The environmental impact of CFC replacements - HFCs and HCFCs
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Environmental Impact of CFC Replacements HFCs and HCFCsTIMOTHY J. WALLINGTON, WILLIAM F. SCHNEIDER, DOUGLAS R. WORSNOP, OLE J. NIELSEN, JENS SEHESTED, WARREN J. DEBRUYN, and JEFFREY A. SHORTERCite this: Environ. Sci. Technol. 1994, 28, 7, 320A–326APublication Date (Print):July 1, 1994Publication History Published online30 May 2012Published inissue 1 July 1994https://pubs.acs.org/doi/10.1021/es00056a714https://doi.org/10.1021/es00056a714research-articleACS PublicationsRequest reuse permissionsArticle Views1379Altmetric-Citations95LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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The atmospheric fate of CF3O2 radicals is reactions with NO, NO2, HO2, and RO2 radicals.
“This is also incorrect; the atmospheric fate of CF3O2 radicals are reactions with NO, NO2, HO2, and RO2 radicals [92].”
Some degradation products of HCFCs, HFCs and HFOs are atmospheric precursors of TFA through hydrolysis of acyl halides, e.g., CF3CFO, or via secondary photochemistry of CF3CHO.
“Some of the degradation products are also atmospheric precursors of TFA through hydrolysis of acyl halides, e.g., CF3CFO, or via secondary photochemistry of trifluoroacetaldehyde (CF3CHO) [205, 206].”
From Changes in tropospheric air quality related to the protection of stratospheric ozone in a changing climate (2023) · cites this paper as [205]
Effective yields of TFA are significantly different, e.g., ~60% for HCFC-123 and 7-20% for HFC-134a.
“However, due to competing fates of the intermediary alkoxy radicals (marked with asterisks in Fig. 10), the effective yields of TFA are significantly different (e.g., ~ 60% for HCFC-123 and 7–20% for HFC-134a).”
From Changes in tropospheric air quality related to the protection of stratospheric ozone in a changing climate (2023) · cites this paper as [205]
The dominant atmospheric fate of CF3CClO and CF3CFO, generated in the atmospheric processing of HCFC-123 and HFC-134a, respectively, is uptake into cloud water followed by effective hydrolysis to yield TFA on a timescale of approximately 5-30 days.
“For instance, the dominant atmospheric fate of CF3CClO and CF3CFO, generated in the atmospheric processing of HCFC-123 and HFC-134a, respectively, is uptake into cloud water, followed by effective hydrolysis to yield TFA, on a timescale of approximately 5–30 days [205].”
From Changes in tropospheric air quality related to the protection of stratospheric ozone in a changing climate (2023) · cites this paper as [205]
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- Authors
- Wallington, T. J., Schneider, W. F., Worsnop, D. R., Nielsen, O. J., Sehested, J., Debruyn, W. J., & Shorter, J. A.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 1994-07-01
- Volume
- 28
- Issue
- 7
- Pages
- 320A-326A
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2087537123
- Cited by
- 198
- References
- 22
- Citations by year
- 2026: 5 · 2025: 9 · 2024: 10 · 2023: 8 · 2022: 4 · 2021: 15 · 2020: 13 · 2019: 13 · 2018: 13 · 2017: 6 · 2016: 7 · 2015: 6 · 2014: 7 · 2013: 5 · 2012: 8
- FWCI
- 4.17
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- Research at the University of Copenhagen (University of Copenhagen) (publishedVersion)
- Research at the University of Copenhagen (University of Copenhagen) (submittedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric Ozone and Climate
- Physical Sciences › Engineering › Mechanical Engineering › Refrigeration and Air Conditioning Technologies
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Keywords
- CFC alternatives, hydrofluorocarbons, hydrochlorofluorocarbons, ozone depletion, stratospheric ozone, chlorofluorocarbons, refrigerants, environmental impact
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
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