, G. S. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200905797 · Cited by 103

Synthesis and crystal structure of pentavalent uranyl complexes. The remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions

Berthet, J. ‐., Siffredi, G., Thuéry, P., & Ephritikhine, M. (2009) · Dalton Transactions · doi:10.1039/b820659g · Cited by 100

Ion Pair Recognition of Quaternary Ammonium and Iminium Salts by Uranyl−Salophen Compounds in Solution and in the Solid State

Cametti, M., Nissinen, M., Cort, A. D., Mandolini, L., & Rissanen, K. T. (2007) · Journal of the American Chemical Society · doi:10.1021/ja068561z · Cited by 97

Isolation of a Uranyl [UO2]+ Species: Crystallographic Comparison of the Dioxouranium( V ) and ( VI ) Compounds [UO2(OPPh3)4](OTf)n (n=1, 2)

Berthet, J. ‐., Nierlich, M., & Ephritikhine, M. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200250506 · Cited by 93

2,2′‐Bipyrimidine as Efficient Sensitizer of the Solid‐State Luminescence of Lanthanide and Uranyl Ions from Visible to Near‐Infrared

Zucchi, G., Maury, O., Thuéry, P., Gumy, F., Bünzli, J. G., & Ephritikhine, M. (2009) · Chemistry - A European Journal · doi:10.1002/chem.200901517 · Cited by 92

Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters

Biswas, B., Mougel, V., Pécaut, J., & Mazzanti, M. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101327 · Cited by 83

An Unsupported Uranium–Rhenium Complex Prepared by Alkane Elimination

Gardner, B. M., McMaster, J., Moro, F., Lewis, W., Blake, A. J., & Liddle, S. T. (2011) · Chemistry - A European Journal · doi:10.1002/chem.201100682 · Cited by 80

Lanthanide(III) and Actinide(III) Complexes [M(BH4)2(THF)5][BPh4] and [M(BH4)2(18-crown-6)][BPh4] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding

Arliguie, T., Belkhırı, L., Bouaoud, S., Thuéry, P., Villiers, C., Boucekkine, A., & Ephritikhine, M. (2008) · Inorganic Chemistry · doi:10.1021/ic801685v · Cited by 79

Synthesis and Structure of (Ph4P)2MCl6(M = Ti, Zr, Hf, Th, U, Np, Pu)

Minasian, S. G., Boland, K. S., Feller, R. K., Gaunt, A. J., Kozimor, S. A., May, I., Reilly, S. D., Scott, B. L., & Shuh, D. K. (2012) · Inorganic Chemistry · doi:10.1021/ic300179d · Cited by 73

A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La)

(2006) · doi:10.1002/anie.200503372 · Cited by 73

Actinide Redox-Active Ligand Complexes: Reversible Intramolecular Electron-Transfer in U(dpp-BIAN)2/U(dpp-BIAN)2(THF)

Schelter, E. J., Wu, R., Scott, B. L., Thompson, J. D., Cantat, T., John, K. D., Batista, E. R., Morris, D. E., & Kiplinger, J. L. (2009) · Inorganic Chemistry · doi:10.1021/ic901636f · Cited by 72

Sterically Congested Uranyl Complexes with Seven-Coordination of the UO2 Unit: the Peculiar Ligation Mode of Nitrate in [UO2(NO3)2(Rbtp)] Complexes

Berthet, J. ‐., Thuéry, P., Dognon, J., Guillaneux, D., & Ephritikhine, M. (2008) · Inorganic Chemistry · doi:10.1021/ic8004486 · Cited by 68

Redox Behavior of Cyclo[6]pyrrole in the Formation of a Uranyl Complex

Melfi, P. J., Kim, S. K., Lee, J. T., et al. (2007) · Inorganic Chemistry · doi:10.1021/ic700781t · Cited by 66

Structurally Characterized Quadruple‐Stranded Bisbidentate Helicates

Xu, J., & Raymond, K. N. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602060 · Cited by 65

A Molecular Actinide–Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La)

(2006) · doi:10.1002/ange.200503372 · Cited by 62

Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)6

Fortier, S., Wu, G. X., & Hayton, T. W. (2008) · Inorganic Chemistry · doi:10.1021/ic800067k · Cited by 53

Homoleptic uranium(iii) imidodiphosphinochalcogenides including the first structurally characterised molecular trivalent actinide–Se bond

(2005) · doi:10.1039/b503106k · Cited by 50

Recent developments in nonaqueous plutonium coordination chemistry

Gaunt, A. J., & Neu, M. P. (2010) · Comptes Rendus Chimie · doi:10.1016/j.crci.2010.06.004 · Cited by 49

Structural Characterization of Pu[N(SiMe3)2]3, a Synthetically Useful Nonaqueous Plutonium(III) Precursor

Gaunt, A. J., Enriquez, A. E., Reilly, S. D., Scott, B. L., & Neu, M. P. (2007) · Inorganic Chemistry · doi:10.1021/ic701673e · Cited by 47

Anhydrous Photochemical Uranyl(VI) Reduction: Unprecedented Retention of Equatorial Coordination Accompanying Reversible Axial Oxo/Alkoxide Exchange

Kannan, S., Vaughn, A. E., Weis, E. M., Barnes, C. L., & Duval, P. B. (2006) · Journal of the American Chemical Society · doi:10.1021/ja065822w · Cited by 45

Fluoride Abstraction and Reversible Photochemical Reduction of Cationic Uranyl(VI) Phosphine Oxide Complexes

Kannan, S., Moody, M. A., Barnes, C. L., & Duval, P. B. (2006) · Inorganic Chemistry · doi:10.1021/ic060742e · Cited by 44

Synthesis, Characterization, and Structures of Uranium(III)N,N-Dimethylaminodiboranates

Daly, S. R., & Girolami, G. S. (2010) · Inorganic Chemistry · doi:10.1021/ic100290j · Cited by 44

Thorium 2-pyridylamidinates: synthesis, structure and catalytic activity towards the cyclo-oligomerization of ε-caprolactone

Rabinovich, E., Aharonovich, S., Botoshansky, M., & Eisen, M. S. (2010) · Dalton Transactions · doi:10.1039/c000661k · Cited by 44

Low-Valent Molecular Plutonium Halide Complexes

Gaunt, A. J., Reilly, S. D., Enriquez, A. E., Hayton, T. W., Boncella, J. M., Scott, B. L., & Neu, M. P. (2008) · Inorganic Chemistry · doi:10.1021/ic8009139 · Cited by 42

Specific recognition of fluoride anion using a metallamacrocycle incorporating a uranyl-salen unit

Cametti, M., Cort, A. D., Mandolini, L., Nissinen, M., & Rissanen, K. T. (2008) · New Journal of Chemistry · doi:10.1039/b806149a · Cited by 42

Hydroxy- and alkoxy-bridged dinuclear uranyl–Schiff base complexes: hydrolysis, transamination and extraction studies

Bharara, M. S., Heflin, K. L., Tonks, S. A., Strawbridge, K., & Gorden, A. E. V. (2008) · Dalton Transactions · doi:10.1039/b800469b · Cited by 42

Lanthanide and Uranium Complexes with an SPS-Based Pincer Ligand

Arliguie, T., Doux, M., Mézailles, N., Thuéry, P., Floch, P. L., & Ephritikhine, M. (2006) · Inorganic Chemistry · doi:10.1021/ic061364g · Cited by 37

Crystal Structure of a CsF−Uranyl−Salen Complex. An Unusual Cesium−Chlorine Coordination

Cametti, M., Nissinen, M., Cort, A. D., Rissanen, K. T., & Mandolini, L. (2006) · Inorganic Chemistry · doi:10.1021/ic060251u · Cited by 35

Versatility of {M(30-crown-10)} (M = K + , Ba 2+ ) as a guest in UO 2 2+ complexes of [3.1.3.1]- and [3.3.3]homooxacalixarenes

Masci, B., & Thuéry, P. (2007) · CrystEngComm · doi:10.1039/b703172f · Cited by 35

The Actinides

(2003) · doi:10.1016/b0-08-043748-6/02001-6 · Cited by 34

The Reaction Chemistry of Plutonyl(VI) Chloride Complexes with Triphenyl Phosphineoxide and Triphenyl Phosphinimine

Berthon, C., Boubals, N., Charushnikova, I. A., Collison, D., Cornet, S. M., Auwer, C. D., Gaunt, A. J., Kaltsoyannis, N., May, I., Petit, S., et al. (2010) · Inorganic Chemistry · doi:10.1021/ic101251a · Cited by 32

Synthesis and Redox Chemistry of High-Valent Uranium Aryloxides

Fortier, S., Wu, G. X., & Hayton, T. W. (2009) · Inorganic Chemistry · doi:10.1021/ic802266y · Cited by 31

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2005

Gottfriedsen, J., & Edelmann, F. T. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.06.011 · Cited by 31

Triamidotriazacyclononane Complexes of Group 3 Metals. Synthesis and Crystal Structures

Monteiro, B., Roitershtein, D. M., Ferreira, H. S., Ascenso, J. R., Martins, A. M., Domingos, A. M. T. S., & Marques, N. (2003) · Inorganic Chemistry · doi:10.1021/ic034090v · Cited by 29

Carbon Dioxide Insertion into Uranium‐Activated Dicarbonyl Complexes

Zuend, S. J., Lam, O. P., Heinemann, F. W., & Meyer, K. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201104189 · Cited by 29

Carbon Dioxide Insertion into Uranium‐Activated Dicarbonyl Complexes

Zuend, S. J., Lam, O. P., Heinemann, F. W., & Meyer, K. (2011) · Angewandte Chemie · doi:10.1002/ange.201104189 · Cited by 29

Differences in actinide metal–ligand orbital interactions: comparison of U(iv) and Pu(iv) β-ketoiminate N,O donor complexes

Schnaars, D. D., Batista, E. R., Gaunt, A. J., Hayton, T. W., May, I., Reilly, S. D., Scott, B. L., & Wu, G. X. (2011) · Chemical Communications · doi:10.1039/c1cc12409a · Cited by 28

Synthesis, crystal structure and reactivity of uranium( iv ) complexes with p-tert-butylcalix[4]arene ligands

Salmon, L., Thuéry, P., Asfari, Z., & Ephritikhine, M. (2006) · Dalton Transactions · doi:10.1039/b601237j · Cited by 26

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the years 2001 and 2002

Gottfriedsen, J., & Edelmann, F. T. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.02.030 · Cited by 25

Trinuclear Schiff base complexes with uranium(V) and copper(II) or zinc(II) ions

Salmon, L., Thuéry, P., & Ephritikhine, M. (2006) · Polyhedron · doi:10.1016/j.poly.2006.08.016 · Cited by 25

Homoleptic 2-Mercapto Benzothiazolate Uranium and Lanthanide Complexes

Roger, M., Arliguie, T., & Ephritikhine, M. (2008) · Inorganic Chemistry · doi:10.1021/ic702474q · Cited by 25

First characterization of an uranium(III) complex with a carbonyl-containing ligand: Syntheses and X-ray crystal structures of the homoleptic dimethylformamide complexes [M(dmf)n]I3 (M=Ce, Nd and n=8; M=La, Ce, U and n=9)

Berthet, J. ‐., Thuéry, P., & Ephritikhine, M. (2005) · Polyhedron · doi:10.1016/j.poly.2005.11.010 · Cited by 25

Immobilization of a hexaphyrin(1.0.1.0.0.0) derivative onto a tentagel-amino resin and its use in uranyl cation detection

Melfi, P. J., Camiolo, S., Lee, J. T., et al. (2008) · Dalton Transactions · doi:10.1039/b718627d · Cited by 24

Strictly heterodinuclear compounds containing U4+ and Cu2+ or Ni2+ ions

Salmon, L., Thuéry, P., & Ephritikhine, M. (2006) · Polyhedron · doi:10.1016/j.poly.2006.08.022 · Cited by 24

Towards high-valent uranium compounds from metallacyclic uranium(iv) precursors

Bénaud, O., Berthet, J. ‐., Thuéry, P., & Ephritikhine, M. (2011) · Chemical Communications · doi:10.1039/c1cc13112e · Cited by 23

Synthesis and reactivity of uranium(iv) amide complexes supported by a triamidotriazacyclononane ligand

Antunes, M. A., Dias, M., Monteiro, B., Domingos, �., Santos, I. C., & Marques, N. (2006) · Dalton Transactions · doi:10.1039/b603000a · Cited by 21

Uranyl(VI) complexes of [O,N,O,N′]-type diaminobis(phenolate) ligands: Syntheses, structures and extraction studies

Sopo, H., Lehtonen, A., & Sillanpää, R. (2007) · Polyhedron · doi:10.1016/j.poly.2007.08.047 · Cited by 21

A homoleptic SPS-based complex and a double-cubane-type sulfur cluster of an actinide element

Arliguie, T., Thuéry, P., Floch, P. L., Mézailles, N., & Ephritikhine, M. (2009) · Polyhedron · doi:10.1016/j.poly.2009.03.027 · Cited by 19

Synthesis and crystal structure of [UO2(BH4)2(hmpa)2], a novel uranyl complex and the first metal oxoborohydride

Villiers, C., Thuéry, P., & Ephritikhine, M. (2007) · Inorganic Chemistry Communications · doi:10.1016/j.inoche.2007.03.034 · Cited by 17

Convenient syntheses of uranyl(VI) cis-dihalide complexes as anhydrous starting materials

Duval, P. B., Kannan, S., & Barnes, C. L. (2006) · Inorganic Chemistry Communications · doi:10.1016/j.inoche.2006.01.023 · Cited by 14

Uranium(V) and uranium(IV/V) mixed valence complexes with p-tert-butylhomocalix[n]arenes (n=4, 6)

Salmon, L., Thuéry, P., Miyamoto, S., Yamato, T., & Ephritikhine, M. (2006) · Polyhedron · doi:10.1016/j.poly.2006.02.006 · Cited by 14

Synthesis and crystal structure of uranium( iv ) complexes with calix[n]arenes (n = 4, 6 and 8): mononuclear, polynuclear and 1D polymeric species

Salmon, L., Thuéry, P., & Ephritikhine, M. (2006) · Dalton Transactions · doi:10.1039/b604712b · Cited by 13

From U(IV) double-decker phthalocyanine with stacked UPc2 sandwiches to unstacked ones

Janczak, J., & Kubiak, R. (2010) · Inorganica Chimica Acta · doi:10.1016/j.ica.2010.12.013 · Cited by 3

New Mechanism for the Ring-Opening Polymerization of Lactones? Uranyl Aryloxide-Induced Intermolecular Catalysis

Walshe, A., Fang, J., Maron, L., & Baker, R. J. (2013) · Inorganic Chemistry · doi:10.1021/ic401275e · Cited by 50