The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Fluorine-Doped Carbon Blacks: Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction
Abstract
For the goal of practical industrial development of fuel cells, inexpensive, sustainable, and high performance electrocatalysts for oxygen reduction reactions (ORR) are highly desirable alternatives to platinum (Pt) and other rare materials. In this work, sustainable fluorine (F)-doped carbon blacks (CB-F) as metal-free, low-cost, and high-performance electrocatalysts for ORR were synthesized for the first time. The performance (electrocatalytic activity, long-term operation stability, and tolerance to poisons) of the best one (BP-18F, based on Black Pearls 2000 (BP)) is on the same level as Pt-based or other best non-Pt-based catalysts in alkaline medium. The maximum power density of alkaline direct methanol fuel cell with BP-18F as the cathode (3 mg/cm 2 ) is ∼15.56 mW/cm 2 at 60 °C, compared with a maximum of 9.44 mW/cm 2 for commercial Pt/C (3 mg Pt /cm 2 ). All these results unambiguously demonstrate that these sustainable CB-F catalysts are the most promising alternatives to Pt in an alkaline fuel cell. Since sustainable carbon blacks are 10 000 times less expensive and much more abundant than Pt or other rare materials, these CB-F electrocatalysts possess the best price/performance ratio for ORR to date.
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Cites
Electrocatalyst approaches and challenges for automotive fuel cells
Debe, M. K. (2012) · Nature · doi:10.1038/nature11115 · Cited by 5,885
Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
Wu, G., More, K. L., Johnston, C. M., & Zelenay, P. (2011) · Science · doi:10.1126/science.1200832 · Cited by 3,984
High oxygen-reduction activity and durability of nitrogen-doped graphene
Geng, D., Chen, Y., Chen, Y., Li, Y., Li, R., Sun, X., Ye, S., & Knights, S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00326c · Cited by 1,219
Self-citationFang, B., Chaudhari, N. K., Kim, M.-S., Kim, J. H., & Yu, J.-S. (2009) · Journal of the American Chemical Society · doi:10.1021/ja905749e · Cited by 311
Cited by
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156
Oxygen Reduction in Alkaline Media: From Mechanisms to Recent Advances of Catalysts
Ge, X., Sumboja, A., Wuu, D., An, T., Li, B., Goh, F. W. T., Hor, T. S. A., Zong, Y., & Liu, Z. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00524 · Cited by 1,341
Zhang, J., & Dai, L. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01563 · Cited by 590
Li, Z., Shao, M., Zhou, L., Zhang, R., Zhang, C., Wei, M., Evans, D. G., & Duan, X. (2016) · Advanced Materials · doi:10.1002/adma.201505086 · Cited by 498
Peng, H., Liu, F., Liu, X., Liao, S., You, C., Tian, X., Nan, H., Luo, F., Song, H., Fu, Z., et al. (2014) · ACS Catalysis · doi:10.1021/cs500744x · Cited by 429
Metadata
- Authors
- Sun, X., Zhang, Y., Song, P., Pan, J., Zhuang, L., Xu, W., & Xing, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-11
- Volume
- 3
- Issue
- 8
- Pages
- 1726-1729
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2323446835
- Cited by
- 378
- References
- 5
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- closed
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