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Adsorption of CO2, CH4, and N2 on Ordered Mesoporous Carbon: Approach for Greenhouse Gases Capture and Biogas Upgrading
Abstract
Separation of CO₂ and N₂ from CH₄ is significantly important in natural gas upgrading, and capture/removal of CO₂, CH₄ from air (N₂) is essential to greenhouse gas emission control. Adsorption equilibrium and kinetics of CO₂, CH₄, and N₂ on an ordered mesoporous carbon (OMC) sample were systematically investigated to evaluate its capability in the above two applications. The OMC was synthesized and characterized with TEM, TGA, small-angle XRD, and nitrogen adsorption/desorption measurements. Pure component adsorption isotherms of CO₂, CH₄, and N₂ were measured at 278, 298, and 318 K and pressures up to 100 kPa, and correlated with the Langmuir model. These data were used to estimate the separation selectivities for CO₂/CH₄, CH₄/N₂, and CO₂/N₂ binary mixtures at different compositions and pressures according to the ideal adsorbed solution theory (IAST) model. At 278 K and 100 kPa, the predicted selectivities for equimolar CO₂/CH₄, CH4/N₂, and CO₂/N₂ are 3.4, 3.7, and 12.8, respectively; and the adsorption capacities for CH₄ and CO₂ are 1.3 and 3.0 mmol/g, respectively. This is the first report of a versatile mesoporous material that displays both high selectivities and large adsorption capacities for separating CO₂/CH₄, CH₄/N₂, and CO₂/N₂ mixtures.
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Metadata
- Authors
- Yuan, B., Wu, X., Chen, Y., Huang, J., Luo, H., & Deng, S.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-08
- Volume
- 47
- Issue
- 10
- Pages
- 5474-5480
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2071766948
- Cited by
- 305
- References
- 46
- FWCI
- 29.23
- Type
- journal article
- Language
- en
- Open access
- closed
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