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The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.

Effect of Transition Metals on the Structure and Performance of the Doped Carbon Catalysts Derived From Polyaniline and Melamine for ORR Application

Peng, Hongliang, Liu, Fangfang, Liu, Xiaojun, Liao, Shijun, You, Chenghang, Tian, Xinlong, Nan, Haoxiong, Luo, Fan, Song, Huiyu, Fu, Zhiyong, Huang, Peiyan·2014·ACS Catalysis

Abstract

In this work, the effects of the addition of transition metals (Mn, Fe, Co, Ni, Cu) on the structure and performance of the doped carbon catalysts M-PANI/C-Mela are investigated. The results show that the doping of various transition metals affected structures and performances of the catalysts significantly. Doping with Fe and Mn leads to a catalyst with a graphene-like structure, and doping with Co, Ni, and Cu leads to a disordered or nanosheet structure. The doping of transition metals can enhance the performance of the catalysts, and their ORR activity follows the order of Fe > Co > Cu > Mn > Ni, which is consistent with the order of their active N contents. We suggest that the various performance enhancements of the transition metals may be the result of the joint effect of the following three aspects: the N content/active N content, metal residue, and the surface area and pore structure, but not the effect of any single factor.

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Metadata

Authors
Peng, H., Liu, F., Liu, X., Liao, S., You, C., Tian, X., Nan, H., Luo, F., Song, H., Fu, Z., & Huang, P.
Venue
ACS Catalysis
Published
2014-09-25
Volume
4
Issue
10
Pages
3797-3805
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2314496634
Cited by
429
References
49
FWCI
7.64
Type
journal article
Language
en
Open access
closed

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