The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Impact of Deashing Treatment on Biochar Structural Properties and Potential Sorption Mechanisms of Phenanthrene
Abstract
Knowledge of the mineral effects of biochars on their sorption of hydrophobic organic contaminants (HOCs) is limited. Sorption of phenanthrene (PHE) by plant-residue derived biochars (PLABs) and animal waste-derived biochars (ANIBs) obtained at two heating treatment temperatures (HTTs) (450 and 600 °C) and their corresponding deashed biochars was investigated. The decreased surface polarity and increased bulk polarity of biochars after deashing treatment indicated that abundant minerals of biochars benefit external exposure of polar groups associated organic matter (OM). Organic carbon (OC)-normalized distribution coefficients (K(oc)) of PHE by biochars generally increased after deashing, likely due to enhancement of favorable and hydrophobic sorption sites caused by mineral removal. Positive correlation between PHE log K(oc) by PLABs and bulk polarity combined with negative correlation between PHE log K(oc) values by ANIBs and surface polarity suggested PLABs and ANIBs have different sorption mechanisms, probably attributed to their large variation of ash content because minerals influenced OM spatial arrangement within biochars. Results of this work could help us better understand the impact of minerals, bulk/surface polarity, and sorption domain arrangement of biochars on their HOCs sorption and predict the fate of HOCs in soils after biochar application.
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Cites
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An overview on engineering the surface area and porosity of biochar
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Influence of Adsorption Sites of Biochar on its Adsorption Performance for Sulfamethoxazole
Li, Y., Wang, B., Shang, H., Cao, Y., Yang, C., Hu, W., Feng, Y., & Yu, Y. (2023) · Chemosphere · doi:10.1016/j.chemosphere.2023.138408 · Cited by 99
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“…2010; Moško et al., 2021; Wiedemeier et al., 2015; Wurster et al., 2013; Xiao et al., 2018) and how it affects its properties (Brewer et al., 2012; Chun et al., 2004; de la Rosa et al., 2014; Fan et al., 2020; Harvey et al., 2011; Singh, Cowie, et al., 2012; Sun et al., 2013; Wei et al., 2017).”
Metadata
- Authors
- Sun, K., Kang, M., Zhang, Z., Jin, J., Wang, Z., Pan, Z., Xu, D., Wu, F., & Xing, B.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-25
- Volume
- 47
- Issue
- 20
- Pages
- 11473-11481
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2318880614
- Cited by
- 271
- References
- 8
- FWCI
- 9.59
- Type
- journal article
- Language
- en
- Open access
- closed
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