The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Hydrogen Generation in Microbial Reverse-Electrodialysis Electrolysis Cells Using a Heat-Regenerated Salt Solution
Abstract
Hydrogen gas can be electrochemically produced in microbial reverse-electrodialysis electrolysis cells (MRECs) using current derived from organic matter and salinity-gradient energy such as river water and seawater solutions. Here, it is shown that ammonium bicarbonate salts, which can be regenerated using low-temperature waste heat, can also produce sufficient voltage for hydrogen gas generation in an MREC. The maximum hydrogen production rate was 1.6 m(3) H(2)/m(3)·d, with a hydrogen yield of 3.4 mol H(2)/mol acetate at a salinity ratio of infinite. Energy recovery was 10% based on total energy applied with an energy efficiency of 22% based on the consumed energy in the reactor. The cathode overpotential was dependent on the catholyte (sodium bicarbonate) concentration, but not the salinity ratio, indicating high catholyte conductivity was essential for maximizing hydrogen production rates. The direction of the HC and LC flows (co- or counter-current) did not affect performance in terms of hydrogen gas volume, production rates, or stack voltages. These results show that the MREC can be successfully operated using ammonium bicarbonate salts that can be regenerated using conventional distillation technologies and waste heat making the MREC a useful method for hydrogen gas production from wastes.
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“Pt-based materials have been the most effective cathode catalysts for MECs;7”
From A 3D hybrid of layered MoS 2 /nitrogen-doped graphene nanosheet aerogels: an effective catalyst for hydrogen evolution in microbial electrolysis cells (2014) · cites this paper as [7]
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Cites
Aqueous Ammonia Equilibrium Calculations: Effect of pH and Temperature
Emerson, K., Russo, R. C., Lund, R. E., & Thurston, R. V. (1975) · Journal of the Fisheries Research Board of Canada · doi:10.1139/f75-274 · Cited by 1,540
Microbial Electrolysis Cells for High Yield Hydrogen Gas Production from Organic Matter
Logan, B. E., Call, D., Cheng, S., Hamelers, H. V. M., Sleutels, T. H. J. A., Jeremiasse, A. W., & Rozendal, R. A. (2008) · Environmental Science & Technology · doi:10.1021/es801553z · Cited by 1,368
Self-citationA novel ammonia—carbon dioxide forward (direct) osmosis desalination process
McCutcheon, J. R., McGinnis, R. L., & Elimelech, M. (2005) · Desalination · doi:10.1016/j.desal.2004.11.002 · Cited by 978
Hydrogen Production in a Single Chamber Microbial Electrolysis Cell Lacking a Membrane
Call, D. F., & Logan, B. E. (2008) · Environmental Science & Technology · doi:10.1021/es8001822 · Cited by 959
Self-citationMcCutcheon, J. R., McGinnis, R. L., & Elimelech, M. (2005) · Journal of Membrane Science · doi:10.1016/j.memsci.2005.10.048 · Cited by 839
Selection of inorganic-based draw solutions for forward osmosis applications
Achilli, A., Cath, T. Y., & Childress, A. E. (2010) · Journal of Membrane Science · doi:10.1016/j.memsci.2010.08.010 · Cited by 781
Sustainable and efficient biohydrogen production via electrohydrogenesis
Cheng, S., & Logan, B. E. (2007) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0706379104 · Cited by 680
Self-citationPractical Potential of Reverse Electrodialysis As Process for Sustainable Energy Generation
Długołęcki, P., Gambier, A., Nijmeijer, K., & Weßling, M. (2009) · Environmental Science & Technology · doi:10.1021/es9009635 · Cited by 369
Veerman, J. A., de Jong, R. M., Saakes, M., Metz, S. J., & Harmsen, G. J. (2009) · Journal of Membrane Science · doi:10.1016/j.memsci.2009.05.047 · Cited by 331
Veerman, J. A., Saakes, M., Metz, S. J., & Harmsen, G. J. (2010) · Environmental Science & Technology · doi:10.1021/es1009345 · Cited by 285
Research works printed but not linked: 1
- McCutcheon J. R., 2005, Desalination, 174, 1, 10.1016/j.desal.2004.11.002 · DOI
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Sen, S., Rath, R., Kamesh, R., & Roy, A. (2023) · Lecture notes in civil engineering · doi:10.1007/978-981-99-6762-9_4 · Cited by 1
Industrial Chemicals Synthesized Today from Carbon Dioxide and Its Direct Uses
Ganesh, I. (2025) · Green energy and technology · doi:10.1007/978-981-96-2321-1_5 · Cited by 1
Membrane-based electrochemical technologies: II. Microbial desalination cell
Zuo, K., Luo, S., & Huang, X. (2022) · Elsevier eBooks · doi:10.1016/b978-0-12-824470-8.00008-5
Enhancing Electricity Generation by Reverse Electrodialysis
Potap, A. (2025) · Portuguese National Funding Agency for Science, Research and Technology (RCAAP Project by FCT)
Chen, Y.-Y., Xu, R.-S., & Yen, H.-C. (2026) · Elsevier eBooks · doi:10.1016/b978-0-443-44692-4.00015-7
Metadata
- Authors
- Nam, J.-Y., Cusick, R. D., Kim, Y., & Logan, B. E.
- Affiliations
- Pennsylvania State University (US)
- Corresponding author
- Logan, Bruce E.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-09
- Volume
- 46
- Issue
- 9
- Pages
- 5240-5246
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2101213156
- Cited by
- 105
- References
- 23
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 2 · 2023: 6 · 2022: 12 · 2021: 8 · 2020: 9 · 2019: 6 · 2018: 7 · 2017: 10 · 2016: 10 · 2015: 12 · 2014: 8 · 2013: 6 · 2012: 5
- FWCI
- 8.21
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- King Abdullah University of Science and Technology Repository (King Abdullah University of Science and Technology) (submittedVersion)
- Funders
- King Abdullah University of Science and Technology
- National Renewable Energy Laboratory
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › Microbial Fuel Cells and Bioremediation
- Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane-based Ion Separation Techniques
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Anaerobic Digestion and Biogas Production
- Keywords
- hydrogen production, waste heat recovery, salinity gradient energy, acetate oxidation, cathodic overpotential, co-current and counter-current flow, energy efficiency, distillation
- MeSH terms
- Bicarbonates, Bioelectric Energy Sources, Hydrogen, Sodium Bicarbonate, Salinity
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