The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Biobased Chemicals from Conception toward Industrial Reality: Lessons Learned and To Be Learned
Open accessAbstract
The development of innovative catalytic technologies to transform biomass into chemicals attracts increasing interest in both academic and industrial arenas as a means to establish a sustainable economy. This Perspective reviews relevant concepts developed in the field of chemocatalytic conversion of biomass and proposes strategies for engineering the future generations of catalytic processes devoted to the production of chemicals from lignocellulose-derived compounds. We discuss (i) approaches currently followed in the selection of biomass conversion routes to chemicals; (ii) required operating conditions to process bioderived feedstocks; (iii) design features for efficient catalysts; and finally, (iv) emerging reactor and separation options. With regard to catalyst families, particular attention is given to zeolites in view of the promising utilization of these crystalline microporous aluminosilicates in dehydration, isomerization, retro-aldolization, and oxidation reactions and of the potential of tailored (hierarchical, functionalized, or both) zeolite-based systems to attain superior performances in the transformation of biobased compounds. Throughout the way from idea to industrial reality, we put forward scientific and technological aspects of the mature petrochemical industry that could be transposed or adapted to the biobased manufacture of chemicals and indicate which knowledge will need to be developed ex novo.
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Cites
Chemical Routes for the Transformation of Biomass into Chemicals
Corma, A., Iborra, S., & Velty, A. (2007) · Chemical Reviews · doi:10.1021/cr050989d · Cited by 5,970
Bozell, J. J., & Petersen, G. R. (2010) · Green Chemistry · doi:10.1039/b922014c · Cited by 4,566
Catalytic conversion of biomass to biofuels
Alonso, D. M., Bond, J. Q., & Dumesic, J. A. (2010) · Green Chemistry · doi:10.1039/c004654j · Cited by 2,333
Catalytic conversion of biomass to monofunctional hydrocarbons and targeted liquid-fuel classes
Kunkes, E. L., Simonetti, D. A., West, R. M., Serrano-Ruiz, J. C., Gärtner, C. A., & Dumesic, J. A. (2008) · Science · doi:10.1126/science.1159210 · Cited by 895
A review of separation technologies in current and future biorefineries
Huang, H.-J., Ramaswamy, S., Tschirner, U. W., & Ramarao, B. V. (2008) · Separation and Purification Technology · doi:10.1016/j.seppur.2007.12.011 · Cited by 846
Design of hierarchical zeolite catalysts by desilication
Verboekend, D., & Pérez-Ramírez, J. (2011) · Catalysis Science & Technology · doi:10.1039/c1cy00150g · Cited by 712
Self-citationEthyl lactate as a solvent: Properties, applications and production processes – a review
Pereira, C. S. M., Silva, V. M. T. M., & Rodrigues, A. E. (2011) · Green Chemistry · doi:10.1039/c1gc15523g · Cited by 544
Robert Robinson Lecture. Retrosynthetic thinking—essentials and examples
Corey, E. J. (1988) · Chem. Soc. Rev. · doi:10.1039/cs9881700111 · Cited by 243
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Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
An overview of effect of process parameters on hydrothermal carbonization of biomass
Nizamuddin, S., Baloch, H. A., Griffin, G. J., Mubarak, N. M., Bhutto, A. W., Abro, R., Mazari, S. A., & Ali, B. S. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2016.12.122 · Cited by 514
Verboekend, D., Nuttens, N., Locus, R., Van Aelst, J., Verolme, P., Groen, J. C., Pérez-Ramírez, J., & Sels, B. F. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00520e · Cited by 355
Self-citationAshok, J., & Kawi, S. (2014) · ACS Catalysis · doi:10.1021/cs400621p · Cited by 321
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
Deuss, P. J., Barta, K., & de Vries, J. G. (2014) · Catal. Sci. Technol. · doi:10.1039/c3cy01058a · Cited by 316
The green solvent: a critical perspective
Winterton, N. (2021) · Clean Technologies and Environmental Policy · doi:10.1007/s10098-021-02188-8 · Cited by 307
Catalytic Isomerization of Biomass‐Derived Aldoses: A Review
Delidovich, I., & Palkovits, R. (2016) · ChemSusChem · doi:10.1002/cssc.201501577 · Cited by 300
Opportunities, recent trends and challenges of integrated biorefinery: Part II
Maity, S. K. (2015) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2014.08.075 · Cited by 295
“Ab initio” synthesis of zeolites for preestablished catalytic reactions
Gallego, E. M., Portilla, M. T., Paris, C., León-Escamilla, A., Boronat, M., Moliner, M., & Corma, A. (2017) · Science · doi:10.1126/science.aal0121 · Cited by 253
Zeolite Synthesis under Nonconventional Conditions: Reagents, Reactors, and Modi Operandi
Deneyer, A., Ke, Q., Devos, J., & Dusselier, M. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b04741 · Cited by 82
Self-metathesis of fatty acid methyl esters: full conversion by choosing the appropriate plant oil
Mutlu, H., Hofsäß, R., Montenegro, R. E., & Meier, M. A. R. (2013) · RSC Advances · doi:10.1039/c3ra40330k · Cited by 77
Yang, W., Wang, X., Ni, S., Liu, X., Liu, R., Hu, C., & Dai, H. (2021) · Separation and Purification Technology · doi:10.1016/j.seppur.2021.118599 · Cited by 32
Metadata
- Authors
- Dapsens, P. Y., Mondelli, C., & Pérez-Ramírez, J.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-06-21
- Volume
- 2
- Issue
- 7
- Pages
- 1487-1499
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2326266449
- Cited by
- 183
- References
- 8
- FWCI
- 10.64
- Type
- journal article
- Language
- en
- Open access
- green
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