The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Photosensitizer Method to Determine Rate Constants for the Reaction of Carbonate Radical with Organic Compounds
Open accessAbstract
Carbonate radical (CO3*-) is a powerful oxidant that is present in sunlit surface waters and in waters treated by advanced oxidation processes. The production of CO3*- in aqueous solution through oxidation of carbonate anion by excited triplet states of aromatic ketones was investigated in this study to provide new methods for the determination of rate constants and to explore a possible photoinduced pathway of CO3*- formation in the aquatic environment. Rate constants for triplet quenching by carbonate anion of up to 3.0 x 10(7) M(-1) s(-1) and CO3*- yields approaching unity, determined using laser flash photolysis, allowed us to conclude that such a formation mechanism might be significant in sulit natural waters. Kinetic methods based on either flash photolysis or steady-state irradiation and on the use of aromatic ketones as photosensitizers gave bimolecular rate constants in the range of 4 x 10(6) to 1 x 10(8) M(-1) s(-1) for the reaction of CO3*- with several s-triazine and phenylurea herbicides. For various anilines and phenoxide anions, rate constants determined by these methods agreed well with published values. Moreover, it could be shown for the first time by a direct method that dissolved natural organic matter (DOM) reduces the lifetime of CO3*- and a second-order rate constant of (280 +/- 90) (mg of C/L)(-1) s(-1) was obtained for Suwannee River fulvic acid.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution
Neta, P., Huie, R. E., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555808 · Cited by 3,651
Nitrogen dioxide and carbonate radical anion: two emerging radicals in biology
Augusto, O., Bonini, M. G., Amanso, A. M., Linares, E., Santos, C. C. X., & De Menezes, S. L. (2002) · Free Radical Biology and Medicine · doi:10.1016/s0891-5849(02)00786-4 · Cited by 555
Canonica, S., Jans, U., Stemmler, K., & Hoigne, J. (1995) · Environmental Science & Technology · doi:10.1021/es00007a020 · Cited by 551
Self-citationHydroxyl Radical Photoproduction in the Sea and Its Potential Impact on Marine Processes
Mopper, K., & Zhou, X. (1990) · Science · doi:10.1126/science.250.4981.661 · Cited by 544
Brezonik, P. L., & Fulkerson-Brekken, J. (1998) · Environmental Science & Technology · doi:10.1021/es9802908 · Cited by 480
Intercalation of Sea Urchin Proteins in Calcite: Study of a Crystalline Composite Material
Berman, A., Addadi, L., Kvick, Å., Leiserowitz, L., Nelson, M., & Weiner, S. (1990) · Science · doi:10.1126/science.250.4981.664 · Cited by 328
Oxidation of Phenols by Triplet Aromatic Ketones in Aqueous Solution
Canonica, S., Hellrung, B., & Wirz, J. (2000) · The Journal of Physical Chemistry A · doi:10.1021/jp9930550 · Cited by 313
Self-citationTixier, C., Singer, H. P., Canonica, S., & Müller, S. R. (2002) · Environmental Science & Technology · doi:10.1021/es025647t · Cited by 261
Self-citationWeeks, J. L., & Rabani, J. (1966) · The Journal of Physical Chemistry · doi:10.1021/j100879a005 · Cited by 223
Electron-Rich Phenols for Probing the Photochemical Reactivity of Freshwaters
Canonica, S., & Freiburghaus, M. (2001) · Environmental Science & Technology · doi:10.1021/es0011360 · Cited by 196
Self-citation
Cited by
Chemistry of persulfates in water and wastewater treatment: A review
Wacławek, S., Lutze, H. V., Grübel, K., Padil, V. V. T., Černík, M., & Dionysiou, D. D. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.132 · Cited by 1,874
Reactive Species in Advanced Oxidation Processes: Formation, Identification and Reaction Mechanism
Wang, J., & Wang, S. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126158 · Cited by 1,585
Wang, J., & Wang, S. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.128392 · Cited by 1,332
Giannakis, S., Lin, K.-Y. A., & Ghanbari, F. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.127083 · Cited by 1,340
Chemistry of Ozone in Water and Wastewater Treatment: From Basic Principles to Applications
von Sonntag, C., & von Gunten, U. (2012) · IWA Publishing eBooks · doi:10.2166/9781780400839 · Cited by 768
Self-citationOxidation of Chlorinated Ethenes by Heat-Activated Persulfate: Kinetics and Products
Waldemer, R. H., Tratnyek, P. G., Johnson, R. L., & Nurmi, J. T. (2007) · Environmental Science & Technology · doi:10.1021/es062237m · Cited by 756
Yang, Y., Lu, X., Jiang, J., Ma, J., Liu, G., Cao, Y., Liu, W., Li, J., Pang, S., Kong, X., et al. (2017) · Water Research · doi:10.1016/j.watres.2017.03.054 · Cited by 637
Lutze, H. V., Kerlin, N., & Schmidt, T. C. (2015) · Water Research · doi:10.1016/j.watres.2014.10.006 · Cited by 521
Multiple Roles of Dissolved Organic Matter in Advanced Oxidation Processes
Yang, X., Rosario-Ortiz, F. L., Lei, Y., Pan, Y., Lei, X., & Westerhoff, P. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.2c01017 · Cited by 459
Methods for reactive oxygen species (ROS) detection in aqueous environments
Burns, J. M., Cooper, W. J., Ferry, J. L., King, D. W., DiMento, B. P., McNeill, K., Miller, C. J., Miller, W. L., Peake, B. M., Rusak, S. A., et al. (2012) · Aquatic Sciences · doi:10.1007/s00027-012-0251-x · Cited by 454
Fan, Y., Ji, Y., Kong, D., Lu, J., & Zhou, Q. (2015) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2015.06.058 · Cited by 450
Ji, Y., Fan, Y., Liu, K., Kong, D., & Lu, J. (2015) · Water Research · doi:10.1016/j.watres.2015.09.005 · Cited by 439
An overview of current issues in the uptake of atmospheric trace gases by aerosols and clouds
Kolb, C. E., Cox, R. A., Abbatt, J. P. D., Ammann, M., Davis, E. J., Donaldson, D. J., Garrett, B. C., George, C., Griffiths, P. T., Hanson, D. R., et al. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-10561-2010 · Cited by 405
Phototransformation of selected pharmaceuticals during UV treatment of drinking water
Canonica, S., Meunier, L., & von Gunten, U. (2008) · Water Research · doi:10.1016/j.watres.2007.07.026 · Cited by 405
Self-citationLi, Y., Yang, T., Qiu, S., Lin, W., Yan, J., Fan, S., & Zhou, Q. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.124382 · Cited by 365
Liu, Y., He, X., Duan, X., Fu, Y., Fatta-Kassinos, D., & Dionysiou, D. D. (2016) · Water Research · doi:10.1016/j.watres.2016.03.011 · Cited by 317
Photodegradation Processes of the Antiepileptic Drug Carbamazepine, Relevant To Estuarine Waters
Chiron, S., Minero, C., & Vione, D. (2006) · Environmental Science & Technology · doi:10.1021/es060502y · Cited by 306
Kim, J. R., & Kan, E. (2016) · Journal of Environmental Management · doi:10.1016/j.jenvman.2016.05.016 · Cited by 286
Xie, Z.-H., He, C.-S., Pei, D.-N., Dong, Y., Yang, S.-R., Xiong, Z., Zhou, P., Pan, Z.-C., Yao, G., & Lai, B. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.143778 · Cited by 279
Pesticide Photolysis in Prairie Potholes: Probing Photosensitized Processes
Zeng, T., & Arnold, W. A. (2013) · Environmental Science & Technology · doi:10.1021/es3030808 · Cited by 273
Photochemical degradation of oxytetracycline: Influence of pH and role of carbonate radical
Liu, Y., He, X., Duan, X., Fu, Y., & Dionysiou, D. D. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.04.048 · Cited by 269
Bicarbonate-activated persulfate oxidation of acetaminophen
Jiang, M., Lu, J., Ji, Y., & Kong, D. (2017) · Water Research · doi:10.1016/j.watres.2017.03.043 · Cited by 259
Zhou, Y., Chen, C., Guo, K., Wu, Z., Wang, L., Hua, Z., & Fang, J. (2020) · Water Research · doi:10.1016/j.watres.2020.116231 · Cited by 228
Barazesh, J. M., Prasse, C., & Sedlak, D. L. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b02232 · Cited by 166
Enhanced sonochemical degradation of bisphenol-A by bicarbonate ions
Pétrier, C., Torres-Palma, R., Combet, E., Sarantakos, G., Baup, S., & Pulgarin, C. (2010) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2009.05.010 · Cited by 144
Liu, T., Yin, K., Liu, C., Luo, J., Crittenden, J., Zhang, W., Luo, S., He, Q., Deng, Y., Liu, H., et al. (2018) · Water Research · doi:10.1016/j.watres.2018.10.007 · Cited by 135
Zhang, G., He, X., Nadagouda, M. N., E. O'Shea, K., & Dionysiou, D. D. (2015) · Water Research · doi:10.1016/j.watres.2015.01.011 · Cited by 128
Yang, Y., Cao, Y., Jiang, J., Lu, X., Ma, J., Pang, S., Li, J., Liu, Y., Zhou, Y., & Guan, C. (2019) · Water Research · doi:10.1016/j.watres.2018.08.074 · Cited by 120
Li, Y., Li, L., Chen, Z.-X., Zhang, J., Gong, L., Wang, Y.-X., Zhao, H.-Q., & Mu, Y. (2018) · Chemosphere · doi:10.1016/j.chemosphere.2017.10.126 · Cited by 102
Wols, B. A., Harmsen, D. J. H., Wanders-Dijk, J., Beerendonk, E. F., & Hofman-Caris, C. H. M. (2015) · Water Research · doi:10.1016/j.watres.2015.02.014 · Cited by 92
Application of Biochar-Based Materials for Effective Pollutant Removal in Wastewater Treatment
Han, M., Liu, Z., Huang, S., Zhang, H., Yang, H., Liu, Y., Zhang, K., & Zeng, Y. (2024) · Nanomaterials · doi:10.3390/nano14231933 · Cited by 37
Bicarbonate enhancing electrochemical degradation of antiviral drug lamivudine in aqueous solution
Wang, Y., Zhou, C., Chen, J., Fu, Z., & Niu, J. (2019) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2019.113314 · Cited by 27
Metadata
- Authors
- Canonica, S., Kohn, T., Mac, M., Real, F. J., Wirz, J., & von Gunten, U.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-11-02
- Volume
- 39
- Issue
- 23
- Pages
- 9182-9188
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W1981872117
- Cited by
- 488
- References
- 22
- FWCI
- 12.81
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
