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A Silica-Supported Iron Oxide Catalyst Capable of Activating Hydrogen Peroxide at Neutral pH Values
Open accessAbstract
Iron oxides catalyze the conversion of hydrogen peroxide (H(2)O(2)) into oxidants capable of transforming recalcitrant contaminants. Unfortunately, the process is relatively inefficient at circumneutral pH values because of competing reactions that decompose H(2)O(2) without producing oxidants. Silica- and alumina-containing iron oxides prepared by sol-gel processing of aqueous solutions containing Fe(ClO(4))(3), AlCl(3), and tetraethyl orthosilicate efficiently catalyzed the decomposition of H(2)O(2) into oxidants capable of transforming phenol at circumneutral pH values. Relative to hematite, goethite, and amorphous FeOOH, the silica-iron oxide catalyst exhibited a stoichiometric efficiency, defined as the number of moles of phenol transformed per mole of H(2)O(2) consumed, which was 10-40 times higher than that of the iron oxides. The silica-alumina-iron oxide catalyst had a stoichiometric efficiency that was 50-80 times higher than that of the iron oxides. The significant enhancement in oxidant production is attributable to the interaction of Fe with Al and Si in the mixed oxides, which alters the surface redox processes, favoring the production of strong oxidants during H(2)O(2) decomposition.
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Pignatello, J. J., Oliveros, E., & MacKay, A. (2006) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643380500326564 · Cited by 4,133
Research works printed but not linked: 29
- Valentine R. L., 1998, J. Environ. Eng., 124, 31, 10.1061/(ASCE)0733-9372(1998)124:1(31) · doi:10.1061/(asce)0733-9372(1998)124:1(31
- Kwan W. P., 2003, Environ. Sci. Technol., 37, 1150, 10.1021/es020874g · DOI · Paper page
- Ravikumar J. X., 1994, Environ. Sci. Technol., 28, 394, 10.1021/es00052a009 · DOI · Paper page
- Miller C. M., 1999, Water Res., 33, 2805, 10.1016/S0043-1354(98)00500-4 · DOI
- Huang H.-H., 2001, Water Res., 35, 2291, 10.1016/S0043-1354(00)00496-6 · DOI · Paper page
- Yeh C. K.-J., 2004, Pract. Period. Hazard.,, Toxic, Radioact. Waste Manage., 8, 161, 10.1061/(ASCE)1090-025X(2004)8:3(161) · doi:10.1061/(asce)1090-025x(2004)8:3(161
- Lim H., 2006, Chem. Commun., 463, 10.1039/B513517F · DOI · Paper page
- Chou S., 1999, Chemosphere, 38, 2719, 10.1016/S0045-6535(98)00474-3 · doi:10.1016/s0045-6535(98)00474-3
- Crowther N., 2003, Appl. Catal., B, 46, 293, 10.1016/S0926-3373(03)00224-8 · doi:10.1016/s0926-3373(03)00224-8
- Calleja G., 2005, Water Res., 39, 1741, 10.1016/j.watres.2005.02.013 · DOI
- Barrault J., 2000, Appl. Catal., B, 27, L225, 10.1016/S0926-3373(00)00170-3 · DOI
- Cheng M., 2008, Appl. Catal., B, 77, 355, 10.1016/j.apcatb.2007.08.006 · DOI
- Luo M., 2009, Appl. Catal., B, 85, 201, 10.1016/j.apcatb.2008.07.013 · DOI · Paper page
- Schwertmann U., 2000, Iron Oxides in the Laboratory: Preparation and Characterization, 10.1002/9783527613229 · DOI · Paper page
- Eisenberg G., 1943, Ind. Eng. Chem., Anal. Ed., 15, 327, 10.1021/i560117a011 · DOI · Paper page
- Tamura H., 1974, Talanta, 21, 314, 10.1016/0039-9140(74)80012-3 · DOI · Paper page
- Corma A., 1997, Chem. Rev., 97, 2373, 10.1021/cr960406n · DOI · Paper page
- Pera-Titus M., 2004, Appl. Catal., B, 47, 219, 10.1016/j.apcatb.2003.09.010 · DOI · Paper page
- Kwan W. P., 2002, Environ. Sci. Technol., 36, 1467, 10.1021/es011109p · DOI · Paper page
- Stefansson A., 2007, Environ. Sci. Technol., 41, 6117, 10.1021/es070174h · DOI
- Lin S. S., 1998, Environ. Sci. Technol., 32, 1417, 10.1021/es970648k · DOI · Paper page
- Petigara B. R., 2002, Environ. Sci. Technol., 36, 639, 10.1021/es001726y · DOI · Paper page
- Haber F., 1934, Proc. R. Soc. London, Ser. A, 332
- Voegelin A., 2003, Environ. Sci. Technol., 37, 972, 10.1021/es025845k · DOI · Paper page
- Keenan C. R., 2008, Environ. Sci. Technol., 42, 1262, 10.1021/es7025664 · DOI · Paper page
- Lee Y. N., 2001, Appl. Catal., A, 215, 245, 10.1016/S0926-860X(01)00536-1 · DOI
- Amonette J. E., 2000, Environ. Sci. Technol., 34, 4606, 10.1021/es9913582 · DOI · Paper page
- Esshington M. E., 2004, Soil and Water Chemistry: An Integrative Approach.
- Zeglínski J., 2006, J. Mol. Struct., 794, 83, 10.1016/j.molstruc.2006.01.043 · doi:10.1016/j.molstruc.2006.01.043
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Yun, E.-T., Yoo, H.-Y., Bae, H., Kim, H.-I., & Lee, J. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b02519 · Cited by 359
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Metadata
- Authors
- Pham, A. L.-T., Lee, C., Doyle, F. M., & Sedlak, D. L.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-10-30
- Volume
- 43
- Issue
- 23
- Pages
- 8930-8935
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2077452659
- Cited by
- 364
- References
- 1
- FWCI
- 14.59
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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