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Effect of Fluorotelomer Alcohol Chain Length on Aqueous Solubility and Sorption by Soils
Abstract
Fluorotelomer alcohols (FTOHs) are a group of polyfluorinated alkyl chemicals that have been widely studied as precursorsto perfluorocarboxylates such as perfluorooctanoic acid and for which knowledge on their fate in soils is sparse. The solubility and sorption by soil of the homologous 4:2 to 10:2 FTOHs were measured in water or cosolvent/ water solutions. For the smaller 4:2 and 6:2 FTOHs, solubility and sorption could be measured adequately in aqueous systems although transformation was apparent even in gamma-irradiated and autoclaved systems. Sorption coefficients estimated by measuring both sorbed and solution-phase concentrations were not significantly affected by the biotransformation process. The use of cosolvents was employed for probing the behavior of the longer-chain FTOHs with limited aqueous solubility. A single log-linear correlation between aqueous solubility and modified McGowan molar volumes resulted for the n-alkanols and FTOHs. Soil organic carbon (OC) consistently appeared to be the key soil property influencing sorption of the FTOHs while the perfluorocarbon chain length was the dominant structural feature influencing solubility and sorption. Each CF2 moiety decreased the aqueous solubility by -0.78 log units (compared to 0.60 log units for each CH2 addition in hydrogenated primary alcohols), and increased OC-normalized sorption coefficients (Koc) by -0.87 log units. Good log-log linear correlations between Koc and both octanol-water partition coefficie…
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Available data for FTOHs suggest that soil organic carbon/water partition coefficients are ∼2 log units lower than Kow.
“Available data for FTOHs suggest that soil organic carbon/water partition coefficients are ∼2 log units lower than Kow.38”
From Intermolecular Interactions, Solute Descriptors, and Partition Properties of Neutral Per- and Polyfluoroalkyl Substances (PFAS) (2023) · cites this paper as [38]
PFAS sorption by subsurface media is greatly affected by the geochemical properties of the solid, particularly the magnitude and nature of organic carbon, magnitude and type of metal oxides, and clay mineralogy.
“Critical factors investigated for PFAS include the magnitude and nature of organic carbon, magnitude and type of metal oxides, and clay mineralogy (Higgins and Luthy, 2006, Liu and Lee, 2007, Ferrey et al., 2012, Milinovic et al., 2015, Zhang et al., 2015).”
From Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface (2018) · cites this paper as Liu and Lee, 2007
Citations
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Metadata
- Authors
- Liu, J., & Lee, L. S.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-06-30
- Volume
- 41
- Issue
- 15
- Pages
- 5357-5362
- ISSN
- 0013-936X
- 1520-5851
- Cited by
- 78
- References
- 6
- Language
- en
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